PUBLICATIONS ON FUNDAMENTAL POLYMER CHEMISTRY
SMALL-MOLECULE MODEL CHEMISTRY
PUBLICATIONS ON BIOMEDICAL MATERIALS
PUBLICATIONS RELATED TO OPTICS, ELECTRONICS, AND PHOTONICS
SURFACE SCIENCE AND COMPOSITE MATERIALS
CLATHRATE (MOLECULAR INCLUSION) CHEMISTRY
REVIEW ARTICLES AND BOOK CHAPTERS
PUBLICATIONS ON FUNDAMENTAL POLYMER CHEMISTRY
- Allcock, H. R.; Eastham, A. M.
Co-Catalysis in Friedel-Crafts Reactions. Polymerization of 2-Butene by Boron Fluoride-Methanol
Can. J. Chem. 1963, 41, 932-936
- Allcock, H. R.; Kugel, R. L.
Ionic Polymerization of Diphenylphosphine Oxide
- Polymer Sci., Part A, 1963, 1, 3627-3642
- Allcock, H. R.; Best, R. J.
The Mechanism of Phosphonitrilic Chloride Polymerization. Capacitance, Conductance, and Electron‑Spin Resonance Studies
Can. J. Chem. 1964, 42, 447‑455.
- Allcock, H. R.; Kugel, R. L.
Synthesis of High Polymeric Alkoxy‑ and Aryloxyphosphonitriles
- Am. Chem. Soc. 1965, 87, 4216‑4217
- Allcock, H. R.; Kugel, R. L.; Valan, K. J.
High Molecular Weight Poly(alkoxy‑ and aryloxyphosphazenes)
Inorg. Chem. 1966, 5, 1709‑1715.
- Allcock, H. R.; Kugel, R. L.
High Molecular Weight Poly(diaminophosphazenes)
Inorg. Chem. 1966, 5, 1716‑1718.
- Allcock, H. R.; Moore, G. Y.
Synthesis of Poly(organophosphazene) Copolymers and Crosslinked Polymers by Ligand Exchange
Macromolecules 1972, 5, 231‑232.
36 Allcock, H. R.; Kugel, R. L.; Stroh, E. G.
The Structure and Properties of Poly(difluorophosphazenes)
Inorg. Chem. 1972, 11, 1120‑1123.
- Allcock, H. R.; Gardner, J. E.; Smeltz, K. M.
Polymerization of Hexachlorocyclotriphosphazene. The Role of Phosphorus Pentachloride, Water, and Hydrogen Chloride
Macromolecules 1975, 8, 36‑42.
- Allcock, H. R.; Moore, G. Y.
Polymerization and Copolymerization of Phenyl‑halogenocyclotriphosphazenes
Macromolecules 1975, 8, 377‑382.
- Allcock, H. R.; Mack, D. P.
High Molecular Weight Poly(diaminophosphazenes) with Mixed Substituents
- Chem. Soc., Chem. Commun.1970, 11, 685.
- Allcock, H. R.; Cook, W. J.; Mack, D. P.
High Molecular Weight Poly[bis(amino)phosphazenes] and Mixed Substituent
Poly(aminophosphazenes), Inorg. Chem. 1972, 11, 2584‑2590.
- Allcock, H. R.; Cook, W. J.
Thermolysis of Poly[bis(trifluoroethoxy)phosphazene]
Macromolecules 1974, 7, 284‑290.
- Allcock, H. R.; Moore, G. Y.; Cook, W. J.
The Thermal Breakdown of Poly(diphenoxyphosphazene)
Macromolecules 1974 7, 571575.
- Allcock, H. R.; Allen, R. W.; Meister, J. J.
Conformational Analysis of Poly(dihalophosphazenes)
Macromolecules 1976, 9, 950‑955
- Allen, R. W.; Allcock, H. R.
Conformational Analysis of Poly(alkoxy‑ and aryloxyphosphazenes)
Macromolecules 1976, 9, 956‑960.
- Allcock, H. R.; Patterson, D. B.
Ring‑Ring and Ring‑Chain Equilibration of Dimethylphosphazenes.
Relationship to Phosphazene Polymerization
- Allcock, H. R.; Allen, R. W.; O’Brien, J. P.
Synthesis of Platinum Derivatives of Polymeric and Cyclic Phosphazenes
- Am. Chem. Soc. 1977, 99, 3984‑3987
- Allcock, H. R.; Patterson, D. B.; Evans, T. L.
Synthesis of Alkyl and Aryl Phosphazene High Polymers
- Am. Chem. Soc. 1977, 99, 6095‑6096.
- Allcock, H. R.; Schmutz, J. L.; Kosydar, K. M.
A New Route for Poly(organophosphazene) Synthesis. Polymerization, Copolymerizaton, and Ring‑Ring Equilibration of Trifluoroethoxy‑ and
Chloro‑substituted Cyclotriphosphazenes
Macromolecules 1978, 11, 179‑186.
- Allcock, H. R.; Patterson, D. B.; Evans, T. L.
Synthesis of Open‑Chain Poly(difluorophosphazene) and its Reactions with Alkoxides
Macromolecules 1979, 12, 172‑177.
- Allcock, H. R.; Chu, C. T.‑W.
The Reaction of Phenyllithium with Poly(dichlorophosphazene)
Macromolecules 1979, 12, 551‑555.
- Ritchie, R. J.; Harris, P. J.; Allcock, H. R.
Polymerization of Monoalkyl‑pentachloro‑cyclotriphosphazenes
Macromolecules 1979, 12, 1014‑1015.
- Allcock, H. R.; Evans, T. L.; Patterson, D. B.
The Reaction of Poly(difluorophosphazene) with Phenyllithium
Macromolecules 1980, 13, 201‑207.
- Allcock, H. R.; Arcus, R. A.
Crystalline Transitions and Related Physical Properties of Poly(dichloro‑phosphazene)
Macromolecules 1979, 12, 1130‑1136.
- Allcock, H. R.; Arcus, R. A.; Stroh, E. G.
X‑Ray Diffraction Analysis of the Stucture of Poly(dichlorophosphazene)
Macromolecules 1980, 919‑928.
- Allcock, H. R.; Fuller, T. J.; Evans, T. L.
Side Group Construction in High Polymeric Phosphazenes Via Lithiophenoxy Intermediates
Macromolecules 1980, 13, 1325‑1332.
- Allcock, H. R.; Ritchie, R. J.; Harris, P. J.
Synthesis of Alkylphosphazene High Polymers Via the Polymerization of Monoalkylpentachlorocyclotriphosphazenes, N3P3Cl5R
Macromolecules 1980, 13, 1332‑1338.
- Allcock, H. R.; Scopelianos, A. G.; O’Brien, J. P.; Bernheim, M. Y.
Synthesis and Structure of Carborane‑Substituted Cyclic and Polymeric Phosphazenes
- Am. Chem. Soc. 1981, 103, 350‑357.
- Evans, T. L.; Allcock, H. R.
Poly(difluorophosphazene): A New Intermediate for the Synthesis of Poly‑(organophosphazenes)
- Macro. Sci. ‑ Chem.(Proc. of Symp. on Inorganic Macromolecules) 1981, A16(1), 409‑423.
- Evans, T. L.; Patterson, D. B.; Suszko, P. R.; Allcock, H. R.
A Crosslinking Mechanism in the Reactions of Poly(difluorophosphazene) with Alkyllithium Reagents
Macromolecules 1981, 14, 218‑221.
- Allcock, H. R.; Austin, P. E.; Rakowsky, T. F.
Diazo Coupling Reactions with Poly(organophosphazenes)
Macromolecules 1981, 14, 1622‑1625.
- Allcock, H. R.; Ferrar, W. T.; Levin, M. L.
Polymerization in Clathrate Tunnel Systems: Stereo‑Controlled Polymerization of Unsaturated Monomers in Crystals of
Tris(o‑phenylenedioxy)cyclotri‑phosphazene
Macromolecules 1982, 15, 697‑703.
- Allcock, H. R.; Scopelianos, A. G.; Whittle, R. R.; Tollefson, N. M.
Cyclic and High Polymeric Carboranyl Phosphazenes as Ligands for Transition Metals
- Am. Chem. Soc. 1983 105, 1316‑1321.
- Austin, P. E.; Riding, G. H.; Allcock, H. R.
An Improved Method for the Synthesis of Poly(organophosphazenes) and Hindered Cyclophosphazenes
Macromolecules 1983, 16, 719‑722.
- Allcock, H. R.; Hymer, W. C.; Austin, P. E.
Diazo Coupling of Catecholamines with Poly(organophosphazenes)
Macromolecules 1983, 16, 1401‑1406.
- Scopelianos, A. G.; Allcock, H. R.
Solution Polymerization of Chlorocyclophosphazenes in Carbon Disulfide
Macromolecules 1987, 20, 432‑433.
- Allcock, H. R.; Brennan, D. J.; Allen, R. W.
Reactions between Hexachlorocyclotriphosphazene and Hexamethylcyclotri‑siloxane: Polymerization, Ring Cleavage, and Crosslinking
Inorganic Chemistry 1985, 18, 139‑144.
- Allcock, H. R.; Levin, M. L.
The Stereocontrolled Polymerization of Acrylic Monomers Within a Tris‑(o‑phenylenedioxy)cyclotriphosphazene Tunnel Clathrate
Macromolecules 1985, 18, 1324‑1330.
- Allcock, H. R.; Connolly, M. S.
Polymerization and Halogen Scrambling Behavior of Phenyl‑Substituted Cyclotriphosphazenes
Macromolecules 1985, 18, 1330‑1340.
- Allcock, H. R.; Lavin, K. D.; Riding, G. H.
Ring‑Opening Polymerization of Metallocene Cyclophosphazene Derivatives
Macromolecules 1985 18, 1340‑1345.
- Dubois, R. A.; Garrou, P. E.; Lavin, K. D.; Allcock, H. R.
Cobalt Hydroformylation Catalyst Supported on a Phosphinated Polyphosphazene: Identification of Phosphorus‑Carbon Bond Cleavage as a
Mode of Catalyst Deactivation
Organometallics 1986, 5, 460‑466.
- Allcock, H. R.; Riding, G. H.; Lavin, K. D.
Polymerization of New Metallocenylphosphazenes
Macromolecules 1987, 20, 6‑10.
- Allcock, H. R.; Mang, M. N.; McDonnell, G. S.; Parvez, M.
Transition Metal Derivatives of Polyphosphazenes: Syntheses of Polyphosphazenes and Cyclic Model Compounds with Iron Cyclopentadienyl
Carbonyl Side Groups
Macromolecules 1987, 20, 2060‑2067.
- Allcock, H. R.; Brennan, D. J.; Graaskamp, J. M.
Ring‑Opening Polymerization of Methylsilane‑ and Methylsiloxane‑Substituted Cyclotriphosphazenes
Macromolecules 1988, 21, 1‑10.
- Allcock, H. R.; Connolly, M. S.; Sisko, J. T.; Al‑Shali, S.
Effects of Organic Side Group Structures on the Properties of Poly‑(organophosphazenes)
Macromolecules 1988, 21, 323‑334.
- Allcock, H. R.; Desorcie, J. L.; Rutt, J. S.
Alkylation of Cyclic and High Polymeric Phosphazenes via Reactions between Aluminum Alkyls and Aminophosphazenes
Organometallics 1988, 7, 612‑619.
- Allcock, H. R.; Brennan, D. J.
Organosilicon Derivatives of Cyclic and High Polymeric Phosphazenes
- Organomet. Chem., 1988, 341, 231‑239.
- Allcock, H. R.; Brennan, D. J.; Dunn, B. S.
Synthesis of Polyphosphazenes Bearing Geminal Trimethylsilylmethylene and Alkyl or Phenyl Side Groups
Macromolecules 1989,22, 1534‑1539.
- Allcock, H. R.; Mang, M. N.; Benesi, A. J.
Polyphosphazene Molecular Dynamics Using Solid State 2D NMR
Reported in Mang, M. N., Ph.D. Thesis, The Pennsylvania State University, 1988.
- Manners, I.; Riding, G. H.; Dodge, J. A.; Allcock, H. R.
Role of Ring Strain and Steric Hindrance in a New Method for the Synthesis of Macrocyclic and High Polymeric Phosphazenes
- Am. Chem. Soc. 1989, 111, 3067‑3069.
- Allcock, H. R.; Mang, M. N.; Dembek, A. A.; Wynne, K. J.
Poly(aryloxyphosphazenes) with Phenylphenoxy and Related Bulky Side Groups. Synthesis, Thermal Transition Behavior, and Optical Properties
Macromolecules 1989, 22, 4179‑4190.
- Manners, I.; Renner, G.; Nuyken, O.; Allcock, H. R.
Polycarbophosphazenes: A New Class of Inorganic‑Organic Macromolecules
- Am. Chem. Soc. 1989, 111, 5478‑5480.
- Allcock, H. R.; Coggio, W. D.
Organosiloxyphosphazene Polymers: Synthesis via Aminosiloxane Reagents
Macromolecules 1990, 23, 1626‑1635.
- Dodge, J. A.; Manners, I.; Allcock, H. R.; Renner, G.; Nuyken O.
Polythiophosphazenes: New Inorganic Macromolecules with Backbones Composed of Phosphorus, Nitrogen, and Sulfur Atoms
- Am. Chem. Soc. 1990, 112, 1268‑1269.
- Brennan, D. J.; Graaskamp, J.; Dunn, B. S.; Allcock, H. R.
Organosilicon Derivatives of Cyclic and High Polymeric Phosphazenes
Inorg. Synth. 1989, 25, 60‑68
- Allcock, H. R.; McDonnell, G. S.; Desorcie, J. L.
Synthesis of New Polyphosphazene Elastomers
Macromolecules 1990, 23, 3873‑3877.
- Allcock, H. R.; McDonnell, G. S.; Desorcie, J. L.
Ring Expansion and Equilibration in Organophosphazenes, and the Relationship to Polymerization
Inorganic Chemistry 1990, 29, 3839‑3844.
- Allcock, H. R.; Coley, S. M.; Manners, I.; Renner, G.; Nuyken, O.
Poly[(aryloxy)carbophosphazenes]: Synthesis, Properties, and Thermal Transition Behavior
Macromolecules 1991, 24, 2024‑2028.
- Visscher, K, B.; Manners, I.; Allcock, H. R.
Interpenetrating Polymer Networks of Poly(organophosphazenes) and Organic Polymers
Macromolecules 1990, 23, 4885‑4886.
- Allcock, H. R.; Rutt, J. S.; Welker, M. F.; Parvez, M.
Cyanophosphazene Small Molecules and High Polymers: Synthesis and Structure
Inorganic Chemistry 1993, 32, 2315‑2321.
- Allcock, H. R.; Rutt, J. S.
Synthesis of Polyphosphazenes with Isothiocyanato, Thiourethane, and Thiourea Side Groups
Macromolecules 1991, 24, 2852‑2857.
- Allcock, H. R.; Rutt, J. S.; Fitzpatrick, R. J.
A Surface Reaction of Poly[bis(trifluoroethoxy)phosphazene] Films by Basic Hydrolysis
Chemistry of Materials 1991, 3, 442‑449.
- Allcock, H. R.; Fitzpatrick, R. J.
Functionalization of the Surface of Poly[bis(trifluoroethoxy)phosphazene] by Reactions with Alkoxide Nucleophiles
Chemistry of Materials 1991, 3, 450‑454.
- Ngo, D. C.; Rutt, J. S.; Allcock, H. R.
Poly(phosphazophosphazenes): A New Class of Inorganic Polymers with Short‑Chain Branching
- Am. Chem. Soc. 1991, 113, 5075‑5076.
- Allcock, H. R.; Dodge, J. A.; Manners, I.; Riding, G. H.
Strain‑Induced Ring‑Opening Polymerization of Ferrocenylorganocyclotriphosphazenes: A New Synthetic Route to Poly(organophosphazenes)
- Am. Chem. Soc. 1991, 113, 9596‑9603.
- Allcock, H. R.; Fitzpatrick, R. J.
Sulfonation of Aryloxy‑ and Arylamino‑Phosphazenes: Small‑Molecule Compounds, Polymers, and Surfaces
Chemistry of Materials 1991, 3, 1120‑1132.
- Allcock, H. R.; Ngo, D. C.
Synthesis of Poly(bis‑phosphazo)phosphazenes Bearing Aryloxy and Alkoxy Side Groups
Macromolecules 1992, 25, 2802‑2810.
- Allcock, H. R.; Fitzpatrick, R. J.; Salvati, L.
Oxidation of Poly[di(4‑methylphenoxy)phosphazene] Surfaces, and Chemistry of the Surface Carboxylic Acid Groups
Chemistry of Materials 1992, 4, 769‑775.
- Allcock, H. R.; Turner, M. L.
Ring Expansion and Polymerization of Transannular‑Bridged Cyclotri-phosphazenes and Their Spirocyclic Analogues
Macromolecules 1993, 26 3‑10.
- Allcock, H. R.; Visscher, K. B.; Manners, I.
Polyphosphazene‑Organic Polymer Interpenetrating Polymer Networks
Chemistry of Materials 1992, 4, 1188‑1192.
- Allcock, H. R.; Fitzpatrick, R. J.; Visscher, K.
Thin Layer Grafts of Poly[bis(methoxyethoxyethoxy)phosphazene] on Organic Polymer Surfaces
Chemistry of Materials 1992, 4, 775‑780.
- Allcock, H. R.; Coggio, W. D.
Synthesis and Properties of High Polymeric Phosphazenes with Trimethylsilyl-Methyl Side Groups
Macromolecules 1993, 26, 764‑771.
- Allcock, H. R.; Dodge, J. A.; Manners, I.
Poly(thiophosphazenes): New Inorganic Polymers
Macromolecules 1993, 26, 11‑16.
- Allcock, H. R.; Nelson, C. J.; Coggio, W. D.; Manners, I.; Koros, W. J.; Walker, D. R. B.; Pessan, L. A.
Gas Permeation and Selectivity of Poly(organophosphazene) Membranes
Macromolecules 1993, 26, 1493‑1502.
- Allcock, H. R.; Klingenberg, E. H.; Welker, M. F.
Alkylsulfonation of Cyclic and High Polymeric Phosphazenes
Macromolecules 1993, 26, 5512‑5516.
- Allcock, H. R.; Kim, Y. B.
Synthesis, Characterization, and Modification of Poly(organophosphazenes) that Bear Both 2,2,2‑Trifluoroethoxy and Phenoxy Groups
Macromolecules 1994, 6, 516‑524.
- Allcock, H. R.; Dudley, G. K.; Silverberg, E. N.
Stereocontrolled Polymerization of Diene Monomers within a Tris(o‑phenylene dioxy)cyclotriphosphazene Tunnel Clathrate
Macromolecules 1994, 27, 1039‑1044.
- Allcock, H. R.; Silverberg, E. N.; Dudley, G. K.
Stereocontrolled Polymerization within a Cyclophosphazene Clathrate Tunnel
Macromolecules 1994, 27, 1033‑1038.
- Allcock, H. R.; Coley, S. M.; Manners, I.; Visscher, K. B.; Parvez, M.
Reactivity and Polymerization of Pentachlorocyclo(carbotriphosphazene), N3P2CCl5
Inorg. Chem. 1993, 32, 5088‑5094.
- Diefenbach, U.; Allcock, H. R.
Synthesis of Cyclo‑ and Polyphosphazenes with Pyridine Side Groups
Inorganic Chemistry 1994, 33, 4562-4565.
- Allcock, H. R.; Coley, S. M.; Morrissey, C. T.
Synthesis and Properties of Poly[amino(carbophosphazenes)]
Macromolecules 1994, 27, 2904-2911.
- Allcock, H. R.; Smith, D. E.; Kim, Y. B.; Fitzgerald, J. J.
Poly(organophosphazenes) Containing Allyl Side Groups: Cross‑linking by Hydrosilylation
Macromolecules 1994, 27, 5206-5215.
- Allcock, H. R.; Silverberg, E. N.; Dudley, G. K.; Pucher, S. R.
Inclusion Polymerization Within a Tris(2,3‑naphthalenedioxy)cyclitrophosphazene Clathrate
Macromolecules 1994, 27, 7550-7555.
- Allcock, H. R.; Kuharcik, S. E.; Morrissey, C. T.; Ngo, D. C.
Poly(monophosphazo)phosphazenes: New Polymers with N=PR3Side Groups
Macromolecules 1994, 27, 7556-7564.
- Allcock, H. R.; Smith, D. E.
