Proposed network calibration procedures
-
Archive tank at each site
– Detect any long-term drifts of the four calibration tanks
– Detect any abrupt changes in the measurements caused by replacement of calibration tanks or maintenance activities -
Four traveling target tanks
-Detect leaks between the calibration gas valve manifold and the leak-test valve, short-term calibration tank drifts, problems with flow rates, insufficient drying of the samples -
Roving system (using LICOR-7000) with independent calibration tanks
-Detect leaks anywhere within the system, short-term calibration tank drifts, problems with flow rates, insufficient drying of the samples, instrument-dependent errors due to the use of the LICOR-820 rather than the LICOR-7000
Preliminary results of the 4th WMO Round-robin intercalibration report indicate that our calibrated results for the three tanks (Group 2) were 0.10, 0.03, and 0.01 ppm different from the NOAA-ESRL measured values.
Tank number | Number of samples (NOAA) | Standard deviation (NOAA) | PSU reported value | Difference (PSU value – NOAA value) |
#4542 | 10 | 0.06 ppm | 355.94 ppm | 0.10 ppm |
#4509 | 6 | 0.02 ppm | 368.28 ppm | 0.03 ppm |
#4539 | 5 | 0.02 ppm | 384.55 ppm | 0.01 ppm |