In the previous post, I talked about the second law of thermodynamics: there can be do thermodynamic transformation whose overall effect is to move heat from a cooler body to a hotter one. Since the *reverse* of such a transformation (moving heat from a hotter body to a cooler one) happens naturally by conduction, the second law naturally contains an element of *irreversibility* which it is natural to expect is expressed by an *inequality*. The quantity to which this applies is the famous **entropy**.

# Tag Archives: thermodynamics

# Thermodynamics III: second law

The first law of thermodynamics says that heat is a form of energy. There is a lot of heat about! For instance, the amount of heat energy it would take to change the temperature of the world’s oceans by one degree is about \(6 \times 10^{24}\) joules. That is four orders of magnitude greater than the world’s annual energy consumption! So, if we could somehow how to figure out how to extract one degree’s worth of heat energy from the oceans, we could power the world for ten thousand years! Continue reading

# Thermodynamics

I’ve been trying to learn a bit about classical *thermodynamics*, using Fermi’s lecture notes which are available as a low-cost Dover reprint.

That’s partly just because the subject has always been a bit mysterious to me and I would like to understand it better, but also because the Second Law of thermodynamics often gets invoked in environmental discussions – and I wonder whether it is being used accurately. (See this blog post for extended discussion about that.)

As a mathematician, I expected the discussion of thermodynamics to be *statistical*, heavily engaged with probability theory. But the main text of Fermi’s book is not about statistical mechanics at all. Instead, it is about *classical* thermodynamics; the nineteenth century theory that attempted to quantify the properties of that mysterious fluid, “heat”, and its transmission from one body to another. Continue reading