Surface Studies of Poly(organophosphazenes) Containing Diemethylsiloxane Grafts
Chemistry of Materials 1995, 7, 1469-1474.
- Allcock, H. R.; Visscher, K. B.; Kim, Y.-B.
New Polyphosphazenes with Unsaturated Side Groups: Use as Reaction Intermediates, Cross-Linkable Polymers, and as Components of
Interpenetrating Polymer Networks
Macromolecules 1996, 2721-2728.
- Honeyman, C. H.; Manners, I,; Morrissey, C. T.; Allcock, H. R.
Ambient Temperature Synthesis of Poly(dichlorophosphazene) with Molecular Weight Control
- Am. Chem. Soc.1995, 117, 7035-7036.
- Mack, L. L.; Fitzpatrick, R. J.; Allcock, H. R.
Hydrophobicity, Hydrophilicity, and Amphiphilicity in Phosphazene Small Molecules and High Polymers: Langmuir-Blodgett Studies
Langmuir, 1997, 13, 2123-2132.
- Allcock, H. R.; Dudley, G. K.
Lower Critical Solubility Temperature Study of Alkyl Ether-Based Polyphosphazenes
Macromolecules 1996, 29, 1313-1319.
- 341. Allcock, H. R.; Kuharcik, S. E.; Nelson, C. J.
The Synthesis and Characterization of Amino-organosiloxane-Bearing Polyphosphazenes: New Properties by the Elimination of Hydrogen
Bonding
Macromolecules 1996, 29, 3686-3693.
- Allcock, H. R.; Morrissey, C. T.; Way, W. K.; Winograd, N.
Controlled Formation of Carboxylic Acid Grops at Polyphosphazene Surfaces: Oxidative and Hydrolytic Routes
Chemistry of Materials 1996, 8, 2730-2738.
- Allcock, H. R.; O’Connor, S. J. M.; Olmeijer, D. L.; Napierala, M. E.; Cameron, C. G.
Polyphosphazenes Bearing Branched and Linear Oligoethyleneoxy Side Groups as Solid Solvents for Ionic Conduction
Macromolecules 1996, 23, 7544-7552.
- Allcock, H. R.; Crane, C. A.; Morrissey, C. T.; Nelson, J. M.; Reeves, S. D.; Honeyman, C. H.; Manners, I.
Living Cationic Polymerization of Phosphoranimines as an Ambient Temperature route to Polyphosphazenes with Controlled Molecular Weights,
Macromolecules 1996, 29, 7740-7747.
- Allcock, H. R.; Nelson, J. M.; Reeves, S. D.; Honeyman, C. H.; Manners, I.
Ambient Temperature Direct Synthesis of Poly(organophosphazenes) via the Living Cationic Polymerization of Organo-substituted
Phosphoranimines
Macromolecules 1997, 30, 50-56.
- Nelson, J. M.; Allcock, H. R.
Synthesis of Triarmed Star Polyphosphazenes via the “Living” Cationic Polymerization of Phosphoranimines at Ambient Temperatures
Macromolecules 1997, 30, 1854-1856.
- Allcock, H. R.; Reeves, S. D.; Nelson, J. M.; Crane, C. A.; Manners, I.
Polyphosphazene Block Copolymers via the Living Cationic, Ambient Temperature Polymerization of Phosphoranimines
Macromolecules 1997, 30, 2213-2215.
- Nelson, J. M.; Allcock, H. R.; Manners, I.
Cationic Homo- and Copolymerization of Fluorophosphoranimines as an Ambient Temperature Synthetic Route to Poly(fluorophosphazenes),
[N=PF(R)]n, with Controlled Architectures
Macromolecules 1997, 30, 3191-3196.
- Allcock, H. R.; Krause, W. E.
Polyphosphazenes with Adamantyl Side Groups
Macromolecules 1997, 30, 5683-5687.
- Nelson, J. M.; Primrose, A. P.; Hartle, T. J.; Allcock, H. R.; Manners, I.
Synthesis and Characterization of High Tg Polyphosphazenes via Functionalized Intermediates: Potential Electro-optical Materials
Macromolecules 1998, 31, 5206-5214.
- Allcock, H. R.; Olmeijer, D. L.; O’Connor, S. J. M.
Cation Complexation and Conductivity in Crown Ether Bearing Polyphosphazenes
Macromolecules 1998, 31, 753-759.
- Allcock, H. R.; McIntosh, M. B.; Klingenberg, E. H.; Napierala, M. E.
Functionalized Polyphosphazenes: Phosphazenes with Pendent Tertiary Trialkylamino Groups
Macromolecules 1998, 31, 5255-5263.
- Allcock, H. R.; Crane, C. A.; Morrissey, C. T.; Olshavsky, M. A.
A New Route to the Phosphazene Polymerization Precursors, Cl3P=NSiMe3 and (NPCl2)3
Inorganic Chemistry 1999, 38, 280-283.
- Allcock, H. R.; Primrose, A. P.; Sunderland, N. J.; Rheingold, A. L.; Guzei, I. A.; Parvez, M.
Inclusion of Polymers within the Crystal Structure of Tris(o-phenylenedioxy) cyclotriphosphazene
Proc. Int. Phosphorus Conf. Phosphorus, Sulfur, and Silicon 1999, 144-146, 61-64.
- Allcock, H. R.
Recent Developments with an Impact on the Future of Polyphosphazene Science and Technology
Proc. of Int. Phosphorus Conf. Phosphorus, Sulfur and Silicon 1999, 144-146, 61-64.
- Allcock, H. R.; Laredo, W. R.; de Denus, C. R.; Taylor, J. P.
Ring-Opening Metathesis Polymerization of Phosphazene-Functionalized Norbornenes
Macromolecules 1999, 32, 7719-7725
- Allcock, H. R; Nelson, J. M.; Prange, R.; Crane, C. A.; de Denus, C. R.
Synthesis of Telechelic Polyphosphazenes via the Ambient Temperature Living Cationic Polymerization of Amino Phosphoranimines
Macromolecules 1999, 32, 5736-5743.
- Prange, R.; Allcock, H. R.
Telechelic Syntheses of the First Phosphazene Siloxane Block Copolymers
Macromolecules 1999, 32, 6390-6392.
- Allcock, H. R.; de Denus, C. R.; Prange, R.; Nelson, J. M.
Synthesis of Trifluoromethyl and Methyl Phosphazene Polymers: Differences Between Polymerization and Initiator/Terminator Properties
Macromolecules 1999, 32, 7999-8004.
- Allcock, H. R.; Reeves, S. D.; Nelson, J. M.; Manners, I.
Synthesis and Characterization of Phosphazene Di- and Tri-block Copolymers via the Controlled Cationic, Ambient Temperature Polymerization
of Phosphornimines
Macromolecules 2000, 33, 3999-4007.
- Diefenbach, U.; Cannon, A. M.; Stromberg, B. E.; Olmeijer, B. E.; Allcock, H. R.
Synthesis and Metal Coordination of Thioether Containing Cyclo- and Poly(organophosphazenes)
- Applied Polymer Science2000, 78, 650-661.
- Allcock, H. R.; Reeves, S. D.; de Denus, C. R.; Crane, C. A.
Influence of Reaction Parameters on the Living Cationic Polymerization of Phosphoranimines to Polyphosphazenes
Macromolecules 2001, 34, 748-754.
- Chang, Y.; Lee, S. C.; Kim, C.; Reeves, S. D.; Allcock, H. R.
Synthesis and Micellar Characterization of an Amphiphilic Diblock Copolyphosphazene
Macromolecules 2001, 34, 269-274.
- Hartle, T. J.; Sunderland, N. J.; McIntosh, M. B.; Allcock, H. R.
Phosphinimine Modifiation of Organic Polymers
Macromoleules 2000, 33, 4307-4309.
- Prange, R.; Reeves, S. D.; Allcock, H. R.
Polyphosphazene-Polystyrene Copolymers: Block and Graft Copolymers from Polyphosphazene and Polystyrene Macromonomers
Macromolecules 2000, 33, 5763-5765.
- Kellam, E. C.; Hofmann, M. A.; Allcock, H. R.
Synthesis of Well-Defined Cyclolinear Phosphazene-Containing Polymers via ADMET Polymerization
Macromolecules 2001, 34, 5140-5146.
- Allcock, H. R.; Laredo, W. R.; Kellam, E. C.; Morford, R. V.
Polynorbornenes Bearing Pendent Cyclotriphosphazenes with Oligoethyleneoxy Side Groups: Behavior as Solid Polymer Electrolytes
Macromolecules 2001, 34, 787-794.
- Allcock, H. R.; Sunderland, N. J.
Separation of Polymers and Small Molecules by Crystalline Host Systems
Macromolecules 2001, 34, 3069-3076.
- Allcock, H. R.; de Denus, C. R.; Prange, R.; Laredo, W. R.
Synthesis of Norbornenyl Telechelic Polyphosphazenes and Ring-Opening Metathesis Polymerization of (ROMP) Reactions
Macromolecules 2001, 34, 2757-2765.
- Allcock, H. R.; Hartle, T. J.; Taylor, J. P.; Sunderland, N. J.
Organic Polymers with Cyclophosphazene Side Groups: Influence of the Phosphazene on Physical Properties and Thermolysis
Macromolecules 2001, 34, 3896-3904.
- Allcock, H. R.; Prange, R.
Properties of Poly(phosphazene-siloxane) Block Copolymers Synthesized via Telechelic Polyphosphazenes and Polysiloxane
Macromolecules 2001, 34, 6858-6865.
- York, S.; Kellam, E. C.; Allcock, H. R.; Frech, R.
A Vibrational Spectroscopic Study of Lithium Triflate in Polyphosphazenes with Linear Oligoethyleneoxy Side Chains of Different Lengths
Electrochim. Acta 2001, 46, 1553-1557.
- Allcock H. R.; Kellam, E. C.
The Incorporation of Cyclic Phosphazene Trimers into Saturated and Unsaturated Ethylene-Like Polymer Backbones
Macromolecules 2002, 35, 40-47.
- Hofmann, M. A.; Ambler, C. M.; Maher, A. E.; Chalkova, E.; Zhou, X. Y.; Lvov, S. N.; Allcock, H. R.
Synthesis of Polyphosphazenes with Sulfonimide Side Groups
Macromolecules 2002, 35, 6490-6493.
- Chang, Y.; Bender, J. D.; Phelps, M. V. B.; Allcock, H. R.
Synthesis and Self-Association Behavior of Biodegradable Amphiphilic Poly[bis(ethyl glycinat-N-y)phosphazene]-PEO Block Copolymers
Biomacromolecules 2002, 3, 1364-1369.
- Allcock, H. R.; Hofmann, M. A.; Ambler, C. M.; Morford, R. V.
Phenylphosphonic Acid Functionalized Poly[aryloxyphosphazenes]
Macromolecules 2002, 35, 3483-3489.
- Chang, Y.; Powell, E. S.; Allcock, H. R.; Park, S. M.; Kim, C.
Thermosensitive Behavior of Poly[bis(methoxyethoxyethoxy)- phosphazene]-Poly(ethylene oxide) Block Copolymers
Macromolecules 2003, 36, 2568-2570.
- Chang, Y.; Allcock, H. R.
A Covalently Interconnected Phosphazene-Silicate Hybrid Network: Synthesis, Characterization, and Hydrogel-Related Applications
Advanced Materials 2003, 15, 537-541.
- Chang, Y.; Prange, R.; Allcock, H. R.; Lee, S. C.; Kim, C.
Amphiphilic Poly[bis(trifluoroethoxy)phosphazene]-Poly(ethylene oxide) Block Copolymers: Synthesis and Micellar Characteristics
Macromolecules 2002, 35, 8556-8559.
- Allcock, H. R.; Maher, A. E.; Ambler, C. M.
Side Group Exchange in Poly(organophosphazenes) with Fluoroalkoxy Substituents
Macromolecules 2003, 36, 5566-5572.
- Maher, A. E.; Ambler, C. M.; Powell, E. S.; Allcock, H. R.
Dependency of Thermal and Mechanical Properties on the Composition of Mixed-Substituent Poly(fluoroalkoxyphosphazenes)
- Applied Polymer Science 2004, 92, 2569-2576.
- Allcock, H. R.; Powell, E. S.; Maher, A. E.; Prange, A. E.; de Denus, C. R.
Telechelic Polyphosphazenes: Reaction of Living Poly(dichlorophosphazene) Chains with Alkoxy and Aryloxy Phosphoranimines
Macromolecules 2004, 37, 3635-3641.
- Allcock, H. R.; Powell, E. S.; Maher, A. E.; Berda, E. B.
Poly(methyl methacrylate)-graft-Poly[bis(trifluoroethoxy)phosphazene] Copolymers: Synthesis, Characterization, and Effects of Polyphosphazene
Incorporation
Macromolecules 2004 37, 5824-5829.
- Maher, A. E.; Allcock, H. R.
Influence of n-Hexoxy Group on the Properties of Fluoroalkoxyphosphazene Polymers
Macromolecules 2005, 38, 641-642.
- Allcock, H. R.; Powell, E. S.; Chang, Y.; Kim, C.
Synthesis and Micellar Behavior of Amphiphilic Polystyrene Poly[bis(methoxyethoxyethoxy)phosphazene] Block Copolymers
Macromolecules 2004, 37, 7163-7167.
- Allcock, H. R.; Welna, D. T.; Maher, A. E.
Single Ion Conductors: Polyphosphazenes with Sulfonimide Functional Groups
Solid State Ionics 2006, 177, 741-747
- Allcock, H. R.; Chang, Y.; Stone, D. A.
Control of the Conjugation Length and Solubility in Electroluminescent Polymers
- Polymer Science 2006, 44, 69-76
- Singh, A.; Laredo, W.; Allcock, H. R.
Synthesis and Characterization of L-Tyrosine-Functionalized Polyphosphazenes
Polym. Prepr. (Am. Chem. Soc. Div. Polym. Chem.) 2004, 45, 703-704.
- Stone, D. A.; Welna, D. T.; Allcock, H. R.
Synthesis of Amphiphilic Copolymers Containing Pendent Substituted Cyclotriphosphazenes via Ring-Opening Metathesis Polymerization
Polym. Prepr. (Am. Chem. Soc. Div. Polym. Chem.) 2004, 45, 696-697
- Powell, E. S.; Chang, Y.; Allcock, H. R.; Kim,C.
Self-Organization of Amphiphilic Polyphosphazene-Polystyrene Block Copolymers
Polym. Prepr. (ACS Div. Polym. Chem) 2004, 45, 49
- Chang, Y.; Allcock, H. R.
Synthesis and Characterization of Covalently Interconnected Phosphazene-Silicate Hybrid Network Membranes
Chemistry of Materials 2005, 17, 4449-4454.
- Welna, D. T.; Stone, D.A.; Allcock, H. R.
Synthesis of Cyclotriphosphazene Functionalized Polyoctenamers Via Ring Opening Metathesis Polymerization of Hydrophilic and Hydrophobic Monomers
Polym. Prepr. (ACS Div. Polym. Chem.) 2005, 46(2),1055-1056
- Allcock, H. R.; Welna, D. T.; Stone, D. A.
Synthesis of Pendent Functionalized-Cyclotriphosphazene Polyoctenamers: Amphiphilic Lithium-Ion Conductive Materials
Macromolecules 2005, 38, 10406-10412.
- Singh, A.; Krogman, N. R.; Sethuraman, S.; Nair, L. S.; Sturgeon, J.; Brown, P. W.; Laurencin, C. T.; Allcock, H. R.
Effect of Side Group Chemistry on the Properties of Biodegradable L-alanine Co-Substituted Polyphosphazenes
Biomacromolecules 2006, 7, 914-918
- Stone D. A., Allcock, H. R.
A New Polymeric Intermediate for the Synthesis of Hybrid Inorganic-Organic Polymers
Macromolecules 2006, 39, 4935-4937.
- Conner, D. A.; Welna, D. T.; Chang, Y.; Allcock, H. R.
Influence of Terminal Phenyl Groups on the Side Chains of Phosphazene Polymers: Structure-Property Relationships and Polymer Electrolyte Behavior
Macromolecules 2007, 40, 322-328.
- Welna, D. T.; Stone, D. A.; Allcock, H. R.
Lithium Ion Conductive Polymers as Prospective Membranes in Lithium-Seawater Batteries
Chemistry of Materials 2006, 18, 4486-4492
- Stone, D. A.; Welna, D. T.; Allcock, H. R.
Synthesis and Characterization of Lithium Ion Conductive Membranes with Low Water Permeation
Chemistry of Materials 2007, 19, 2473-2482
- Allcock, H. R.; Cho, S. Y.; Steely, L. B.
New Amphiphilic Poly[bis(2,2,2-trifluoroethoxy)phosphazene]/Poly(propylene-glycol) Triblock Copolymers: Synthesis and Micellar Characteristics
Macromolecules 2006, 39, 8334-8338
- Klein, R.; Welna, D.T.; Weikel, A.; Allcock, H. R.; Runt, J.
Counterion Effects on Ion Mobility Ion Concentration of Doped Polyphosphazenes and Polyphosphazene Ionomers
Macromolecules 2007, 40, 3990-3995
- Cho, S. Y.; Allcock, H. R.
Dendrimers Derived from Polyphosphazene-Poly(propyleneimine) Systems: Encapsulation and Triggered Release of Hydrophobic Guest Molecules
Macromolecules 2007, 40, 3115-3121
- Krogman, N. R.; Steely, L.; Hindenlang, M. D.; Nair, L. S.; Laurencin, C. T.; Allcock, H. R.
Synthesis and Ccharacterization of Phosphazene-Block-Polyester and Poly-phosphazene-Block-Polycarbonates
Macromolecules 2008, 41, 1126-1130
- Chang, Y.; Cho, S. Y.; Steely, L. B.; Allcock, H. R.
Synthesis and Self Association Behavior of Poy[bis(2-(2-methoxyethoxy)-ethoyxy-phosphazene]-b-Poly(propylene-glycol) Triblock Copolymers
- Polym. Sci., Part A, Polym. Chem. 2009, 47, 692-699
- Cho, S.Y.; Allcock, H. R.
Synthesis of Adamantyl Polyphosphazene-Polystyrene Block Copolymers and beta-Cyclodextrin-Adamantyl Side Group Complexation
Macromolecules 2009, 42, 4484-4490
- Chen, C.; Hess, A. R.; Jones, A.; Liu, X.; Barber, G. D.; Mallouk, T. E.; Allcock, H. R.
Quaternization of Poly(aryloxy- and alkoxyphosphazenes)
Macromolecules 2012, 45, 1182-1189
- Liu, X.; Tian, Z.; Chen. C.; Allcock, H. R.
Synthesis and Characterization of Brush-shapred Hybrid Inorganic-Organic Polymers
Macromolecules 2012, 45, 1417-1426
- Tian, Z.; Liu, X.; Chen. C.; Allcock, H. R.
Synthesis and Micellar Behavior of Novel Amphiphilic Poly[bis(trifluoroethoxy)-phosphazene]-co-poly[(dimethylamino)ethyl methacrylate] Block Copolymers
Macromolecules 2012, 45, 2502-2508
- Chen, C.; Liu, X.; Tian, Z.; Allcock, H. R
Trichloroethoxy-Substituted Polyphosphazenes: Synthesis Characterization and Properties
Macromolecules 2012
- Liu, X.; Breon, J.; Chen, C.; Allcock, H. R.
Substituent Exchange Reactions of Linear Oligomeric Aryloxy Phosphazenes with Sodium 2,2,2-Trifluoroethoxide
Inorganic Chemistry, 2012, 51(21), 11910-11916
- Liu, Zhang, H.; Tian, Z.; Sen, A.; Allcock, H. R.
Preparation of Quaternized Organic-Inorganic Hybrid Brush Polyphosphazene-co-poly[2-(dimethylamino-ethyl methacrylate] Elecrospun Fibers and their Anti-bacterial Properties
Polymer Chemisty 2012, 3, 2082-2091
SMALL-MOLECULE MODEL CHEMISTRY
- Kugel, R. L.; Hodgson, W. G.; Allcock, H. R.
The Formation of Radical Anions in Fluorene Metallation
Chem. and Ind. 1962, 1649‑1650.
- Allcock, H. R.
New Reactions of Phosphonitrilic Chloride Trimer. Substitution and Cleavage Reactions with Catechol and Triethylamine
- Am. Chem. Soc. 1963, 85, 4050.
- Reactions of Phosphonitrilic Chlorides with Catechol and Triethylamine
- Am. Chem. Soc. 1964, 86, 2591‑2595.
- Allcock, H. R.; Siegel, L. A.
Molecular Inclusion Compounds of Tris(o‑phenylenedioxy)phosphonitrilic Trimer
- Am. Chem. Soc. 1964, 86, 5140‑5144.
- Allcock, H. R.; Kugel, R. L.
Cyclized Products From the Reactions of Hexachlorocyclotriphosphazene (Phosphonitrilic Chloride Trimer) with Aromatic Dihydroxy, Dithiol, and
Diamino Compounds
Inorg. Chem. 1966, 5, 1016‑10.
- Allcock, H. R.; Kugel, R. L.
Degradation of Halogenophosphazenes to a New Phosphorane System
- Chem. Soc., Chem. Commun. 1968, 24, 1606‑1607.
- Allcock, H. R.; Walsh, E. J.
The Base‑Catalyzed Hydrolysis of Aryloxy‑ and Alkoxycyclophosphazenes
- Am. Chem. Soc. 1969, 91, 3102‑3103.
- Allcock, H. R.; Kugel, R. L.
The Reaction of o‑Aminophenol with Phosphazenes
- Am. Chem. Soc. 1969, 91, 5452‑5456.
- Allcock, H. R.; Birdsall, W. J.
Phosphonitrilic Radical Anions
- Am. Chem. Soc. 1969, 91, 7541‑7542.
- Allcock, H. R.; Walsh, E. J.
The Basic Hydrolysis of Hexakis(aryloxy)cyclotriphosphazenes
- Chem. Soc., Chem. Commun. 1970, 10, 580.
- Allcock, H. R.; Stein, M. T.; Stanko, J. A.
The Crystal and Molecular Structure of Tris(2,2’‑dioxybiphenyl)cyclotri-phosphazene
- Chem. Soc., Chem. Commun. 1970, 15, 944‑945
- Allcock, H. R.; Walsh, E. J.
Synthesis of Spirophosphazenes with Five‑, Six‑, and Seven‑Membered Exocyclic Rings at Phosphorus
Inorg. Chem. 1971, 10, 1643‑1647.
- Allcock, H. R.; Birdsall, W. J.
Electroreduction and Electron Spin Resonance Spectra of Phosphazenes
Inorg. Chem. 1971, 10, 2495‑2499.
- Allcock, H. R.; Stein, M. T.; Stanko, J. A.
The Crystal and Molecular Structure of Tris(2,2’‑dioxybiphenyl)cyclotri‑phosphazene
- Am. Chem. Soc. 1971, 93, 3173‑3178.
- Allcock, H. R.; Walsh, E. J.
The Alkaline Hydrolysis of Fluoroalkoxycyclophosphazenes
- Am. Chem. Soc. 1972, 94, 119‑124.
- Allcock, H. R.; Walsh, E. J.
The Basic Hydrolysis of Aryloxy and Spiroarylene‑dioxycyclophosphazenes
- Am. Chem. Soc. 1972, 94, 4538‑4545.
- Allcock, H. R.; Bissell, E. C.; Shawl, E. T.
The Crystal and Molecular Structure of a New Hexamolybdate‑Cyclophosphazene Complex
Inorg. Chem. 1973, 12, 2963‑2968.
- Allcock, H. R.; Bissell, E. C..
Triethylammonium Tris(o‑phenylenedioxy)phosphate: Crystal and Molecular Structure
- Am. Chem. Soc. 1973, 95, 3154‑3157.
- Allcock, H. R.; Stein, M. T.
Clathration by Tris(2,3‑naphthalenedioxy)cyclotriphosphazene. An X‑ray Crystal and Molecular Structure Study
- Am. Chem. Soc..1974, 96, 49‑52.
- Allcock, H. R.; Stein, M. T.; Bissell, E. C.
A p‑Xylene Clathrate of Tris(1,8‑naphthalenedioxy)cyclotriphosphazene
- Am. Chem. Soc. 1974, 96, 4795‑4800.
- Schmutz, J. L.; Allcock, H. R.
The Reaction of Sodium 2,2,2‑Trifluoroethoxide with Hexachlorocyclotri‑phosphazene
Inorg. Chem. 1975, 14, 2433‑2438.
- Allcock, H. R.; Kugel; R. L.; Moore, G. Y.
Mechanism of the Reactions between o‑Dinucleophiles and Cyclophosphazenes
Inorg. Chem. 1975, 14, 2831‑2837.
- Allcock, H. R.; Smeltz, L. A.
Substituent Exchange and Carbon‑Oxygen Bond Cleavage with Aryloxycyclo‑phosphazenes
- Am. Chem. Soc. 1976, 98, 4143‑4149.
- Allcock, H. R.; Allen, R. W.; Bissell, E. C.; Smeltz, L. A.; Teeter, M.
Molecular Motion and Molecular Separations in Cyclophosphazene Clathrates
- Am. Chem. Soc. 1976, 98, 5120‑5125.
- Allen, R. W.; O’Brien, J. P.; Allcock, H. R.
Crystal and Molecular Structure of a Platinum‑Cyclophosphazene Complex‑‑cis‑Dichloro[octa(methylamino)cyclotetraphosphazene‑N,N’]platinum(II)
- Am. Chem. Soc. 1977, 99, 3987‑3991.
- Avanzino, S. C.; Jolly, W. L.; Schaaf, T. F.; Allcock, H. R.
Core Electron Binding Energies of Cyclotriphosphazenes and Cyclotetra‑phosphazenes
Inorg. Chem. 1977, 16, 2046.
- Harris, P. J.; Allcock, H. R.
Hydridophosphazenes. Synthesis via Organocopper Reagents
- Am. Chem. Soc. 1978, 100, 6512.
- Evans, T. L.; Fuller, T. J.; Allcock, H. R.
The Preparation of [NP(p‑OC6H4Li)2]3 by Metal‑Halogen Exchange, and Its Reactions with Electrophiles
- Am. Chem. Soc. 1979, 101, 242.
- O’Brien, J. P.; Allen, R. W.; Allcock, H. R.
The Crystal and Molecular Structures of Two Cyclophosphazene‑Platinum Compounds: [N4P4(CH3)8PtCl2.CH3CN] and [H2N4P4(CH3)8]2+PtCl42‑
Inorg. Chem.,1979, 18, 2230‑2235.
- Allcock, H. R.; Evans, T. L.
The Partial Aminolysis of (NPF2)3 or 4.
Inorg. Chem. 1979, 18, 2342‑2344.
- Greigger, P. P.; Allcock, H. R.
A Spirocyclophosphazene with Iron‑Phosphorus Bonds and a P‑Fe‑Fe Three‑Membered Ring
- Am. Chem. Soc. 1979, 101, 2492.
- Allcock, H. R.; Harris, P. J.
Formation of Hydridocyclotriphosphazenes Via the Reactions of Organocopper Reagents with Halocyclotriphosphazenes: The Reaction Mechanism
- Am. Chem. Soc. 1979, 101, 6221‑6229.
- Ritchie, R. J.; Harris, P. J.; Allcock, H. R.
The Crystal and Molecular Structure of 1‑Hydrido‑1‑iso‑propyl‑tetrachloro‑cyclotriphosphazene
Inorg. Chem. 1980, 2483‑2486.
- Allcock, H. R.; Evans, T. L.; Fuller, T. L.
Small‑Molecule Cyclic Models for the Synthesis of New Polyphosphazenes: Side Group Construction Via Lithiophenoxy Derivatives
Inorg. Chem. 1980, 19, 1026‑1030
- Ritchie, R. J.; Fuller, T. J.; Allcock, H. R.
The Crystal and Molecular Structure of Hexa(imidazolyl)cyclotriphosphazene
Inorg. Chem. 1980, 19, 3842‑3845.
- Ferrar, W. T.; Distefano, F. V.; Allcock, H. R.
The Thermal Rearrangement of {NP(OCH3)2]3 and 4
Macromolecules 1980, 13, 1345‑1350.
- Allcock, H. R.; Fuller, T. J.; Matsumura, K.
Reactions of Steroid Salts with Hexachlorocyclotriphosphazenes
- Org. Chem. 1981, 46, 13‑22.
- Allcock, H. R.; Scopelianos, A. G.; O’Brien, J. P.; Bernheim, M. Y.
Synthesis and Structure of Carborane‑Substituted Cyclic and Polymeric Phosphazenes
- Am. Chem. Soc. 1981, 103, 350‑357.
- Allcock, H. R.; Harris, P. J.; Connolly, M. S.
Synthesis of Alkylphosphazenes Via Copper‑Phosphazene Intermediates
Inorg. Chem. 1981, 20, 11‑16.
- Allcock, H. R.; Greigger, P. P.; Wagner, L. J.; Bernheim, M. Y.
Synthesis and Molecular Structure of Two Cyclotriphosphazenes with Phosphorus‑Iron Bonds
Inorg. Chem 1981, 21, 716.
- Allcock, H. R.; Fuller, T. J.
The Synthesis and Hydrolysis of Hexa(imidazolyl)cyclotriphosphazenes)
- Am. Chem. Soc. 1981, 103, 2250‑2256.
- Harris, P. J.; Nissan, R. A.; Allcock, H. R.
Organometallic Phosphazenes: Synthesis and Rearrangement of Propynyl and Propadienyl Cyclotriphosphazenes
- Am. Chem. Soc. 1981, 103, 2256‑2261.
- Allcock, H. R.; Harris, P. J.
Synthesis of New 1‑Halo‑1‑alkyltetrachlorocyclotriphosphazenes, Including the First Cyclophosphazenes with a Direct P‑I Bond.
Inorg. Chem. 1981, 20, 2844‑2848.
- Allcock, H. R.; Fuller, T. J.; Matsumura, K.
Hydrolysis Pathways for Aminophosphazenes
Inorg. Chem. 1982, 515‑521.
- Allcock, H. R.; Connolly, M. S.; Harris, P. J.
Reactions of Bi(cyclophosphazenes) with Sodium Alkoxides or Aryloxides
- Am. Chem. Soc.1982, 104, 2482‑2490.
- Suszko. P. R.; Whittle, R. R.; Allcock, H. R.
Synthesis of a Di‑iron‑spirocyclotriphosphazene and a Tri‑iron‑cluster‑cyclotriphosphazene
- Chem. Soc., Chem. Commun. 1982, 649‑650.
- Levin, M. L.; Fieldhouse, J. W.; Allcock, H. R.
Structure of the Triphenylphosphate‑Boron Trichloride Adduct
Acta Cryst. 1982, B38, 2284‑2286.
- Suszko, P. R.; Whittle, R. R.; Allcock, H. R.
Ferrocene‑Bound Cyclophosphazenes
- Chem. Soc., Chem. Commun. 1982, 960‑962.
- Allcock, H. R.; Suszko, P. R.; Evans, T. L.
Phosphazenes with Olefinic Side Groups: Proton Abstraction Reactions of Fluoroalkoxy Derivatives
Organometallics 1982, 1, 1443‑1449.
- Allcock, H. R.; Lavin, K. D.; Tollefson, N. M.; Evans, T. L.
Phosphine‑Linked Phosphazenes as Carrier Molecules for Transition Metals
Organometallics 1983, 2, 267‑275.
- Allcock, H. R.; Scopelianos, A. G.; Whittle, R. R.; Tollefson, N. M.
Cyclic and High Polymeric Carboranyl Phosphazenes as Ligands for Transition Metals
- Am. Chem. Soc. 1983 105, 1316‑1321.
- Allcock, H. R.; Wagner, L. J.; Levin, M. L.
Iron‑ and Ruthenium‑Linked Phosphazenes
- Am. Chem. Soc. 1983, 105, 1321‑1327.
- Allcock, H. R.; Desorcie, J. L.; Harris, P. J.
Mechanism of the Reaction Between Alkyl or Aryl Grignard Reagents and Hexa‑chlorocyclotriphosphazene: An explanation of
Bi(cyclophosphazene) Formation
- Am. Chem. Soc. 1983, 105, 2814‑2819.
- Allcock, H. R.; Connolly, M. S.; Whittle, R. R.
Synthesis of 1‑Halo and 1‑Alkyl‑1‑phenyltetrachlorocyclotriphosphazene Polymerization “Monomers” from Bi(cyclophosphazenes)
Organometallics 1983, 2, 1514‑1523.
- Allcock, H. R.; Lavin, K. D.; Riding, G. H.; Suszko, P. R.; Whittle, R. R.
Synthesis and Structure of Metallocene Cyclophosphazene Derivatives
- Am. Chem. Soc. 1984, 106, 2337‑2347. 133.
- Allcock, H. R.; Nissan, R. A.; Harris, P. J.; Whittle, R. R.
Dicobalt‑Hexacarbonyl Complexes of Acetylenic Phosphazenes
Organometallics 1984, 3, 432‑440.
- Dubois, R. A.; Garrou, P. E.; Lavin, K. D.; Allcock, H. R.
Cobalt‑Mediated Phosphorus‑Aryl Bond Cleavage During Hydroformylation
Organometallics 1984, 3, 649‑650.
- Allcock, H. R.; Lavin, K. D.; Riding, G. H.; Whittle, R. R.
The Reaction of Mono‑ and Dilithioferrocene with Octachlorotetraphosphazene: The Crystal and Molecular Structures of
N4P4Cl6(n‑C5H4)Fe(H‑C5H5)]2 and N3P3Cl4(n‑C5H4)Fe(h‑C5H5)N4P4Cl7
Organometallics 1984, 3, 663‑669.
- Allcock, H. R.; Riding, G. H.; Whittle, R. R.
Chromium‑, Molybdenum‑, and Tungsten‑Chlorophosphazenes: Molecular Structures of N3P3Cl5[Cr(CO)3(H‑C5H5)] and
N3P3Cl4(C5H5)[Mo(CO)3(H‑C5H5)]
- Am. Chem. Soc. 1984 106, 5561‑5567.
- Allcock, H. R.; Suszko, P. R.; Wagner, L. J.; Whittle, R. R.; Boso, B.
Iron‑Containing Metallophosphazenes and their Clusters Derived from Chloro‑phosphazenes and Organometallic Dianions
- Am. Chem. Soc. 1984, 106, 4966‑4977.
- Allccock, H. R.; Suszko, P. R.; Wagner, L. J.; Whittle, R. R.; Boso, B.
Metal Exchange Reactions Under the Influence of a Cyclophosphazene Template: Iron, Cobalt, and Rhodium Metallophosphazenes
Organometallics 1985, 4, 446‑457.
- Allcock, H. R.; Desorcie, J. L.; Wagner, L. J.
Reations Between Alkyl Grignard Reagents and Aminiphosphazenes: Synthesis of Alkyl‑chloro‑cyclotriphosphazenes
Inorganic Chemistry 1985, 24, 333‑340.
- Whittle, R. R.; Desorcie, J. L.; Allcock, H. R.
Structure of 1‑1’‑Dimethyl‑3,3,3’3′,5,5,5′,5’‑octachlorobi(cyclo)phosphazene, [N3P3Cl4CH3]2.
Acta Cryst. 1985, C41, 546‑548.
- Allcock, H. R.; Tollefson, N. M.; Arcus, R. A.; Whittle, R. R.
Conformation, Bonding, and Flexibility in Short‑Chain Linear Phosphazenes
- Am. Chem. Soc. 1985, 107, 5166‑5177.
- Allcock, H. R.; Levin, M. L.; Whittle, R. R.
Tris(o‑phenylenedioxy)cyclotriphosphazene: The Clathration‑Induced Monoclinic to Hexagonal Solid State Transition
Inorganic Chemistry 1986, 25, 41‑47.
- Allcock, H. R.; Lavin, K. D.; Riding, G. H.; Whittle, R. R.; Parvez, M.
Reactions of Ferrocenyl‑ and Ruthenocenylphosphazenes with Lithio‑metallocenes, and the X‑ray Structure s of N3P3F4(H‑C5H4)2Fe,
[N3P3F3‑{(H‑C5H4)2Fe}{(H‑C5H4)Fe(H‑C5H5)}], 1,5‑N4P4F6(H‑C5H4)2Fe, and 1,5,3,7‑N4P4F4[(H‑C5H4)2Ru]2
Organometallics 1986, 5, 1626‑1635.
- Allcock, H. R.; Brennan, D. J.; Graaskamp, J. M.; Parvez, M.
Synthesis and Molecular Structure of Methylsilane‑ and Methylsiloxane‑Cyclotriphosphazenes
Organometallics 1986, 5, 2434‑2446.
- Allcock, H. R.; Mang, M. N.; Riding, G. H.; Whittle, R. R.
The Synthesis and Structure of Transition Metal‑Bound Phosphazenes Derived from Phosphazene Anions
Organometallics 1986, 5, 2244‑2250.
- Riding, G. F.; Parvez, M.; Allcock, H. R.
A Dibenzenechromium‑Bridged Cyclophosphazene: X‑ray Structure Analysis of N3P3F4(H‑C6H5)2Cr
Organometallics 1986, 5, 2153‑2154.
- Rutt, J. S.; Parvez, M.; Allcock, H. R.
Synthesis and Characterization of the First Stable Cyanophosphazenes
- Am. Chem. Soc. 1986, 108, 6089‑6090.
- Allcock, H. R.; Mang, M. N.; McDonnell, G. S.; Parvez, M.
Transition Metal Derivatives of Polyphosphazenes: Syntheses of Poly‑phosphazenes and Cyclic Model Compounds with Iron Cyclopentadienyl
Carbonyl Side Groups
Macromolecules 1987, 20, 2060‑2067.
- Allcock, H. R.; Desorcie, J. L.; Rutt, J. S.
Alkylation of Cyclic and High Polymeric Phosphazenes via Reactions between Aluminum Alkyls and Aminophosphazenes
Organometallics 1988, 7, 612‑619.
- Allcock, H. R.; Brennan, D, J.; Dunn, B. S.; Parvez, M.
Cyclotriphosphazenes with Geminal Trimethylsilylmethylene and Alkyl‑ or Aryl Side Groups
Inorg. Chem. 1988, 27, 3226‑3233.
- Allcock, H. R.; Brennan, D. J.
Organosilicon Derivatives of Cyclic and High Polymeric Phosphazenes
- Organomet. Chem., 1988, 341, 231‑239.
- Manners I.; Coggio, W. D.; Mang, M. N.; Parvez, M.; Allcock, H. R.
Isolation and X‑Ray Crystal Structure of a Phosphazene Anion
- Am. Chem. Soc. 1989, 111, 3481‑3482.
- Welker, M. F.; Manners, I.; Parvez, M.; Allcock, H. R.
Synthesis and Structure of the First Borazinylcyclotriphosphazene
- Chem. Soc. Chem. Commun. 1989, 871‑872.
- Allcock, H. R.; Manners, I.; Mang, M. N.; Parvez, M.
Transition Metal Derivatives of Phosphinophosphazenes: X‑Ray Crystal Structures of N3P3Cl4PhPPh2, N3P3Cl4PhPPh4.Cr(CO)5, and N3P3Cl4PhPPh2.Ru3(CO)11
Inorganic Chemistry 1990, 29, 522‑529.
- Brennan, D. J.; Graaskamp, J.; Dunn, B. S.; Allcock, H. R.
Organosilicon Derivatives of Cyclic and High Polymeric Phosphazenes
Inorg. Syntheses. 1989, 25, 60‑68.
- Allcock, H. R.; Coggio, W. D.; Parvez, M.; Turner, M. L.
New Cyclic Phosphazenes with Trimethylsilylmethyl Side Groups: X‑ray Crystal Structure of [NP(CH2SiMe3)2]3, and its Conversion to
(NPMe2)3
Organometallics 1991, 10, 677‑683.
- Allcock, H. R.; Ngo, D. C.; Parvez, M.; Whittle, R. R.; Birdsall, W. J.
Syntheses and Structures of Cyclic and Short Chain Linear Phosphazenes Bearing 4‑Phenylphenoxy Side Groups
- Am. Chem. Soc. 1991, 113, 2628‑2634.
- Allcock, H. R.; Rutt, J. S.; Welker, M. F.; Parvez, M.
Cyanophosphazene Small Molecules and High Polymers: Synthesis and Structure
Inorganic Chemistry 1993, 32, 2315‑2321.
- Allcock, H. R.; Rutt, J. S.; Parvez, M.
Synthesis of Cyclic Phosphazenes with Isothiocyanato, Thiourea, and Thiourea Side Groups: X‑ray Crystal Structure of N3P3(NMe2)3(NCS)3
Inorganic Chemistry 1991, 30, 1776‑1782.
- Allcock, H. R.; Dembek, A. A.; Bennett, J. L.; Manners, I.; Parvez, M.
Synthesis and Structure of Phosphazene (H6‑Arene)chromium Tricarbonyl Derivatives
Organometallics 1991, 10, 1865‑1874.
- Allcock, H. R.; Coggio, W. D.; Manners, I.; Parvez, M.
Synthesis, Reactivity, and the Electronic Structures of Fluoro‑ and Hydrido-Phosphazene Anions: X‑ray Crystal Structure of
[Li(THF)3][N3P3F2H(BEt3) (h‑C5H4)2Fe]
Organometallics 1991, 10, 3090‑3098.
- Allcock, H. R.; Dodge, J. A.; Manners, I.; Parvez, M.; Riding, G. H.; Visscher, K. B.
Synthesis of Strained Ferrocenylorganocyclophosphazenes. X‑ray Crystal Structures of N3P3(OCH2CF3)4(h‑C5H4)2Fe,
N3P3(OPh)4(h‑C5H4)2Fe, and N3P3Ph2(OCH2)(h‑C5H4)2Fe
Organometallics 1991, 10, 3098‑3104.
- Allcock, H. R.; Ngo, D. C.; Parvez, M.; Visscher, K.
Synthesis and Structures of Para‑Halogenophenoxy Phosphazenes: A Comparison of the Structures of Cyclic and Linear‑Short‑Chain Species.
Inorganic Chemistry 1994, 24, 5208-5214.
- Allcock, H. R.; Dembek, A. A.; Klingenberg, E. H.
Synthesis and Characterization of Polyphosphazene (h6‑Arene)chromium Tricarbonyl Derivatives
Macromolecules 1991, 24, 5208‑5214.
- Allcock, H. R.; Dembek, A. A.; Mang, M. N.; Riding, G. H.; Parvez, M.; Visscher, K.B.
Synthesis and Structure of Small‑Molecule Cyclic Phosphazenes Bearing Ortho‑Substituted Aryloxy and Phenoxy Substituents
Inorganic Chemistry 1992, 31, 2734‑2739.
- Allcock, H. R.; Nelson, C. J.; Coggio, W. D.
Synthesis and Reactivity of Cyclotriphosphazenes Bearing Reactive Silane Functionalities: Novel Derivatives via Hydrosilylation Reactions
Organometallics 1991, 19, 3819‑3825.
- Allcock, H. R.; Fitzpatrick, R. J.
Sulfonation of Aryloxy‑ and Arylamino‑Phosphazenes: Small‑Molecule Compounds, Polymers, and Surfaces
Chemistry of Materials 1991, 3, 1120‑1132.
- Allcock, H. R.; Ngo, D. C.; Parvez, M.; Visscher, K.
The Synthesis and Molecular Structures of Cyclic and Short‑Chain Linear Phosphazenes Bearing the o‑Dichlorophenoxy and o‑Dimethylphenoxy
Side Groups
- Chem. Soc. 1992 10, 1687‑1699.
- Allcock, H. R.; Turner, M. L.; Visscher, K. B.
Synthesis of Transannular and Spiro‑Substituted Cyclotriphosphazenes X‑ray Crystal Structures of 1,1‑[N3P3(OCH2CF3)4{O2C12H8}],
1‑3‑[N3P3(OCH2CF3)4{O2C12H8}], 1,1‑[N3P3(OCH2CF3)4{O2C10H6}], and 1,3‑[N3P3(OCH2CF3)4{O2C10H6}]
Inorganic Chemistry 1992, 31, 4354‑4364.
- Allcock, H. R.; Diefenbach, U.; Pucher, S. R.
New Mono‑ and Trispiro‑Cyclotriphosphazenes from the Reactions of (NPCl2)3 With Aromatic Ortho‑Dinucleophiles
Inorg. Chem. 1994, 33, 3091-3095.
- Allcock, H. R.; Klingenberg, E. H.; Welker, M. F.
Alkylsulfonation of Cyclic and High Polymeric Phosphazenes
Macromolecules 1993, 26, 5512‑5516.
- Allcock, H. R.; Silverberg, E. N.; Nelson, C. J.; Coggio, W. D.
Synthesis and Characterization of Metallophosphazene Derivatives: Solution State And Surface Reactions.
Chem. Mater. 1993, 5, 1307‑1314.
- Diefenbach, U.; Allcock, H. R.
Synthesis of Cyclo‑ and Polyphosphazenes with Pyridine Side Groups
Inorganic Chemistry 1994, 33, 4562-4565.
- Allcock, H. R.; Kuharcik, S. E.; Visscher, K. B.; Ngo, D. C.
Molecular Structures of Cyclic Mono- and Diphosphazophosphazenes: Small Molecule Models for High Polymers
- Chem. Soc. (Dalton) 1995, 2785-2795.
- Diefenbach, U.; Allcock, H. R.; Visscher, K. B.
The Structure of an Inorganic Spiro-cyclotriphosphazene with 9,10-Diaminophenanthrene
Acta Cryst. 1995, C51, 1215-1218.
- Allcock, H. R.; Al-Shali, S.; Ngo, D. C.; Visscher, K. B.; Parvez, M.
Small-Molecule Phosphazenes with Para Substituted Phenoxy Side Groups: Synthesis, X-ray Structures and Comparisons with the
Corresponding High Polymer
- Chem. Soc. (Dalton)1996, 3549-3559.
- Mack, L. L.; Fitzpatrick, R. J.; Allcock, H. R.
Hydrophobicity, Hydrophilicity, and Amphiphilicity in Phosphazene Small Molecules and High Polymers: Langmuir-Blodgett Studies
Langmuir, 1997, 13, 2123-2132.
- Allcock, H. R.; Brennan, D. J.; Whittle, R. R.
The Synthesis and Structure of Triphenylsiloxycyclotriphosphazenes
Heteroatom Chemistry 1996, 7, 67-95.
- Primrose, A. P., Parvez, M.; Allcock, H. R.
Inclusion Adduct Formation Between Tris(o-phenylenedioxy)cyclo- and Poly(ethylene oxide) or Polyethylene
Macromolecules 1997, 30, 670-672.
- Allcock, H. R.; Crane, C. A.; Morrissey, C. T.; Olshavsky, M. A.
A New Route to the Phosphazene Polymerization Precursors, Cl3P=NSiMe3 and (NPCl2)3
Inorganic Chemistry 1999, 38, 280-283.
- McIntosh, M. B.; Hartle, T. J.; Allcock, H. R.
Synthesis and Reactivity of Alkoxy, Aryloxy, and Dialkylamino Phosphazene Azides
- Am. Chem. Soc.1999, 121, 884-885.
- Allcock, H. R.; Sunderland, N. J.; Primrose, A. P.; Rheingold, A. L.; Guzei, I. A.; Parvez, M.
A New Host for Polymer and Small-Molecule Clathration
Chemistry of Materials 1999, 11, 2478-2485.
- Allcock, H. R.; McIntosh, M. B.; Hartle, T. J.
Azido Phosphazenes as Functionalized Intermediates
Inorganic Chemistry 1999, 38, 5535-5544.
- Allcock, H. R.; Primrose, A. P.; Silverberg, E. N.; Visscher, K. B.; Rheingold, A. L.; Guzei, I. A.; Parvez, M.
Synthesis and Crystal Structure of Tris(9,10-phenanthrenedioxy)cyclotri-phosphazene – A New Clathration System
Chemistry of Materials 2000, 12, 2530-2536.
- Allcock, H. R.; Sunderland, N. J.
Separation of Polymers and Small Molecules by Crystalline Host Systems
Macromolecules 2001, 34, 3069-3076.
- Allcock, H. R.; Hofmann, M. A.; Wood, R. M.
Phosphonation of Aryloxyphosphazenes
Macromolecules 2001, 34, 6915-6921.
- Allcock H. R.; Kellam, E. C.
The Incorporation of Cyclic Phosphazene Trimers into Saturated and Unsaturated Ethylene-Like Polymer Backbones
Macromolecules 2002, 35, 40-47.
- Hofmann, M. A.; Ambler, C. M.; Maher, A. E.; Chalkova, E.; Zhou, X. Y.; Lvov, S. N.; Allcock, H. R.
Synthesis of Polyphosphazenes with Sulfonimide Side Groups
Macromolecules 2002, 35, 6490-6493.
- Allcock, H. R.; Hofmann, M. A.; Ambler, C. M.; Morford, R. V.
Phenylphosphonic Acid Functionalized Poly[aryloxyphosphazenes]
Macromolecules 2002, 35, 3483-3489.
- Allcock, H. R.; Chang, Y.; Stone, D. A.
Control of the Conjugation Length and Solubility in Electroluminescent Polymers
- Polymer Science 2006, 44, 69-76.
- Stone D. A., Allcock, H. R.
A New Polymeric Intermediate for the Synthesis of Hybrid Inorganic-Organic Polymers
Macromolecules 2006, 39, 4935-4937.
- Fushimi, T.; Allcock, H. R.
Cyclotriphosphazenes with Sulfur-Containing Side Groups: Refractive Index and Optical Dispersion
Royal. Soc. Chem., Dalton Trans. 2009, 14, 2477-2481
- Liu, X.; Breon, J. P.; Chen, C.; Allcock, H. R.
Substituent Exchange Reactions of Trimeric and Tetrameric Aryloxycyclo-phosphazenes with Sodium 2,2,2-Trifluoroethoxide
Royal Soc. Chem., Dalton Trans. 2012, 41, 2100-2109
- Liu, X.; Breon, J.; Chen. C.; Allcock, H. R.
Substituent Exchange Reactions of Linear Oligomeric Aryloxy Phosphazenes with 2,2,2-Trifluoroethoxide
Inorganic Chemistry 2012, 51(21), 11910-11916
PUBLICATIONS ON BIOMEDICAL MATERIALS
- Allcock, H. R.; Allen, R. W.; O’Brien, J. P.
Antitumor Agents Synthesized from K2PtCl4 and Polymeric or Cyclic Phosphazenes
- Chem. Soc., Chem. Commun.1976, 717‑718.
- Allcock, H. R.; Allen, R. W.; O’Brien, J. P.
Synthesis of Platinum Derivatives of Polymeric and Cyclic Phosphazenes
- Am. Chem. Soc.1977, 99, 3984‑3987.
- Allcock, H. R.; Fuller, T. J.; Mack, D. P.; Matsumura, K.; Smeltz, K. M.
Synthesis of Poly[(amino acid alkyl ester)phosphazenes]
Macromolecules 1977, 10, 824‑830.
- Allcock, H. R.
Poly(organophosphazenes) Designed for Biomedical Uses
Organometallic Polymers, Academic Press, 1978, 283‑288.
- Allcock, H. R.; Greigger, P. P.; Gardner, J. E.; Schmutz, J. L.
Water‑Soluble Polyphosphazenes as Carrier Molecules for Iron(III) and Iron(II) Porphyrins
- Am. Chem. Soc.1979, 101, 606‑611.
- Allcock, H. R.; Fuller, T. J.; Matsumura, K.
Reactions of Steroid Salts with Hexachlorocyclotriphosphazenes
- Org. Chem.1981, 46, 13‑22.
- Allcock, H. R.; Fuller, T. J.
The Synthesis and Hydrolysis of Hexa(imidazolyl)cyclotriphosphazenes)
- Am. Chem. Soc.1981, 103, 2250‑2256.
- Allcock, H. R.; Austin, P. E.
Schiff’s‑Base Coupling of Cyclic and High Polymeric Phosphazenes to Aldehydes and Amines: Chemotherapeutic Models
Macromolecules 1981, 14, 1616‑1622.
- Allcock, H. R.; Fuller, T. J.; Matsumura, K.
Hydrolysis Pathways for Aminophosphazene
Inorganic. Chemistry. 1982, 515‑521.
- Allcock, H. R.; Austin, P. E.; Neenan, T. X.
Phosphazene High Polymers with Bioactive Substituent Groups: Prospective Anesthetic Aminophosphazenes
Macromolecules 1982, 15, 689‑693.
- Allcock, H. R.; Neenan, T. X.; Kossa, W. C.
Coupling of Cyclic and High Polymeric Aminoaryloxyphosphazenes to Carboxylic Acids: Prototypes for Bioactive Polymers
Macromolecules 1982, 15, 693‑696.
- Neenan, T. X.; Allcock, H. R.
Synthesis of a Heparinized Poly(organophosphazene)
Biomaterials 1982, 3, 2, 78‑80.
- Allcock, H. R.; Scopelianos, A. G.
Synthesis of Sugar‑Substituted Cyclic and Polymeric Phosphazenes, and their Oxidation, Reduction, and Acetylation Reactions
Macromolecules 1983, 16, 715‑719.
- Allcock, H. R.; Hymer, W. C.; Austin, P. E.
Diazo Coupling of Catecholamines with Poly(organophosphazenes).
Macromolecules 1983, 16, 1401‑1406.
- Allcock, H. R.
A New Approach to Polymer Chemistry: Organometallic and Bioactive Phosphazenes
- Polym. Sci., Polym. Symp. 1983, Vol. 70, 71‑77.
- Allcock, H. R.; Neenan, T. X.; Boso, B.,
Synthesis, Oxygen-Binding Behavior, and Mossbauer Spectroscopy of Covalently Bound Phosphazene-Heme Complexes
Inorganic. Chemistry. 1985, 24, 2656-2662.
- Allcock, H. R.; Austin, P. E.; Neenan, T. X.; Sisko, J. T.; Blonsky, P. M.; Shriver, D. F.
Polyphosphazenes with Etheric Side Groups: Prospective Biomedical and Solid Electrolyte Polymers
Macromolecules 1986, 19, 1508‑1512.
- Allcock, H. R.; Kwon, S.
Covalent Linkage of Proteins to Surface‑Modified Poly(organophosphazenes): Immobilization of Glucose‑6‑Phosphate Dehydrogenase and
Trypsin
Macromolecules 1986, 19, 1502‑1508.
- Laurencin C.; Koh, H. J.; Neenan, T. X.; Allcock, H. R.; Langer, R. S.
Controlled Release Using a New Bioerodible Polyphosphazene Matrix System
- Biomed. Mater. Res. 1987, 21, 1231‑1246.
- Allcock, H. R.; Gebura, M.; Kwon, S.; Neenan, T. X.
Amphiphilic Polyphosphazenes as Membrane Materials: Influence of Side Group on Radiation Crosslinking, Semipermeability, and Surface
Morphology
Biomaterials 1988, 19, 500‑508.
- Allcock, H. R.; Kwon, S.
Glyceryl Polyphosphazenes: Synthesis, Properties, and Hydrolysis
Macromolecules 1988, 21, 1980‑1985.
- Allcock, H. R.; Kwon, S.; Riding, G. H.; Fitzpatrick, R. J.; Bennett, J. L.
Hydrophilic Polyphosphazenes as Hydrogels: Radiation Crosslinking and Hydrogel Characteristics of Poly[bis(methoxyethoxyethoxy)phosphazene]
Biomaterials 1988, 19, 509‑513.
- Allcock, H. R.; Kwon, S.
An Ionically‑Crosslinkable Polyphosphazene: Poly[di(carboxylatophenoxy‑phosphazene] and its Hydrogels and Membranes
Macromolecules 1989, 22, 75‑79.
- Allcock, H. R.
Polyphosphazenes as New Biomedical and Bioactive Materials
Chapter in Biodegradable Polymers as Drug Delivery Systems, (R. Langer and M. Chasin, eds),
Marcel Dekker: New York 1990, 163‑193.
216 Allcock, H. R.; Chang, Ji Young
Poly(organophosphazenes) with Oligopeptides as Side Groups: Prospective Biomaterials
Macromolecules 1991, 24, 993‑999.
- Allcock, H. R.; Pucher, S. R.
Polyphosphazenes with Glucosyl‑ and Methylamino‑, Trifluoroethoxy‑, Phenoxy‑, Or Methoxyethoxyethoxy Side Groups
Macromolecules 1991, 24, 23‑34.
- Bano, M. C.; Cohen S.; Visscher, K. B.; Allcock, H. R.; Langer, R.
A Novel Synthetic Method for Hybridoma Cell Encapsulation
Biotechnology 1991, 9, 468‑471.
- Allcock, H. R.; Rutt, J. S.; Fitzpatrick, R. J.
A Surface Reaction of Poly[bis(trifluoroethoxy)phosphazene] Films by Basic Hydrolysis
Chemistry of Materials 1991, 3, 442‑449.
- Allcock, H. R.; Fitzpatrick, R. J.
Functionalization of the Surface of Poly[bis(trifluoroethoxy)phosphazene] by Reactions with Alkoxide Nucleophiles
Chemistry of Materials 1991, 3, 450‑454.
- Allcock, H. R.; Pucher, S. R.; Fitzpatrick, R. J.
Antibacterial Activity and Mutagenicity Studies of Water‑soluble Phosphazene High Polymers
Biomaterials 1992 13, 857‑862.
- Nelson, C. J.; Coggio, W. D.; Allcock, H. R.
Ultraviolet Radiation‑Induced Crosslinking of Poly[bis(2‑(2‑methoxyethoxy)ethoxy)phosphazene]
Chemistry of Materials 1991, 3, 786‑787.
- Cohen, S.; Bano, M. C.; Cima, L. G.; Allcock, H. R.; Vacanti, J. P.; Vacanti, C. A.; Langer R.
Design of Synthetic Polymeric Structures for Cell Transplantation and Tissue Engineering
Clinical Materials 1993, 13, 3‑10.
- Allcock, H. R.; Pucher, S. R.; Turner, M. L.; Fitzpatrick, R. J.
Poly(organophosphazenes) with Poly(alkyl ether) Side Groups: A Study of Their Water‑Solubility and the Swelling Characteristics of Their
Hydrogels
Macromolecules 1992, 25, 5573‑5577.
- Allcock, H. R.; Fitzpatrick, R. J.; Visscher, K.
Thin Layer Grafts of Poly[bis(methoxyethoxyethoxy)phosphazene] on Organic Polymer Surfaces
Chemistry of Materials 1992, 4, 775‑780.
- Pucher, S. R.; Allcock, H. R.
Poly[(amino acid ester)phosphazenes]: Bioerodible Substrates for Controlled Drug Delivery
Polym. Prepr. (ACS Div. Polym. Chem.) 1992, 33, 108‑109.
- Laurencin, C. A.; Norman, M. E.; Elgendy, H. M.; El‑Amin, S. F.; Allcock, H. R.; Pucher, S. R.; Ambrosio, A. A.
Use of Polyphosphazenes for Skeletal Tissue Regeneration
- Biomed. Mater. Res. 1993, 27, 963‑973.
- Andrianov, A.; Cohen, S.; Langer, R.; Visscher, K. B.; Allcock, H. R.
Controlled Release Using Ionotropic Polyphosphazene Hydrogels
- Controlled Release 1993, 27, 69‑77.
- Cohen, S.; Allcock, H. R.; Langer, R.
Cell and Enzyme Immobilization in Ionotropic Synthetic Hydrogels
Minutes (Editions de Sante, France) 1993, 36-48.
- Allcock, H. R.; Pucher, S. R.; Visscher, K. B.
The Activity of Urea Amidohydrolase Immobilized Within Poly[di(methoxyethoxyethoxy)phosphazene] Hydrogels
Biomaterials 1994, 15, 502-506.
- Allcock, H. R.; Pucher, S. R.; Scopelianos, A. G.
Poly[amino acid ester)phosphazenes] as Substrates for the Controlled Release of Small Molecules
Biomaterials 1994, 15, 563-569.
- Allcock, H. R.; Pucher, S. R.; Scopelianos, A. G.
Synthesis of Poly(organophosphazenes) with Glycolic Acid Ester and Lactic Acid Ester Side Groups: Prototypes for New Bioerodible Polymers
Macromolecules 1994, 1, 1‑4.
- Allcock, H. R.; Pucher, S. R.; Scopelianos, A. G.
Poly[(amino acid ester)phosphazenes]: Synthesis, Crystallinity, and Hydrolytic Sensitivity in Solution and the Solid State
Macromolecules 1994, 27, 1071‑1075.
- Allcock, H. R.; Nelson, C. J.; Coggio, W. D.
Photoinitiated Graft Poly(organophosphazenes): Functionalized Immobilization Substrates for the Binding of Amines, Proteins, and Metals
Chemistry of Materials 1994, 6, 516‑524
- Allcock, H. R.
Water‑Soluble Polymers and their Hydrogels
Chapter in Hydrophilic Polymers (J. E. Glass, ed.)
ACS Symp. Ser. 1996, 248, 3-29.
- Allcock, H. R.
Cross‑Linking Reactions for the Conversion of Polyphosphazenes into Useful Materials
Chemistry of Materials Review 1994, 6, 1476-1491.
- Andrianov, A. K.; Payne, L. G.; Visscher, K. B.; Allcock, H. R.; Langer, R.
Hydrolytic Degradation of Ionically Cross‑Linked Polyphosphazene Microspheres
- Appl. Polym. Sci. 1994, 53, 1573-1578.
- Ten Huisen, K. S.; Brown, P. W.; Reed, C. S.; Allcock, H. R.
Low Temperature Synthesis of a Self-Assembling Composite: Hydroxyapatite Poly[bis(sodium carboxylatophenoxy)phosphazene]
- Mater. Sci., Mater. Med. 1996, 7, 673-682.
- Reed, C. S.; TenHuisen, K. S.; Brown, P. W.; Allcock, H. R.
Thermal Stability and Compressive Strength of Calcium Deficient Hydroxyapatite Poly[bis(Carboxylatophenoxy)phosphazene] Composites
Chemistry of Materials 1996, 8, 440-447.
- Allcock, H. R.; Dudley, G. K.
Lower Critical Solubility Temperature Study of Alkyl Ether-Based Polyphosphazenes
Macromolecules 1996, 29, 1313-1319.
- 339. Ibim, S. M.; Ambrosio, A.; Larrier, D.; Allcock, H. R.; Laurencin, C.
The Controlled Macromolecular Release from Polyphosphazene Matrices
- Control. Release 1996, 40, 31-39.
- Laurencin, C. T.; El-Amin, S. F.; Ibim, S. E.; Willoughby, D. A.; Attawia, M.; Ambrosio, A. M. A.; Allcock, H. R.
A Highly Porous 3-Dimensional Polyphosphazene Polymer Matrix for Skeletal Tissue Regeneration
- Biomed. Mater. Res. 1996, 303, 133-138.
- Allcock, H. R.; Ambrosio, A. M. A.
Synthesis and Characterization of pH-Sensitive Poly(organophosphazene) Hydrogels
Biomaterials 1996, 17, 2295-2302.
- Allcock, H. R.
Design and Synthesis of New Biomaterials via Macromolecular Substitution
Chapter in Bioartificial Organs (A. Prokop, D. Hunkler, A. Cherrington, eds.)
Annals of the New York Academy of Sciences 1997, 831, 13-31.
- Ibim, S. E. M.; Ambrosio, A. M. A.; Kwon, M. S.; El-Amin, A. F.; Allcock, H. R.; Laurencin, C. T.
Novel Polyphosphazene Polyphosphazene/Poly(lactide-co-glycolide) Blends: Miscibility and Degradation Studies
Biomaterials 1998, 18, 1565-1569.
- Laurencin, C. T.; Ambrosio, A. M. A.; Attawia, M. A.; Ibim, S. E. M.; Allcock, H. R.; Ulrich, K. E.
Biodegradable Polyphosphazenes and Poly(anhydride-co-imides) for Controlled Drug Delivery and Skeletal Repair
Proc. 1997 Portlland Bone Symp. 1998, 490-518.
- Ibim, S. M.; El-Amin, S. F.; Goad, M. E. P.; Ambrosio, A. M. A.; Allcock, H. R.
In Vitro Release of Colchicine Using Polyphosphazenes: The Development of Delivery Systems for Musculoskeletal Use
Pharmaceutical Development and Technology 1998, 3(1), 55-62.
- Laurencin, C. T.; Ibim, S. E. M.; Allcock, H. R.; Ambrosio, A. M. A.; El-Amin, S.; Kwon, M. S.
Biodegradable Polyphosphazene/poly(lactide-co-Glycolide) Blends
Bioact. Mater. 1997, 24, 971-972.
- Laurencin, C. T.; Ambrosio, A. M. A.; Bauer, T. W.; Allcock, H. R.; Attawia, M. A.; Borden, M. D.; Gorum, W. J.; Frank, D.
The Biocompatibility of Polyphosphazenes: Evaluation in Bone
Soc. of Biomaterials 1998, 436.
- Laurencin C. T.; Ambrosio, A. M. A.; Bauer, T. W.; Allcock, H. R.; Attawia, M. A.; Borden, M. D.; Gorum, W. J.; Frank, D.
Histiological Evaluation of Polyphosphazene Matrices in a Rabbit 5 mm Bone Defect Model
Society of Biomaterials
- Allcock, H. R.
Inorganic-Organic Polymers as a Route to Biodegradable Polymers
Intern. Conf. on Biodegradable Polymers, Stockholm,1998
Macromol. Symp. 2000, 144, 33-46
- Chang, Y.; Lee, S. C.; Kim, C.; Reeves, S. D.; Allcock, H. R.
Synthesis and Micellar Characterization of an Amphiphilic Diblock Copolyphosphazene
Macromolecules 2001, 34, 269-274.
- Allcock, H. R.; Singh, A.; Ambrosio, A. M. A.; Laredo, W. R.
Tyrosine-Bearing Polyphosphazenes
Biomacromolecules 2003, 4, 1646-1653.
- Kim, C.; Chang, Y.; Lee, S. C.; Allcock, H. R.; Reeves, S. D.
An Amphiphilic Diblock Copolyphosphazene: Synthesis and Micellar Characeristics in the Aqueous Phase.
Polym. Prepr. ACS Div. Polym. Chem. 2000, 41, 609-610.
- Allcock, H. R.
Rational Design and Synthesis of Polyphosphazenes for Tissue Engineering
Chapter in “Methods of Tissue Engineering” (A. Atala, R. Lanza, eds.)
Academic Press 2001, 597-607.
- Allcock, H. R.; Ambrosio, A. M. A.
Synthesis and Characterization of pH-Responsive Poly(organophosphazene) Hydrogels
Chapter in Polymer Gels (H. B. Bohidar, P. L. Dubin, eds.)
ACS Symp. Ser. 2002, 833, 82-101.
- Ambrosio, A. M. A.; Allcock, H. R.; Laurencin, C. T.
Degradable Polyphosphazene/Polyester Blend with Self-Neutralizing Potential
Proc. Soc. for Biomaterials 1999, 25, 9.
- Ambrosio, A. M. A.; Allcock, H. R.; Katti, D. S.; Laurencin, C. T.
Degradable Polyphosphazene/poly( hydroxyester) Blends: Degradation Studies
Biomaterials 2002, 23, 1667-1672.
- Chang, Y.; Bender, J. D.; Phelps, M. V. B.; Allcock, H. R.
Synthesis and Self-Association Behavior of Biodegradable Amphiphilic Poly[bis(ethyl glycinat-N-y)phosphazene]-PEO Block Copolymers
Biomacromolecules 2002, 3, 1364-1369.
- Chang, Y.; Powell, E. S.; Allcock, H. R.; Park, S. M.; Kim, C.
Thermosensitive Behavior of Poly[bis(methoxyethoxyethoxy)- phosphazene]-Poly(ethylene oxide) Block Copolymers
Macromolecules 2003, 36, 2568-2570.
- Chang, Y.; Prange, R.; Allcock, H. R.; Lee, S. C.; Kim, C.
Amphiphilic Poly[bis(trifluoroethoxy)phosphazene]-Poly(ethylene oxide) Block Copolymers: Synthesis and Micellar Characteristics
Macromolecules 2002, 35, 8556-8559.
- Greish, Y. E.; Brown, P. W.; Bender, J. D.; Allcock, H. R.; Laurencin, C. T.
Formation of Hydroxyapatite-poly[bis(calcium carboxylatophenoxy)phosphazene] Composites at Physiological Temperature
- Biomed. Mater. Res.2006, 77A, 416-425.
- Lakshmi, S.; Lee, D.; Bender, J. D.; Barrett, E. W.; Greish, Y. E.; Brown, P. W.; Allcock, H. R.; Laurencin, C. T.
Synthesis, Characterization and in vitro Osteocompatibility Evaluation of Novel Biodegradable Poly(ethyl alanato)(alkyl
oxybenzoate)phosphazenes]
Journal of Biomaterials Research 2006, 76A, 206-213.
- Lakshmi, S.; Lee, D. A.; Bender, J. D.; Allcock, H. R.; Laurencin, C. T.
In Vitro Evaluation of Novel Biodegradable Polyphosphazenes for Bone Tissue Engineering
Proc. Annual Mtg. of Orthopaedic Res. Soc. 2003, 937.
- Greish, Y. E.; Bender, J. D.; Lakshmi, S.; Brown, P. W.; Allcock, H. R.; Laurencin, C. T.
Low Temperature Formation on Hydroxyapatite-poly(alkyloxybenzoate)phosphazene Composites for Biomedical Applications
Biomaterials 2004, 26, 1-9.
- Bhattacharyya, S.; Lakshmi, S.; Bender, J. D.; Greish, Y. E.; Brown, P. W.; Allcock, H. R.; Laurencin, C. T.
Preparation of Poly[bis(carboxylato phenoxy)phosphazene] Non-Woven Nanofiber Mats by Electrospinning
Proc. Mat. Res. Soc. (Plant, A.; Chilkoti, A.; Barron. A. E. ; Wong, J., eds.) 2004, F8.10, 157-163.
- Chang, Y.; Powell, E. S.; Allcock, H. R.
Environmentally Induced Morphological Changes in Micellar Aggregates of Polystyrene-Poly[bis(carboxylatophenoxy)phosphazene] Block Copolymers
- Polymer Sci.2005, 43, 2912-2920.
- Allcock, H. R.; Powell, E. S.; Chang, Y.; Kim, C.
Synthesis and Micellar Behavior of Amphiphilic Polystyrene Poly[bis(methoxyethoxyethoxy)phosphazene] Block Copolymers
Macromolecules 2004, 37, 7163-7167.
- Allcock, H. R.; Welna, D. T.; Maher, A. E.
Single Ion Conductors: Polyphosphazenes with Sulfonimide Functional Group
Solid State Ionics 2006, 177, 741-747.
- Nair, L.; Bhattacharyya, S.; Bender, J. D.; Greish, Y. E.; Brown, P. W.; Allcock, H. R.; Laurencin, C. T.
Fabrication and Optimization of Methylphenoxy Substituted Polyphosphazene Nanofibers for Biomedical Applications
Biomacromolecules 2004, 5, 2212-2220.
- Silva, R.; Gaumond R.; Phelps, M. V.; Allcock, H. R.; Vasudevan, N.
Neuroblastoma Biosensor System Proc.
IEEE Ann. N.E. Bioeng. Conf. 2004, 110-111.
- Phelps, M. V. B.; Allcock, H. R.
Synthesis of a Polyphosphazene Bearing Aryloxy Carboxylic Acid, Amino Acid Ester, and Alkyl Ether Side Groups for Sustained Release
Applications
Polym. Prepr. (Am. Chem. Soc. Div. Polym. Chem.) 2004, 91, 550-551
- Singh, A.; Laredo, W.; Allcock, H. R.
Synthesis and Characterization of L-Tyrosine-Functionalized Polyphosphazenes
Polym. Prepr. (Am. Chem. Soc. Div. Polym. Chem.) 2004, 45, 703-704.
- Barrett, E. W.; Phelps, M. V. B.; Allcock, H. R.; Silva, R. J.; Gaumond, R. P.
Microcontact Printing of Poly(organophosphazenes): Potential Applications for Selective Cell Adhesion
PMSE Prepr. (Amer. Chem. Soc. Div. Poly. Mater. Sci. Eng.) 2004, 91, 633-634.
- Greish, Y. E.; Brown, P. W.; Bender, J. D.; Allcock, H. R.; Lakshmi, S.; Laurencin, C. T.
Kinetics and Chemistry Formulation of Stoichiometric Hydroxyapatite- Polyphosphazene Composites at and near Physiologic Temperature
- Amer. Ceram. Soc. (submitted)
- Greish, Y. E.; Brown, P. W.; Bender, J. D.; Allcock, H. R.; Laurencin, C. T.
Low Temperature Reaction between Stoichiometric Hydroxyapatite and Sodium and Potassium Salts of
Poly[bis(carboxylatophenoxy)phosphazenes]
- Mater. Sci., Mater. Med. 2005, 16, 613-620
- Chang, Y.; Allcock, H. R.
Synthesis and Characterization of Covalently Interconnected Phosphazene Silicate Hybrid Network Membranes
Chemistry of Materials 2005, 17, 4449-4454.
- Barrett, E. W.; Phelps, M. V. B.; Silva, R. J.; Gaumond, R. P.; Allcock, H. R.
Patterning Poly(organophosphazenes) for Selective Cell Adhesion Applications
Biomacromolecules 2005, 6, 1689-1698.
- Allcock, H. R.; Phelps, M. V. M.; Barrett, E. W.; Pishko, M, V.; Koh, W.-G.
Ultraviolet Phtolithigraphic Development for Polyphosphazene Hydrogel Micro-structures for Potential Use in Microarray Biosensors
Chemistry of Materials 2006, 181, 609-613
- Greish, Y. E.; Bender, J. D.; Lakshmi, S.; Brown, P. W.; Allcock, H. R.; Laurencin, C. T.
Composite Formation from Hydroxyapatite with Sodium and Potassium Salts of Polyphosphazenes
- Mater. Sci., Mater. in Medicine 2005, 16(7), 613-621
- Bhattacharyya, S.; Lakshmi, S.; Singh, A.; Greish, Y. E.; Brown, P. E.; Allcock, H. R.; Laurencin, C. T.
Polyphosphazene Nanohydroxyapatite Composite Nanofibers as Scaffolds for Bone Tissue Engineering
Chapter in Applications of Micron and Nanoscale Materials in Medicine and Biology. Proc. of Mater. Res. Soc. 2005, 845, 91-96.
- Bhattacharyya, S.; Nair, L. S.; Singh, A.; Krogman, N. R.; Bender, J. D.; Greish, Y. E.; Brown, P. W.; Allcock, H. R.; Laurencin, C. T.
Development of Biodegradable Polyphosphazene-Nanohydroxyapatite Composite Nanofibers via Electrospinning
Chapter in Applic. of Micron and Nanoscale Mater. for Biology and Medicine Proc. of Mater. Res. Soc. 2005, 845, 291-296.
- Singh, A.; Krogman, N.; Sethuraman, S.; Nair, L. S.; Sturgeon, J. L.; Brown, P. W.; Laurencin, C. T.; Allcock, H. R.
Synthesis, Characterization, and in vitro degradation of L-alanine cosubstituted Polyphosphazenes
Polym.Prepr. (ACS Div. Polym. Chem.) 2005, 46(2), 713-714.
- Sethuraman, S.; Nair, L. S.; Singh, A.; Bender, J. D.; Greish, Y. E.; Allcock, H. R.; Laurencin, C. T.
Development of Novel Biodegradable Amino Acid Ester Based Polphosphazene-Hydroxyapatite Composites for Bone Tissue Engineering
Chapter in Applications of Micron and Nanoscale Matrials for Biology and Medicine
- Nair, L. S.; Lee, D.; Bender, J. D.; Barrett, E.; Greish, Y.; Brown, P. W.; Allcock, H. R.; Laurencin, C. T.
Synthesis, Characterization, and Cytotoxicity Evaluations of Novel Degradable Alanine-Based Polyphosphazenes
- Biomed. Mater. Res., Part A 2006, 76 (1),206-213
- Fei, S.-T.; Phelps, M. V. B.; Wang, Y.; Barrett, E.; Gandhi, F.; Allcock, H. R.
A Redox Responsive Gel Based on Ionic Crosslinking
Soft Matter 2006, 2, 397-401.
- Swaminathan, S.; Nair, L.; El-Amin, S.; Ferrar, R.; Nguyen, M.-T.; Singh, A.; Allcock, H. R.; Greish, Y.; Brown, P. W.; Laurencin, C. T.
In vivo Biodegradability and Biocompatibility Evaluation of Novel Alanine Ester Cosubstituted Polyphosphazenes in a Rat Model
- Biomed. Res.(A) 2006, 77(4), 679-687.
- Singh, A.; Krogman, N. R.; Sethuraman, S.; Nair, L. S.; Sturgeon, J.; Brown, P. W.; Laurencin, C. T.; Allcock, H. R.
Effect of Side Group Chemistry on the Properties of Biodegradable L-alanine Co Substituted Polyphosphazenes
Biomacromolecules 2006, 7, 914-918.
- Bhattacharyya, S.; Nair, L.; Singh, A.; Krogman, N., Greish, Y.; Brown, P. W.; Allcock, H. R.; Laurencin, C. T.
Electrospinning of Biodegradable Polyphosphazenes for Biomedical Applications. Fabrication of Poly[bis(ethyl alanate)phosphazene] Nanofibers
- Biomed. Nanotech. 2006, 2, 1-10.
- Krogman, N.; Singh, A.; Nair, L. S.; Laurencin, C. T.; Allcock, H. R.
The Miscibility of Bioerodible Polyphosphazene/Poly(lactide-co-glycolide) Blends:
Biomacromolecules 2006, 2, 1-10.
- Cho, S.-Y.; Allcock, H. R.
Dendrimers Derived from Polyphosphazene-Poly(propyleneinine) Systems: Encapsulation and Triggered Release of Hydrophobic Guest Molecules
Macromolecules 2007, 40, 3115-3121
- Brown, J. L.; Nair, L. S.; Bender, J.; Allcock, H. R.; Laurencin, C. T.
The Formation of an Apatite Coating on Carboxylated Polyphosphazenes via Biomimetic Process
Materials Letters 2007, 61, 3692-3695
- El-Amin, S. F.; Kwon, M. S.; Starnes, T.; Allcock, H. R., Laurencin, C. T.
The Biocompatibility of Biodegradable Glycine Containing Polyphosphazenes: A Comparative Study in Bone
- Inorg. Organometl. Polym and Mater. 2006, 16, 387-396
- Deng, M.; Nair, L. S.; Nukavarapur, S. P.; Kumbar, S. G.; Jiang, T.; Krogman, N. R.; Singh, A.; Allcock, H. R.; Laurencin, C. T.
Miscibility and in vitro Osteocompatibility of Biodegradable Blends of Poly-[ethyl alanato) (p-phenyl phenoxy) phosphazene] and Poly(lactic acid-glycolic acid)
Biomaterials 2008, 29, 337-349
- Sethuraman, S.; Nair, L. S.; El-Amin, S.; Nguyen, M. N.; Greish, Y. E.; Bender, J. D.; Brown, P. W.; Allcock, H. R.; Laurencin, C. T.
Novel Low Temperature Setting Nanocrystalline Calcium Phosphate Cements for Bone Repair: Osteoblast Cellular Response and Gene Expression Studies
- Biomed. Mater. Res. (A) (in press)
- Nukavararapu, S. P.; Kumbar, S.; Brown, J. L.; Krogman, N. R.; Weikel, A. L.; Hindenlang, M. D.; Nair, L. S.; Allcock, H. R.; Laurencin, C. T.
Polyphosphazene/NanoHydroxyapatite-Composite Microsphere Scaffolds for Bone Tissue Engineering
Biomacromolecules 2008 , 9, 1818-1825
- Krogman, N. R.; Hindenlang, M. D.; Nair, L. S.; Laurencin, C. T.; Allcock, H. R.
Synthesis of Purine and Pyrimidine-Containing Polyphosphazenes: Physical Properties and Hydrolytic Degradation
Macromolecules 2008, 41, 8467-8472
- Krogman, N. R; Nhu,; Nguyen, N. Q.; Weikel, A. L; Nair, L. S.; Laurencin. C.T.; Allcock, H. R.
Synthesis and Characterization of Serine- Threonin Containing Polyphosphazenes and Poly(L-lactic acid) Grafted Copolymers
Macromolecules 2008, 41, 7824-7828
- Greish, Y. E.; Sturgeon, J. L.; Singh, A.; Krogman, N. R.; Towny, A. H.; Sethuranathan, S.; Nair, L. S.; Laurencin, C. T.; Allcock, H. R.; Brown, P. W.
Formation and Properties Comprised on Calcium-Deficient Hydroxyapatite and Ethyl Alanate Polyphosphazenes
- Poly. Sci. 2008, 19, 3153-3160
- Greish, Y. E.; Bender, J. D.; Lakshmi, S.; Brown, P. W.; Allcock, H. R.; Laurencin, C. T.
Hydroxyapatite-Polyphosphazene Composites Prepared at Low Temperatures
- Am. Ceram. Soc, 2007, 90, 2728-2734
- Sethuranathan, S.; Nair, L. S.; Nguyen, M.; Singh, A.; Krogman, N. R.; Greish, Y. E.; Allcock, H. R.; Brown, P. W.; Laurencin, C. T.
Effect of Side Group Chemistry on the Mechanical Properties and Osteocompatibility of Biodegradable Alanine-Based Polyphosphazenes
Biomaterials (submitted)
- Deng, M.; Nair, L. S.; Nukavarapu, S. P.; Kumbar, S. G.; Brown, J. L.; Krogman, N. R.; Weikel, A. L.; Hindenlang, M. D.; Allcock, H. R.; Laurencin, C. T.
Etheric Polyphosphazene-Poly(lactide-co-glycolide) Blends for Bone Tissue Engineering
- Biomed. Mat. Res.Part A, 2009 92A, 114-125
- Sethuranathan, S.; Nair, L. S.; Nguyen, M.; Singh, A.; Greish, Y. E.; Allcock, H. R.; Brown, P. W.; Laurencin, C. T.
In Vitro Evaluation of Novel Biodegradable Polyphosphazene-Calcium Deficient Nanocrystalline Hydroxyapatite Composites for Orthopaedic Applications
Advanced Materials (in press)
- Oredein-McCoy, O.; Krogman, N. R.; Weikel, A. L.; Hindenlang, M. D.; Allcock, H. R.; Laurencin, C. T.
Novel Factor-Loaded Polyphosphazene Matrices: Potential for Driving Angiogenesis
- Microencapsulation 2009, 26, 544-555
- Touny. A.; Laurencin, C. T.; Nair, L., Allcock, H. R.; Brown, P.
Formation of Composites Comprised of Calcium Deficient HAp and Crosslinked Gelatin
- Mater. Sci, Mater. in Med. 2008, 19, 3193-3201
- Weikel, A. L.; Krogman, N. R.; Nguyen, N. Q.; Nair, L. S.; Laurencin, C. T.; Allcock, H. R.
Polyphosphazenes that Contain Dipeptides of Nonpolar Character; Synthesis, Characterization, and Sensitivity to Hydrolysis
Macromolecues 2009, 42, 636-639
- Bhattacharyya, S.; Kumbar, Khan, Y.; Singh, A.; Nair, L., Krogman, N. R.; Brown, P. W.; Allcock, H. R.; Laurencin, C. T.
Biodegradable Polyphosphazene Nanohydroxyapatite Composite Nanofibers: Scaffolds for Bone Tissue Engineering
- Biomed. Nanotechnol. 2009, 5, 69-75
- Krogman, N. R.; Weikel, A. L.; Kristhart, K. A.; Nukavarapu, S. P.; Deng, M.; Nair, L. S.; Laurencin, C. T.; Allcock, H. R.
The Influence of Side group Modification in Polyphosphazenes on Hydrolysis and Cell Adhesion of Blends with PLGA
Biomaterials 2009, 30, 3035-3041
- Krogman, N. R.; Weikel, A. L.; Nguyen, K. A.; Nukavarapu, S. P.; Nair, L. S.; Laurencin, C. T.; Allcock, H. R.
Hydrogen Bonding in Blends of Polyesters with di-peptide-containing polyphosphazenes
- Appl. Polym. Sci. 2010, 115, 431-437
- Deng, M.; Nair, L. S.; Nukavarapu, S. P.; Jiang, T.; Li, Kanner, W.; Li, X.; Kumber, S. G.; Weikel, A. L.; Krogman, N. R.; Allcock, H. R.; Laurencin, C. T.
Di-Peptide-Based Polyphosphazene and Polyester Blends for Bone Tissue Engineering
Biomaterials 2010, 31(18), 4898-4908
- Sethuuraman, S.; Swami, ; Nair, L. S.; El-Amin, S.; Teresa, N.; Singh, A.; Greish, Y. E.; Allcock, H. R.; Brown, G.; Laurencin, C. T.
Development and Characterization of Biodegradable Nanocomposite Injectables for Orthopaedic Applications Based on Polyphosphazenes
Biomacromolecules 2010, 39, 5349-5355
- Deng, M.; Nair, L.S.; Nukavarapu, S.; Kumbar, S. G.; Krogman, N. R.; Weikel, A. L.; Allcock, H. R.; Laurencin, C. T.
Dipeptide-based Biodegradable Polyphosphazene and Composites: Evolving, Programmable Three-dimensional Matrices for Tissue Engineering
Biomacromolecules (accepted)
- Deng, M.; Nair, L.S.; Nukavarapu, S.; Kumbar, S. G.; Jiang, T.; Weikel, A. L.; Krogman, N. R.; L.; Allcock, H. R.; Laurencin, C. T.
In Situ Porous Structures: A Unique Polymer Erosion Mechanism in Biodegradable Dipeptide-Based Polyphosphazene and Polyester Blends Producing Matrices for Regenerative Engineering
Advanced Functional Materials 2010, 20, 2794-2806
- Sethuranathan, S.; Nair, L. S.; El-Amin, S.; Nguyen, M.; Singh, A.; Krogman, N.; Greish, Y. E.; Allcock, H. R.; Brown, P. W.; Laurencin, C. T.
Mechanical Properties and Osteocompatibility of Novel Biodegradable Alanin-Based Polyphosphazene Side Groups
Acta Biomateriala 2010, 6,1931-1937
- S. Y. Nukavarapu, S. G. Kumbar, H. R. Allcock, and C. T. Laurencin
Biodegradable Polyphosphazene Scaffolds for Tissue Engineering
Chapter in Biomedical Applications of Polyphosphazenes (A. Andrianov, Ed. ), John Wiley & Sons 2009, 119-138
- Deng, M.; Nair, L.; Krogman, N. R.; Allcock, H. R.; Laurencin, C. T.
“Biodegradable Polyphosphazene Blends for Biomedical Applications”
Chapter in Biomedical Applications of Polyphosphazenes ( A. Andrianov, Ed.) John Wiley & Sons 2009, 139-154.
- Deng, M.; Nair, L. S.; Nukavarapu, S. P.; Kumbar, S. G.; Jiang, T.; Weikel, A. L.; Krogman, N. R.; Allcock, H. R.; Laurencin, C.
In Situ Porous Structures: A Unique Polymer Erosion Mechanism in Biodegradable Dipeptide-based Polyphosphazenes and Polyester Blends Producing Matrices for Regenerative Engineering
Advanced Functional Materials 2010, 17, 2743-2957
- Deng, M.; Kumbar, S. G.; Wan, Y.; Toti, U. S.; Allcock, H. R.; Laurencin, C. T.
Polyphosphazene Polymers for Tissue Engineering: An Analysis of Material Synthesis, Characterization, and Applications
Synthesis, Characterization, and Applications
- Weikel, A. L.; Owens, S. G.; Fushimi, T,; Allcock, H. R,
Synthesis and Characterization of Methionine- and Cysteine-Substituted Phosphazenes
Macromolecules 2010, 43, 5205-5210
- Hindenlang, M. D.; Soudakov, A. A.; Imler, G. H; Laurencin, C. T.; Nair, L. S.; Allcock, H. R.
Iodine-containing Radio-Opaque Polyphosphazenes
R.S.C. Polymer Chemistry 2010, 1, 1467-1474
- Weikel, A. L; Cho, S. Y.; Morozowich, N. L.; Nair, L. S.; Laurencin, C. T., Allcock, H. R.
Hydrolyzable Polylactide-polyphosphazene Block Copolymers for Biomedical Applications– Synthesis, Characterization, and Composites with Poly(lactic-co-glycolic acid)
R.S.C. Polymer Chemistry 2010, 1, 1459-1466
- Deng, M.; Nair, L. S.; Nukavarapu, S. P.; Jiang, T.; Li, X.; Kumbar, S. G.; Weikel A. L.; Krogman, N. R.; Allcock, H. R.; Laurencin, C. T.
Di-Peptide-Based Polyphosphazene and Polyester Blends for Bone Tissue Di-Peptide-Based Polyphosphazene and Polyester Blends for Bone Tissue Studies
Biomaterials 2010, 31, 4898-4908
- Deng, M.; Nair, L. S.; Nukavarapu, S. G.; Brown, J. L.; Krogman, N. R.; Allcock, H. R.; Laurencin, C. T.
Biomimetic Bioactive Etheric Polyphosphazene-poly(lactide-co-glycolide) Blends for Bone Tissue Engineering
- Biomed. Mater. Res. (A) 2010, 92A(1), 114-125
- Weikel, A. L.; Owens, S. G.; Morozowich, N. L.; Deng, M., Nair, L.S.; Laurencin, C. T.; Allcock, H. R.
Miscibility of Choline-Substituted Polyphosphazenes: Blend Compatibility with PLGA and Osteoblast Activity on Resulting Blends
Biomaterials 2010. 31, 8507-8515
- Sethuraman, S.; Nair, L. S.; El-Amin, S.; Nguyen, M. T.; Singh, A., Greish, Y. E.; Allcock, H. R.; Brown, P. W.; Laurencin, C. T.
Composite Scaffolds: Bridging Nanofiber and Microsphere Architectures to Improve Bioactivity of Mechanically Competent Constructs
- Biomater. Sci., Polymer Ed., 2011, 22(4), 733-752
- Morozowich, N. L.; Weikel, A.L ; Nichol, J. L.; Chen, C.; Nair, L.; Laurencin, C. T., Allcock, H. R.
Polyphosphazenes Containing Vitamin Substituents: Synthesis, Characterization, and Hydrolytic Sensitivity
Macromolecules 2011, 44, 1355-1364
- Sethuraman, S.; Nair, L.S,; El-Amin, S.; Nguyen, M. T.; Singh, S.; Greish, Y. E.; Allcock, H. R.; Brown, P. E.; Laurencin, C. T.
Development and Characterization of Biodegradable Nanocomposite Injectables for Orthopaedic Applications
- Biomater. Sci., Polymer Ed. 2011, 22(4), 733-752 (a review).
- Deng, M.; Kumbar, S. G.; Nair, L. S.; Weikel, A. L.; Allcock, H. R.; Laurencin, C. T.
Biomimetic Structures: Biological Implications of Di-peptide Substituted Phosphazene-Polymer Blend Nanofiber Matrices for Load Bearing Bone Regeneration
Adv. Functional Mater 2011, 21, 2641-2651. (highlighted on cover).
- Morozowich, N.; Weikel, A.; Mondschein, R.; Chen, C.; Nair, L.; Laurencin, C. T.; Allcock, H. R.
Synthesis and Synthetic Challenges of Biomolecule-Containing Polyphosphazenes
ACS Div. Poly. Chem. 2011, 52(2), 354-355
- Morozowich, N. L.; Weikel, A. L.; Nichol, J. L.; Chen, C.; Nair, L.; Laurencin, C. T.; Allcock, H. R.
Polyphosphazenes as Tissue Engineering Materials
ACS Div. Poly. Chem. 2011, 52(2), 312-313
- Sethuraman, S.; Nair, L. S.; Nuygen, M. T; Singh, A.; Greish, Y. E.; Allcock, H. R. Brown, P. W.; Laurencin, C, T.
In Vitro Evaluation of Novel Biodegradable Polyphosphazene-Calcium Deficient Nanocrystalline Hydroxyapatite Composites for Orthopaedic Applications
Advanced Functional Materials (in press)
- Deng, M.; Nair, L.S.; Nukavarapu, S.; Kumbar, S. G.; Krogman, N. R; Allcock, H. R.; Laurencin, C. T.
Dipeptide-based Biodegradable Polyphosphazene and Composites: Evolving, Programmable Three-Dimensional Matrices for Tissue Regeneration
Biomacromolecules (accepted for publication)
- Allcock, H. R.; Morozowich, N. L
Bioerodible Polyphosphazenes and their Medical Potential
R.S.C. Polymer Chemistry 2012, 3, 578-590
- Deng, M.; Kumbar, S. G.; Allcock, H. R.; Laurencin, C. T
Polyphosphazenes as Biomaterials
in Polymeeric Structures and Materials, I (Dumitriv, V.; Popa, V. Eds.) CRC Press 2013 (January 16) 20 pages)
- Peach, M. S.; Kumbar, S. G.; James, R.; Toti, U. S.; Balasubramaniam, D.; Deng, M. Ulery, B.; Mazzocca, A. D.; McCarthy, M. B.; Morozowich, N. L.; Allcock, H. R. Laurencin, C. T.
Design and Optimization of Polyphosphazene Functionalized Fiber Matrices for Soft Tissue Regeneration
- Biomed. Nanotech. 2012, 8, 107-124
- Morozowich, N. L.; Nichol, J. L.; Mondschein, R. J.; Allcock, H. R.
Design and Examination of an Antioxidant-Containing Polyphosphazene Scaffold for Tissue Engineering
R.S.C. Polymer Chem. 2012, 3, 778-786
- Peach, M. S.; James, R.; Toti, U. S.; Deng, M.; Morozowich, N. L.; Allcock, H. R.; Laurencin, C. T.; Kumbar, S. G
Polyphosphazene Functionalized Polyester Fiber Matrices for Tendon Tissue Engineering: In Vitro Evaluation of Human Mesenchymal Stem Cells
Biomedical Materials 2012, 7, 1-13
- Nichol, J. L.; Morozowich, N. L.; Allcock, H. R.
Biodegradable Alanine and Phenylalanine Alkyl Ester Polyphosphazenes as Ligament and Tendon Tissue Scaffolds
RSC Polymer Chemistry. 2012, 3, 778-786
- Morozowich, N. L.; Modzelewski, T.; Allcock, H. R.
Synthesis of Phosphate Polyphosphazenes via Two Synthetic Routes
Macromolecules 2012, 45, 7684-7691
- Morozowich, N. L.; Nichol, J. L.; Allcock, H. R.
Investigation of Apatite Mineralization on Antioxidant Polyphosphazenes for Bone Tissue Engineering
Chem. Mater. 2012, 24, 3500-3509
- Tian, Z.; Zhang, Y.; Liu, X.; Chen, C.; Guiltinan, M. J.; Allcock, H. R.
Bioderadable Polyphosphazenes Containing Antibiotics: Synthesis, Characterization, and Hydrolytic Release Behavior
Polymer (accepted)
- Liu, X.; Zhang, H.; Tian, Z.; Sen, A.; Allcock, H. R.
Preparation of quaternized organic-inorganic hybrid brush polyphosphazene-co-poly[2-(dimethylamino)ethyl methacrylate] electrospun fibers and their antibacterial properties
Polymer Chemistry 2012, 3, 2082-2091
- Liu, X,; Tian, Z.; Chen, C.; Allcock, H. R.
UV-Cleavable Unimolecular Micelles: Synthesis and Characterization Toward Photocontrolled Drug Release Carriers
Polymer Chemisry 2013, 4, 1115-1125
PUBLICATIONS RELATED TO OPTICS, ELECTRONICS, AND PHOTONICS
- Allcock, H. R.; Wright, S. D.; Kosydar, K. M.
Poly(organophosphazenes) with Chromophores as Substituent Groups
Macromolecules 1978, 11, 357‑359.
- O’Brien, J. P.; Ferrar, W. T.; Allcock, H. R.
The Photolysis of Poly(alkoxy‑ and aryloxyphosphazene), [NP(OR)2]n
Macromolecules 1979, 12, 108‑113.
- Allcock, H. R.; Levin, M. L.; Austin, P. E.
Quaternized Cyclic and High Polymeric Phosphazenes and their Interactions with Tetracyanoquinodimethane
Inorganic Chemistry 1986, 25, 2281‑2288.
- Allcock, H. R.; Neenan, T. X.
Synthesis of Polyphosphazenes Bearing Covalently‑Linked Copper Phthalocyanine Units
Macromolecules 1986, 19, 1495‑1501.
- Saraceno, R. A.; Riding, G. H.; Allcock, H. R.; Ewing, A. G.
Electronic Properties of Phosphazene Substituents on Ferrocene
- Am. Chem. Soc. 1988, 110, 980‑982.
- Saraceno, R. A.; Riding, G. H.; Allcock, H. R.; Ewing, A.G.
Electronic Properties and Redox Conduction of Ferrocene‑Substituted High Polymeric Phosphazenes
- Am. Chem. Soc. 1988, 110, 7254‑7255.
197 Allcock, H. R.; Kim, C.
Liquid Crystalline Phosphazenes ‑ High Polymeric and Cyclic Trimeric Systems with Aromatic Azo Side Groups
Macromolecules 1989, 22, 2596‑2602.
- Allcock, H. R.; Kim, C.
Liquid Crystalline Phosphazenes Bearing Biphenyl Mesogenic Groups
Macromolecules 1990, 23, 3881‑3887
- Dembek, A. A.; Kim, C.; Allcock, H. R.; Devine, R. L. S.; Steier, W. H.; Spangler, C. W.
A Second‑Order Nonlinear Optical Poly(organophosphazene)
Chemistry of Materials 1990, 2, 97‑99.
- Dembek, A. A.; Allcock, H. R.; Kim, C., Steier; W. H.; Devine, R. L. S.; Shi, Y.; Spangler, C. W.
“Second Order Nonlinear Optically‑Active Polyphosphazenes” in Materials for
Nonlinear Optics (S. Marder, J. E. Sohn, and G. S. Stucky, eds.), pp. 258‑266, ACS Symp. Ser. 455, 1991.
- Allcock, H. R.; Ngo, D. C.; Parvez, M.; Whittle, R. R.; Birdsall, W. J.
Syntheses and Structures of Cyclic and Short Chain Linear Phosphazenes Bearing 4‑Phenylphenoxy Side Groups
- Am. Chem. Soc. 1991, 113, 2628‑2634.
- Allcock, H. R.; Kim, C.
Poly(organophosphazenes) with Azoxybenzene Side Groups: Synthesis and Morphology
Macromolecules 1991, 24, 2841‑2845.
- Allcock, H. R.; Kim, C.
Photochromic Polyphosphazenes with Spiropyran Units
Macromolecules 1991, 24, 2846‑2851.
- Allcock, H. R.; Dembek, A. A.; Kim, C.; Devine, R. L. S.; Shi, Y.; Steier, W. H.; Spangler, C.W.
Second‑Order Nonlinear Optical Poly(organophosphazenes): Synthesis and Nonlinear Optical Characterization
Macromolecules 1991, 24, 1000‑1010.
- Allcock, H. R.; Ngo, D. C.; Parvez, M.; Visscher, K.
Synthesis and Structures of Para‑Halogenophenoxy Phosphazenes: A Comparison of the Structures of Cyclic and Linear‑Short‑Chain Species.
Inorganic Chemistry 1994, 24, 5208-5214.
- Nelson, C. J.; Coggio, W. D.; Allcock, H. R.
Ultraviolet Radiation‑Induced Crosslinking of Poly[bis(2‑(2‑methoxyethoxy)ethoxy)phosphazene]
Chemistry of Materials 1991, 3, 786‑787.
- Allcock, H. R.; Dodge, J. A.; L. S. Van Dyke, Martin, C. R.
Polyphosphazenes Bearing Polymerizable Pyrrole, Thiophene, and Furan Side Groups: Synthesis and Chemical Oxidation
Chemistry of Materials 1992, 4, 780‑788.
- Welker, M. F.; Allcock, H. R.; Grune, G. L.; Chern, R. T.; Stannett, V. T.
The Effects of Radiation on Newly Synthesized Allylamino‑Substituted Polyphosphazenes
Polym. Prepr. (ACS Div. Polym. Chem.) 1992, 66, 259‑260.
- Welker, M. F.; Allcock, H. R.; Grune, G. L.; Chern, R. T.; Stannett, V. T.
Radiation‑Induced Modifications of Allylamino‑Substituted Polyphosphazenes
ACS Sym. Ser. 1994, 537, 293‑303.
- Allcock, H. R.; Cameron, C. G.
The Synthesis and Characterization of Small Molecule and High Polymeric Phosphazenes Bearing Cinnamate Groups
Macromolecules 1994, 27, 3125‑3130.
- Allcock, H. R.; Cameron, C. G.
The Synthesis and Photocrosslinkable Chalcone‑Bearing Polyphosphazenes
Macromolecules 1994, 27, 3131‑3135.
- Stannett, V. T.; Grune, G. L.; Chern, R. T.; Allcock, H. R.
Radiation Cross-Linking of Some Polyphosphazenes and Possible Applications in Microlithography.
Polym. Prepr. (ACS Div. Polym. Chem) 1994, 35, 876-877.
- Allcock, H. R.; Klingenberg, E. H.
The Synthesis of Liquid Crystalline Phosphazenes Containing Chiral Mesogens
Macromolecules 1995, 28, 4351-4360.
- Olshavsky, M. A.; Allcock, H. R.
Polyphosphazenes that Exhibit High Refractive Indices: Synthesis, Characterization, and Optical Effects
Macromolecules 1995, 28, 6188-6197.
- Allcock, H. R.; Al-Shali, S.; Ngo, D. C.; Visscher, K. B.; Parvez, M.
Synthesis and Structure of Small-Molecule Phosphazene Rings that Bear Fused-Ring Aryloxy Side Groups: Models for Optically Useful High
Polymers
J. Chem. Soc. (Dalton) 1995, 3521-3532.
- Allcock, H. R.; Cameron, C. G.; Skloss, T. W.; Taylor-Meyers, S.; Haw, J. F.
Molecular Motion of Phosphazene-Bound NLO Chromophores
Macromolecules 1996, 29, 233-238.
- Olshavsky, M.; Allcock, H. R.
Polyphosphazenes with High Refractive Indices: Optical Dispersion and Molar Reactivity
Macromolecules 1997, 30, 4179-4183.
- Olshavsky, M. A.; Allcock, H. R.
Synthesis of CdS Nanoparticles in Solution and in a Polyphosphazene Matrix
Chemistry of Materials 1997, 9, 1367-1376.
- Allcock, H. R.; Bender, J. D.; Chang, Y.; McKenzie, M.; Fone, M. M.
Controlled Refractive Index Polymers: Polyphosphazenes with Chlorinated- and Fluorinated- Aryloxy and Alkoxy Side Groups
Chemistry of Materials 2003, 15, 473-477.
- Allcock, H. R.; Chang, Y.; Stone, D. A.
Synthesis and Light-Emitting Characteristics of Phosphazene-Functionalized Polyphenylenevinylenes
- Polymer Sci2006, 44, 69-76.
- Cho, S.-Y.; Allcock, H. R.
Novel Highly Fluorinated Perfluorocyclobutane-Based Polymers for Photonic Applications
Chem. Mater. 2007, 19, 6338-6344
- Fushimi, T.; Allcock, H. R.
Synthesis and Optical Properties of Sulfur-Containing Monomers and Cyclomatrix Phosphazenes
- Chem. Soc., Daltan Trans. 2010, 39, 5349-5355
- Ainscough, E. W.; Allcock, H. R.; Brodie, A., M.; Gordon, K. C.; Hindenlang, M. D.; Horvath, R.; Otter, C. A.
Specttroscopic Studies of Phosphazene Polymers Containing Photoluminescent Metal Complexes
Eur. J. Inorg. Chem. 2011, 25, 3691-3704
- Davidson, R. J.; Ainscough, E. W.; Brodie, A. M.; Jameson, G. B.; Waterland, M. R.; Allcock, H. R.; Hindenlang, M. D.; Moubaraki, B.; Murray, K.; Gordon, K.; Horvath, R.
Inorg. Chem. 2012, 51, 8307-8316
- Blonsky, P. M.; Shriver, D. F.; Austin, P. E.; Allcock, H. R.
Polyphosphazene Solid Electrolytes
- Am. Chem. Soc. 1984, 106, 6854‑6855.
- Allcock, H. R.; Austin, P. E.; Neenan, T. X.; Sisko, J. T.; Blonsky, P. M.; Shriver, D. F.
Polyphosphazenes with Etheric Side Groups: Prospective Biomedical and Solid Electrolyte Polymers
Macromolecules 1986, 19, 1508‑1512.
- Blonsky, P. M.; Shriver, D. F.; Austin, P. E.; Allcock, H. R.
Complex Formation, Conductivity, and Lithium Ion Transport in Poly‑phosphazene‑Based Solid Electrolytes
Polym. Mater. Sci. Eng. 1985, 53, 118‑122.
- Allcock, H. R.; Mang, M. N.; Riding, G. H.; Whittle, R. R.
The Synthesis and Structure of Transition Metal‑Bound Phosphazenes Derived from Phosphazene Anions
Organometallics 1986, 5, 2244‑2250.
- Blonsky, P. M.; Shriver, D. F.; Austin, P. E.; Allcock, H. R.
Complex Formation and Ionic Conductivity of Polyphosphazene Solid Electrolytes
Solid State Ionics 1986, 18 & 19, 258‑264.
- Bennett, J. L.; Dembek, A. A.; Allcock, H. R.; Heyen, B. J.; Shriver, D. F.
Radiation Crosslinking of Poly[bis(2‑(2‑methyloxyethoxy)ethoxy]phosphazene Effect on Solid State Ionic Conductivity
Polym. Prepr. (ACS Polym. Div.) 1989, 30, 437‑438.
- Lerner, M.; Tipton, A.; Shriver, D. F.; Dembek, A. A.; Allcock, H. R.
Characterization and Conductivities of Polyphosphazene‑Iodine Complexes
Chemistry of Materials 1991, 3, 1117‑1120.
- Allcock, H. R.; Fitzpatrick, R. J.
Sulfonation of Aryloxy‑ and Arylamino‑Phosphazenes: Small‑Molecule Compounds, Polymers, and Surfaces
Chemistry of Materials 1991, 3, 1120‑1132.
- Nelson, C. J.; Coggio, W. D.; Allcock, H. R.
Ultraviolet Radiation‑Induced Crosslinking of Poly[bis(2‑(2‑methoxyethoxy)ethoxy)phosphazene]
Chemistry of Materials 1991, 3, 786‑787.
- Allcock, H. R.; Nelson, C. J.; Coggio, W. D.
Solid Polymeric Electrolytes Based on Crosslinked MEEP‑Type Materials
Poly. Prepr. (ACS PMSE Div.) 1993, 68, 76‑77.
- Allcock, H. R.; Napierala, M. E.; Cameron, C. G.; O’Connor, S. J. M.
The Synthesis and Characterization of Ionically-Conducting Alkoxy Ether/Ålkoxy Mixed Substituent Poly(organophosphazenes) and their Use
as Solid Solvents for Ionic Conduction
Macromolecules 1996, 29, 1951-1956.
- Allcock, H. R.; Kuharcik, S. E.; Reed, C. S.; Napierala, M. E. Allcock, H. R.; Kuharcik, S. E.; Reed, C. S.; Napierala, M. E.
Synthesis of Polyphosphazenes with Ethyleneoxy-Containing Side Groups: New Solid Electrolyte Materials
Macromolecules 1996, 29, 3384-3389.
- Allcock, H. R.; Napierala, M. E.; Olmeijer, D. L.; Cameron, C. G.; Kuharcik, S. E.; Reed, C. S.; O.Connor, S. J. M.
Proc. Intern. Conf. on Solid Polym. Electrolytes, Uppsala, Sweden (J. Thomas, ed.)
Electrochimica Acta 1997, 1-6.
- Allcock, H. R.; Ravikiran, R.; O’Connor, S. J. M.
Effect of Oligoethyleneoxy-cyclotriphosphazenes, Tetraglyme, and Other Small Molecules on the Ionic Conductivity of the
Poly[methylethoxyethoxy)phosphazene](MEEP)/Lithium Triflate System
Macromolecules 1997, 30, 3184-3190.
- Allcock, H. R.; Napierala, M. E.; Best, S. A.; Merz, K. M.
Examination of the Mechanism of Ionic Conduction in Polyphosphazenes by 13C,31P, and 15N NMR Spectroscopy and Molecular Dynamics
Macromolecules 1999, 32, 732-741.
- Allcock, H. R.; Olmeijer, D. L.; O’Connor, S. J. M.
Cation Complexation and Conductivity in Crown Ether Bearing Polyphosphazenes
Macromolecules 1998, 31, 753-759.
- Allcock, H. R.; Sunderland, N. J.; Ravikiran, R.; Nelson, J. M.
Polyphosphazenes with Novel Architectures: Influence on Physical Properties and Behavior as Solid Polymer Electrolytes
Macromoleucles 1998, 31, 8026-8035.
- Lvov, S. N.; Zhou, X. Y.; Benning, L.; Wei, X. J.; Fedkin, M. V.; Allcock, H. R.; Hofmann, M. A.; Cannon, A. M.; Kellam, E. C.; Morford, R.
V.
Development of Proton-Conducting Membranes for High Temperature Direct Methanol Fuel Cells
Proc. Intern. Symp. on Energy Engineering in the 21st Century (Ping Cheng, ed.) Begnall House: New York, 2000, 1483-1488.
- Allcock, H. R.; Laredo, W. R.; Kellam, E. C.; Morford, R. V.
Polynorbornenes Bearing Pendent Cyclotriphosphazenes with Oligoethyleneoxy Side Groups: Behavior as Solid Polymer Electrolytes
Macromolecules 2001, 34, 787-794.
- Allcock, H. R.; Laredo, W. R.; Morford, R. V.
Polymer Electrolytes Derived From Polynorbornenes with Pendent Cyclophosphazenes: Poly(ethylene glycol) Methyl Ether Derivatives
Solid State Ionics 2001, 139, 27-36.
- Allcock, H. R.; Kellam, E. C.; Morford, R. V.
Gel Electrolytes from Co-Substituted Oligoethyleneoxy/Trifluoroethoxy Linear Polyphosphazenes
Solid State Ionics 2001, 143, 297-308.
- Allcock, H. R.; Prange, R.; Hartle, T. J.
Poly(phosphazene-ethylene oxide) Di- and Triblock Copolymers as Solid Polymer Electrolytes
Macromolecules 2001, 34, 5463-5470.
- Allcock, H. R.; Hofmann, M. A.; Wood, R. M.
Phosphonation of Aryloxyphosphazenes
Macromolecules 2001, 34, 6915-6921.
- Zhou, X. Y.; Hofmann, M. A.; Weston, J. A.; Chalkova, E.; Allcock, H. R.; Lvov, S. N.
High Temperature Methanol Crossover in Proton-Conducting Polyphosphazene Membranes
Proc. Electrochem. Soc. 2001, 34-41.
- Fedkin, M. V.; Zhou, X. Y.; Hofmann, M. A.; Chalkova, E.; Weston, J. A.; Allcock, H. R.; Lvov, S. N.
Evaluation of Methanol Crossover in Proton-Conducting Polyphosphazene Membranes
Materials Letters 2002, 52, 192-196.
- York, S.; Kellam, E. C.; Allcock, H. R.; Frech, R.
A Vibrational Spectroscopic Study of Lithium Triflate in Polyphosphazenes with Linear Oligoethyleneoxy Side Chains of Different Lengths
Electrochim. Acta 2001, 46, 1553-1557.
- Allcock, H. R.; Hofmann, M. A.; Ambler, C. M.; Lvov, S. N.; Zhou, X. Y.; Chalkova, E.; Weston, J.
Phenyl Phosphonic Acid Functionalized Poly[aryloxyphosphazenes] as Proton- Conducting Membranes for Direct Methanol Fuel Cells
- Membrane Science2002, 202, 47-54
- Hofmann, M. A.; Ambler, C. M.; Maher, A. E.; Chalkova, E.; Zhou, X. Y.; Lvov, S. N.; Allcock, H. R.
Synthesis of Polyphosphazenes with Sulfonimide Side Groups
Macromolecules 2002, 35, 6490-6493.
- Allcock, H. R.; Hofmann, M. A.; Ambler, C. M.; Morford, R. V.
Phenylphosphonic Acid Functionalized Poly[aryloxyphosphazenes]
Macromolecules 2002, 35, 3483-3489.
- Gao, L. ; Macdonald, D. D.; Urquidi-Macdonald, M.; Olmeijer, D.; Allcock, H. R.
Charge Cycling and Impedance Characterization of a Polyphosphazene Solid Polymer Electrolyte-Manganese(IV) Oxide Intercalation Cathode
Elecrochim Acta 2002, 47, 3863-3872.
- Zhou, X.; Weston, J.; Chalkova, E.; Lvov, S. N.; Hofmann, M. A.; Ambler, C. M.; Allcock, H. R.
High Temperature Transport Properties of Polyphosphazene Membranes for Direct Methanol Fuel Cells
Electrochim. Acta 2003, 48, 2173-2180.
- Allcock, H. R.; Bender, J. D.; Morford, R. V.; Berda, E. B.
Synthesis and Characterization of Novel Solid Polymer Electrolytes Based on Poly(7-oxanonorbornene)s with Pendent Oligoethyleneoxy)-
Functionalized Cyclotriphosphazenes
Macromolecules 2003, 36, 3563-3569.
- Frech, R.; York, S.; Allcock, H. R.; Kellam, E. C.
Ionic Transport in Polymer Electrolytes: The Essential Role of Associated Ionic Species
Macromolecules 2004, 23, 8699-8702.
- Allcock, H. R.; Hofmann, M. A.; Ambler, C. M.; Maher, A. E.; Wood, R. M.; Lvov, S.; Zhou, X. Y.; Chalkova, E.; Fedkin, M. W.; Weston, J.
A.
Chapter in special volume of Polymers for Advanced Technology (submitted)
- Allcock, H. R.; Welna, D. T.; Maher, A. E.
Single Ion Conductors: Polyphosphazenes with Sulfonimide Functional Groups
Solid State Ionics, 2006, 177, 741-747.
- Fei, S.-T.; Lee, S.-H. A.; Pursel, S. M.; Bashem, J.; Hess, A.; Grimes, C. A.; Horn, M. W.; Mallouk, T. E.; Allcock, H. R.
Electrolyte Infiltration for Phosphazene-Based Dye-Sensitized Solar Cells
- Polymer Sources 2011, 196, 5223-5230
- Allcock, H. R.; Chang, Y.; Welna, D. T.
Ionic Conductivity of Covalently Interconnected Polyphosphazene-Silicate Hybrid Networks
Solid State Ionics, 2006, 177, 569-572.
- Allcock, H. R.; Welna, D. T.; Stone, D. A.; Powell, E. s.; Wood, R.; Kwak, G.,
Recent Advances in Polyphosphazenes Used as Ionic Conductors and in Electroactive Materials
Polym. Prepr. (ACS Div. Polm. Chem.), 2005, 93, 782-783.
- Allcock, H. R.; Wood, R. M.
Design and Synthesis of Ion Conductive Polyphosphazenes for Fuel Cell Applications (Review)
- Polm. Sci, Part B, Polymer Physics, 2006, 44, 2358-2368.
- Morford, R. V.; Welna, D. T.; Kellam, C. E.; Hofmann, M. A.; Allcock, H. R.
A Phosphate Additive for Poly(ethylene oxide)-Based Gel Polymer Electrolytes
Solid State Ionics, 2006, 177, 721-726.
- Allcock. H. R.; Welna, D. T.; Stone, D. A.
Synthesis of Pendent Functionalized Cyclophosphazene Polyoctenamers: Amphiphilic Lithium-Ion Conductive Materials
Macromolecules 2005, 38, 10406-10412.
- Conner, D. A.; Welna, D. T.; Chang, Y.; Allcock, H. R.
Influence of Terminal Phenyl Groups on the Side Chains of Phosphazene Polymers: Structure-Property Relationships and Polymer Electrolyte Behavior
Macromolecules (In press).
- Welna, D. T.; Stone, D. A.; Allcock, H. R.
Lithium Ion Conductive Polymers as Prospective Membranes in Lithium Seawater Batteries
Chemistry of Materials 2006, 18, 4486-4492.
- Stone, D. A.; Welna, D. T.; Allcock, H. R.
Synthesis and Characterization of Lithium Ion Conductive Membranes with Low Water Permeation
Chemistry of Materials (in Press)
- Allcock, H. R.; Cho, S. Y.; Steely, L. B.
New Amphiphilic Poly[bis(2,2,2-trifluoroethoxy)phosphazene]-Poly(propylene-glycol) Triblock Copolymers: Synthesis and Micellar Characteristics
Macromolecules 2006, 39, 8334-8338
- Klein, R.; Welna, D. T.; Weikel, A.; Allcock, H. R.; Runt, J.
Counterion Effects on Ion Mobility Ion Concentration of Doped Polyphosphazenes and Polyphosphazene Ionomers
Macromolecules 2007, 40, 3990-3995
- Klein, R.; Welna, D.T.; Weikel, A.; Allcock, H. R.; Runt, J.
Counterion Effects on Ion Mobility Ion Concentration of Doped Polyphosphazenes and Polyphosphazene Ionomers
Macromolecules (submitted).
- Cho, S.-Y.; Allcock, H. R.
Dendrimers Derived from Polyphosphazene-Poly(propyleneimine) Systems: Encapsulation and Triggered Release of Hydrophobic Guest Molecules
Macromolecules 2007, 40, 3115-3121
- Fei, S.-T.; Allcock, H. R.
Recent Progress with Ethyleneoxy Phosphazenes as Lithium Battery Electrolyes
Mater. Res. Soc. Symp. 2009, 1127-T01-05
- Fei, S.-T.; Allcock, H. R.
Methoxyethoxyethoxyphosphazenes as Ionic Conductive Fire Retardant Additives for Lithium Battery Systems
Power Sources 2010, 195(7), 2082-2088
- Argun, A.; Ashcroft, J.; Herring, M.; Lee, D.; Allcock, H. R.; Hammond, P.
Ion Conduction and Water Transport in Polyphosphazene-Based Multilayers
Chem. Mater. 2009, 22, 226-232
- Lee, D.; Allcock, H. R.
The Effects of Cations and Anions on the Ionic Conductivity of Poly[bis(2-(2-methoxyethoxy)phosphazene] Doped with Lithiun and Magnesium Salts of Trifluoromethanesulfonate and Bis(trifluoromethanesulfonyl)imidate
Solid State Ionics 2010, 181, 1721-1726
- Lee, S.-H. A.; Jackson, A-M.S; Hess, A.; Fei, S-T.S.; Pursel, S. M.; Basham, J.; Grimes, C. A.; Horn, M. W.; Allcock, H. R.; Mallouk, T. E.
Influence of Different Iodide Salts on the Performance of Dye-Sensitized Solar Cells Containing Phosphazene-Based Nonvolatile Electrolytes
- Phys. Chem. 2010, 114, 15234-15242
- Lee, D. K.; Saito, T.; Benesi, A. J.; Hickner, M. A.; Allcock, H. R.
Characterization of Water in Proton-Conducting Membranes by Deuterium NMR T Relaxation
- Phys. Chem. 2011, 115(5), 776-783
- Fei, S.-T.; Lee, S.-H. A.; Pursel, S. M.; Bashem, J.; Hess, A.; Grimes. C. A.; Horn, M. W.; Mallouk, T. E.; Allcock, H. R.
Electrolye Filtration in Phosphazene-Based Dye Sensitized Solar Cells
- Power Sources 2011, 196, 5223-5230
- Lee, D.; Saito, T.; Benesi, A.; Hickner, M.; Allcock, H. R.
Characterization of Water in Proton Conducting Membranes by Deuterium NMR
- Phys. Chem. 2011, 115(5), 776-783
- Chen, C.; Hess, A. R.; Jones, A.; Liu, X.; Barber, G. D.; Mallouk T. E.; Allcock, H. R.
Quaternization of Poly(aryloxy- and alkoxyphosphazenes)
Macromolecules 2012, 45, 1182-1189
- Alaaeddine, A.; Hess, A.; Boschet, Allcock, H. R.; Ameduri, B.
Synthesis and Characerization of Novel Alternating Fluorinated Copolymers Bearing Oligo(ethylene oxide) Side Chains
Polymer Chemistry 2013, (in press)
SURFACE SCIENCE AND COMPOSITE MATERIALS
- Allcock, H. R.; Kwon, S.
Covalent Linkage of Proteins to Surface‑Modified Poly(organophosphazenes): Immobilization of Glucose‑6‑Phosphate Dehydrogenase and
Trypsin
Macromolecules 1986, 19, 1502‑1508.
- Allcock, H. R.; McDonnell, G. S.; Riding, G. H., Manners, I.
Influence of Different Organic Side Groups on the Thermal Behavior of Polyphosphazenes: Random Chain Cleavage, Depolymerization, and
Pyrolytic Crosslinking
Chemistry of Materials 1990, 2, 425‑432.
- Visscher, K, B.; Manners, I.; Allcock, H. R.
Interpenetrating Polymer Networks of Poly(organophosphazenes) and Organic Polymers
Macromolecules 1990, 23, 4885‑4886
- Allcock, H. R.; Rutt, J. S.; Fitzpatrick, R. J.
A Surface Reaction of Poly[bis(trifluoroethoxy)phosphazene] Films by Basic Hydrolysis
Chemistry of Materials 1991, 3, 442‑449.
- Allcock, H. R.; Fitzpatrick, R. J.
Functionalization of the Surface of Poly[bis(trifluoroethoxy)phosphazene] by Reactions with Alkoxide Nucleophiles
Chemistry of Materials 1991, 3, 450‑454.
- Allcock, H. R.; Fitzpatrick, R. J.; Salvati, L.
Oxidation of Poly[di(4‑methylphenoxy)phosphazene] Surfaces, and Chemistry of the Surface Carboxylic Acid Groups
Chemistry of Materials 1992, 4, 769‑775.
- Allcock, H. R.; Welker, M. F.; Parvez, M.
Synthesis and Structure of Borazinyl‑Substituted Small‑Molecule and High Polymeric Phosphazenes: Ceramic Precursors
Chemistry of Materials 1992, 4, 296‑307.
- Allcock, H. R.; Visscher, K. B.; Manners, I.
Polyphosphazene‑Organic Polymer Interpenetrating Polymer Networks
Chemistry of Materials 1992, 4, 1188‑1192.
- Allcock, H. R.; Visscher, K. B.
Preparation and Characterization of Poly(organophosphazene) Blends
Chemistry of Materials 1992, 4, 1182‑1187.
- Allcock, H. R.; Fitzpatrick, R. J.; Visscher, K.
Thin Layer Grafts of Poly[bis(methoxyethoxyethoxy)phosphazene] on Organic Polymer Surfaces
Chemistry of Materials 1992, 4, 775‑780.
- Allcock, H. R.; Nelson, C. J.; Coggio, W. D.; Manners, I.; Koros, W. J.; Walker, D. R.B.; Pessan, L. A.
Gas Permeation and Selectivity of Poly(organophosphazene) Membranes
Macromolecules 1993, 26, 1493‑1502.
- Allcock, H. R.; Nelson, C. J.; Coggio, W. D.
Photoinitiated Graft Poly(organophosphazenes): Functionalized Immobilization Substrates for the Binding of Amines, Proteins, and Metals
Chemistry of Materials 1994, 6, 516‑524
- Allcock, H. R.; Visscher, K. B.
Metal Ion‑Complexing Polyphosphazene Interpenetrating Polymer Networks
Chemistry of Materials 1994, 6, 2040-2050.
- Allcock, H. R.; Smith, D. E.
Surface Studies of Poly(organophosphazenes) Containing Diemethylsiloxane Grafts
Chemistry of Materials 1995, 7, 1469-1474.
- Ten Huisen, K. S.; Brown, P. W.; Reed, C. S.; Allcock, H. R.
Low Temperature Synthesis of a Self-Assembling Composite: Hydroxyapatite Poly[bis(sodium carboxylatophenoxy)phosphazene]
- Mater. Sci., Mater. Med.1996, 7, 673-682.
- Mack, L. L.; Fitzpatrick, R. J.; Allcock, H. R.
Hydrophobicity, Hydrophilicity, and Amphiphilicity in Phosphazene Small Molecules and High Polymers: Langmuir-Blodgett Studies
Langmuir, 1997, 13, 2123-2132.
- Reed, C. S.; TenHuisen, K. S.; Brown, P. W.; Allcock, H. R. ;
Thermal Stability and Compressive Strength of Calcium Deficient Hydroxyapatite Poly[bis(Carboxylatophenoxy)phosphazene] Composites
Chemistry of Materials 1996, 8, 440-447.
- Laurencin, C. T.; El-Amin, S. F.; Ibim, S. E.; Willoughby, D. A.; Attawia, M.; Ambrosio, A. M. A.; Allcock, H. R.
A Highly Porous 3-Dimensional Polyphosphazene Polymer Matrix for Skeletal Tissue Regeneration
- Biomed. Mater. Res.1996, 303, 133-138.
- Reed, C. A.; Taylor, J. P.; Guigley, K. S.; Kully, K. S.; Bernheim, K. A.; Coleman, M. M.; Allcock, H. R.
Polyurethane/Poly[bis(carboxylatophenoxy)phosphazene] Blends and Their Potential as Flame-Retardant Materials
- Polym. Sci. & Eng.2000, 40, 465-472.
- Allcock, H. R.; Taylor, J. P.
Phosphorylation of Phosphazenes and its Effects on Thermal Properties and Fire Retardant Behavior
Polymer Engineering & Science 2000, 40, 1177-1189.
- Nagai, K.; Freeman, B. D.; Cannon, A.; Allcock, H. R.
Gas Permeability of Poly(bis-trifluoroethoxyphosphazene) and its Blends with Adamantane Amino/trifluoroethoxy (50/50) Polyphosphazene
- Membrane Science 2000, 172, 167-176.
- Ambrosio, A. M. A.; Allcock, H. R.; Laurencin, C. T.
Degradable Polyphosphazene/Polyester Blend with Self-Neutralizing Potential
Proc. Soc. for Biomaterials 1999, 25, 9.
- Chang, Y.; Bender, J. D.; Phelps, M. V. B.; Allcock, H. R.
Synthesis and Self-Association Behavior of Biodegradable Amphiphilic Poly[bis(ethyl glycinat-N-y)phosphazene]-PEO Block Copolymers
Biomacromolecules 2002, 3, 1364-1369.
- Ambrosio, A. M. A.; Sahota, J. S.; Runge, C.; Kurtz, S. M.; Lakshmi, S.; Allcock, H. R.; Laurencin, C. T.
Novel Polyphosphazene-Hydroxyapatite Composite for Bone Tissue Engineering
Eng. Biol. Magazine, Special Ed., Tissue Eng. 2003, 22, 18-26.
- Greish, Y. E.; Brown, P. W.; Bender, J. D.; Allcock, H. R.; Laurencin, C. T.
Formation of Hydroxyapatite-poly[bis(calcium carboxylatophenoxy phosphazene] Composites at Physiological Temperature
- Biomed. Mater. Res.2006, 77A, 416-425.
- Greish, Y. E.; Bender, J. D.; Lakshmi, S.; Brown, P. W.; Allcock, H. R.; Laurencin, C. T.
Low Temperature Formation on Hydroxyapatite – poly(alkyloxybenzoate)Phosphazene Composites for Biomedical Applications
Biomaterials 2005, 26 (1), 1-9.
- Bhattacharyya, S.; Lakshmi, S.; Bender, J. D.; Greish, Y. E.; Brown, P. W.; Allcock, H. R.; Laurencin, C. T.
Preparation of Poly[bis(carboxylato phenoxy)phosphazene] Non-Woven Nanofiber Mats by Electrospinning
Proc. Mat. Res. Soc. (Plant, A.; Chilkoti, A.; Barron. A. E. ; Wong, J., eds.) 2004, F8.10, 157-163.
- Welna. D. T.; Bender, J. D.; Wei. X.; Sneddon, L. G.; Allcock, H. R.
Preparation of Boron Carbide Nanofibers from Poly(norbornenyldecarb-carborane) Single-Source Precursor via Electrostatic Spinning
Advanced Materials 2005, 17, 859-862.
- Chang, Y.; Welna. D. T.; Allcock, H. R.
Phosphazene-Silicate Hybrid Nework Membranes: Characterization and Applications
Polym. Prepr. (Am. Chem. Soc. Div. Polym. Chem.) 2004, 45, 529-530.
- Chang, Y.; Allcock, H. R.
Synthesis and Characterization of Covalently Interconnected Phosphazene-Silicate Hybrid Network Membranes
Chemistry of Materials 2006, 17, 4449-4454.
- Singh, A.; Steely, L.; Allcock, H. R.
Electrospinning Nanofiber Membranes of Poly[bis(trifluoroethoxy)phosphazene]
Polym. Prepr. (ACS Div. Polym. Chem) 2005, 46(2), 599-600.
- Allcock, H. R.
Fluorine-Containing Polyphosphazenes as Hydrophobic and Superhydrophobic Materials
Polym. Prepr. (ACS Div. Polym. Chem.) 2005, 46(2), 603.
- Allcock, H. R.; Steely, L. B.; Singh, A.
Hydrophobic and Superhydrophobic Surfaces from Polyphosphazenes
Polymer International 2006, 55, 621-625.
- Wei, X.; Welna, D. T.; Bender, J. D.; Sneddon, L. G.; Allcock, H. R.
Design and Syntheses of Poly(norbornenyldecarborane) Precursors to Boron Carbide and Boron-Carbide/Silicon-Carbide Ceramics
Mater. Res. Soc. Symp. Proc. 2005, 848, FF1.8.1-6.
- Welna, D. T.; Wei, X.; Bender, J. D.; Krogman, N. R.; Sneddon, L. G.; Allcock, H. R.
Electrostatic Spinning, Pyrolysis, and Characterization of Boron Carbide Nanofibers Prepared from Poly(norbornenyldecacarborane) – a
Polymerization Ceramic Precursor
Mater. Res. Soc. Symp. 2005, 848, FF6.13.1-6.
- Singh, A., Steely, L., Allcock, H. R.
Electrospinning of Poly[bis(2,2,2-trifluoroethoxy)phosphazene] Superhydrophobic Nanofibers
Langmuir 2005, 21, 11604-11607.
- Allcock, H. R.; Steely, L. B.; Kim, S.; Kang, B.
Plasma Surface Functionalization of Poly[bis(2,2,2-trifluoroethoxy)phosphazene] Films and Nanofibers
Langmuir 2007, 23, 8103-8107
- Steely, L. B.; Li, Q.; Badding, J. V.; Allcock, H. R.
Foam Formation from Fluorinated Polyphosphazenes by Liquid CO2 Processing
Polym. Sci. Eng. 2008, 48, 683-686
- Steely, L. B.; Allcock, H. R.; Kim, S.H.; Kang, B. K.
Plasma Surface Functionalization of Poly[bis(2,2,2-trifluoroethoxy)phosphazene]
Mater. Res. Soc. Symp. 2007, 951E, 0951E-12-41
- Allcock, H. R.; Steely, L. B.; Singh, A.; Hindenlang, M. D.
Hydrophobic and Superhydrophobic Polyphosphazenes
- Adhesion Sci. & Technol 2009, 23, 435-445
- Guron, M. M.; Wei, X.; Welna, D.; Krogman, N.; Kim, M. J.; Allcock, H. R.; Sneddon, L. G.
Preceramic Polymer Blends as Precursors for Boron-Carbide/Silicon-Carbide Composite Ceramics and Ceramic Fibers
Chem. Mater. 2009, 21, 1708-1715
- Weikel, A. L.; Lee, D.; Krogman, N. R.; Allcock, H. R.
Phase Changes of Poly(alkoxyphosphazenes) and their Behavior in the Presence of Oligoisobutylene
- Polym. Sci. Eng. 2010, 92A, 114-125
- Weikel, A. L.; Lee, D. K.; Krogman, N. R.; Allcock, H. R.
Phase Changes in Poly(alkoxyphosphazenes) and their Behavior in the Presence of Oligoisobutylene
Polymer. Eng. and Science 2011, 51, 1693-1700
- Wynne, K. J.; Allcock, H. R.; Presnall, D.; Steely, L. B.
Semicrystalline Polyphosphazenes: A Comparative Study of Topology, Morphology, and Contact Angles for Three Fluorous and One Aryl Poly-phosphazene
Polymer (accepted)
CLATHRATE (MOLECULAR INCLUSION) CHEMISTRY
- Allcock, H. R.
New Reactions of Phosphonitrilic Chloride Trimer. Substitution and Cleavage Reactions with Catechol and Triethylamine
- Am. Chem. Soc. 1963, 85, 4050.
- Allcock, H. R.
Reactions of Phosphonitrilic Chlorides with Catechol and Triethylamine
- Am. Chem. Soc. 1964, 86, 2591‑2595.
- Allcock, H. R.; Siegel, L. A.
Molecular Inclusion Compounds of Tris(o‑phenylenedioxy)phosphonitrilic Trimer
- Am. Chem. Soc. 1964, 86, 5140‑5144.
- Allcock, H. R.; Kugel, R. L.
Cyclized Products From the Reactions of Hexachlorocyclotriphosphazene (Phosphonitrilic Chloride Trimer) with Aromatic Dihydroxy, Dithiol, and
Diamino Compounds
Inorg. Chem. 1966, 5, 1016‑10.
- Allcock, H. R.; Kugel, R. L.
Degradation of Halogenophosphazenes to a New Phosphorane System
- Chem. Soc., Chem. Commun. 1968, 24, 1606‑1607.
- Allcock, H. R.; Stein, M. T.; Stanko, J. A.
The Crystal and Molecular Structure of Tris(2,2’‑dioxybiphenyl)cyclotriphosphazene
- Chem. Soc., Chem. Commun. 1970, 15, 944‑945.
- Allcock, H. R.; Walsh, E. J.
Synthesis of Spirophosphazenes with Five‑, Six‑, and Seven‑Membered Exocyclic Rings at Phosphorus
Inorg. Chem. 1971, 10, 1643‑1647.
- Allcock, H. R.; Stein, M. T.; Stanko, J. A.
The Crystal and Molecular Structure of Tris(2,2’‑dioxybiphenyl)cyclotri‑phosphazene
- Am. Chem. Soc. 1971, 93, 3173‑3178.
- Allcock, H. R.; Stein, M. T.
Clathration by Tris(2,3‑naphthalenedioxy)cyclotriphosphazene. An X‑ray Crystal and Molecular Structure Study
- Am. Chem. Soc..1974, 96, 49‑52.
- Allcock, H. R.; Stein, M. T.; Bissell, E. C.
A p-Xylene Clathrate of Tris(1,8‑naphthalenedioxy)cyclotriphosphazene
- Am. Chem. Soc. 1974, 96, 4795‑4800.
- Allcock, H. R.; Kugel; R. L.; Moore, G. Y.
Mechanism of the Reactions between o‑Dinucleophiles and Cyclophosphazenes
Inorg. Chem. 1975, 14, 2831‑2837.
- Allcock, H. R.
Cyclophosphazene Clathrates‑‑Exploring the Adjustable Tunnel
Accts. Chem. Res. 1978, 11, 81‑87.
- Allcock, H. R.; Ferrar, W. T.; Levin, M. L.
Polymerization in Clathrate Tunnel Systems: Stereo‑Controlled Polymerization of Unsaturated Monomers in Crystals of
Tris(o‑phenylenedioxy)cyclotri‑phosphazene
Macromolecules 1982, 15, 697‑703.
- Allcock, H. R.
Cyclophosphazene Inclusion Adducts
Chapter 8 in “Chemistry of Host‑Guest Complexes,” Academic Press” New York. 1984, 351‑374.
- Allcock, H. R.; Levin, M. L.
The Stereocontrolled Polymerization of Acrylic Monomers Within a Tris‑(o‑phenylenedioxy)cyclotriphosphazene Tunnel Clathrate
Macromolecules 1985, 18, 1324‑1330.
- Allcock, H. R.; Levin, M. L.; Whittle, R. R.
Tris(o‑phenylenedioxy)cyclotriphosphazene: The Clathration‑Induced Monoclinic to Hexagonal Solid State Transition
Inorganic Chemistry 1986, 25, 41‑47.
- Allcock, H. R.; Dudley, G. K.; Silverberg, E. N.
Stereocontrolled Polymerization of Diene Monomers within a Tris(o‑phenylenedioxy)cyclotriphosphazene Tunnel Clathrate
Macromolecules 1994, 27, 1039‑1044.
- Allcock, H. R.; Silverberg, E. N.; Dudley, G. K.
Stereocontrolled Polymerization within a Cyclophosphazene Clathrate Tunnel
Macromolecules 1994, 27, 1033‑1038.
- Allcock, H. R.; Silverberg, E. N.; Dudley, G. K.; Pucher, S. R.
Inclusion Polymerization Within a Tris(2,3‑naphthalenedioxy)cyclitrophosphazene Clathrate
Macromolecules 1994, 27, 7550-7555.
- Primrose, A. P., Parvez, M.; Allcock, H. R.
Inclusion Adduct Formation Between Tris(o-phenylenedioxy)cyclo- and Poly(ethylene oxide) or Polyethylene
Macromolecules 1997, 30, 670-672.
- Allcock, H. R.; Primrose, A. P.; Sunerland, N. J.; Rheingold, A. L.; Guzei, I. A.; Parvez, M.
Inclusion of Polymers with the Crystal Structure of Tris(o-phenylenedioxy)cyclo Recent Developments with an Impact on the Future of
Polyphosphazene Science and Technology
Proc. of Intern. Phosphorus Conf. Phosphorus, Sulfur, and Silicon 1999, 144-146, 61-64.
- Allcock, H. R.; Sunderland, N. J.; Primrose, A. P.; Rheingold, A. L.; Guzei, I. A.; Parvez, M.
A New Host for Polymer and Small-Molecule Clathration
Chemistry of Materials 1999, 11, 2478-2485.
- Allcock, H. R.; Primrose, A. P.; Silverberg, E. N.; Visscher, K. B.; Rheingold, A. L. Guzei, I. A.; Parvez, M.
Synthesis and Crystal Structure of Tris(9,10-phenanthrenedioxy)cyclotri-Phosphazene – A New Clathration System
Chemistry of Materials 2000, 12, 2530-2536.
- Sunderland, N. J.; Allcock, H. R.
Entrapment and Separation of Polymers in Crystalline Host Systems
Polym. Prepr., ACS Div. Polym. Chem. 1999, 40, 750-751.
- Allcock, H. R.; Sunderland, N. J.
Separation of Polymers and Small Molecules by Crystalline Host Systems
Macromolecules 2001, 34, 3069-3076.
- Allcock, H. R.
Clathrate Inclusion Adducts – Molecular Recognition Using Solid State Structures
ACS Petroleum Research Fund 60th Anniversary Commemoration 2004
- Lee, D. K.; Jackson, A.-M.; Fushimi, T.; Allcock, H. R.
Synthesis and Inclusion Behavior of Cyclotriphosphazene Molecules with Asymmetric Spiro Rings
- Chem. Soc., Dalton Trans. 2010, 39, 5341-5348
REVIEW ARTICLES AND BOOK CHAPTERS
- Allcock, H. R.
Phosphonitrilic Chemistry
Chem. and Eng. News 1968, 46, 68‑81.
- Allcock, H. R.
Phosphonitrilic Polymers
Encyclopedia of Polymer Sci. and Techn. 1969, 10, 139‑144.
- Allcock, H. R.
Ring‑Chain Equilibria
- Macromol. Sci. ‑ Revs. Macro. Chem. 1970, C4, 149‑189.
- Allcock, H. R.
Recent Advances in Phosphazene (Phosphonitrilic) Chemistry
Chem. Rev. 1972, 72, 315‑356.
- Allcock, H. R.
Inorganic Polymers
Scientific American, March 1974, pp. 66‑74.
- Allcock, H. R.
Phosphazene High Polymers
Chemistry in Britain, April 1974, pp. 118‑121.
- Allcock, H. R.
Poly(organophosphazenes). A New Class of Applicable High Polymers
Chem. Tech. 1975, 5, 552‑560.
- Allcock, H. R.
Polyphosphazenes: New Polymers with Inorganic Backbone Atoms
Science 1976, 193, 1214‑1219.
- Allcock, H. R.
Poly(organophosphazenes) ‑ Unusual High Polymers
Angew. Chem. 1977, 89 153; Int. Ed. English 1977, 16, 147‑156.
- Allcock, H. R.
Cyclophosphazene Clathrates‑‑Exploring the Adjustable Tunnel
Accounts. Chem. Res. 1978, 11, 81‑87.
- Allcock, H. R.
Poly(organophosphazenes) Designed for Biomedical Uses
Organometallic Polymers, Academic Press, 1978, 283‑288.
- Allcock, H. R.
High Polymeric Organophosphazenes‑‑Macromolecules with a Difference
Contemporary Topics in Polymer Science, Plenum Press, 1979, Vol. 3, 55‑78.
- Allcock, H. R.
Small‑Molecule Rings as Models for High Polymeric Chains
Accounts of Chemical Research 1979, 12, 351‑358.
- Allcock, H. R.
Polyphosphazenes, and the Inorganic Approach to Polymer Chemistry
Science Progress 1980, 66, 355‑369.
- Allcock, H. R.
Polymerization of Cyclic Phosphazenes and Other Inorganic Ring Systems
Polymer 1980, 21, 673‑683.
- Evans, T. L.; Allcock, H. R.
Poly(difluorophosphazene): A New Intermediate for the Synthesis of Poly‑(organophosphazenes)
- Macro. Sci. ‑ Chem. (Proc. of Symp. on Inorganic Macromolecules) 1981, A16(1), 409‑423
- Allcock, H. R.
Controlled Synthesis of Organic/Inorganic Polymers that Possess a Backbone of Phosphorus and Nitrogen Atoms
Makromol. Chem. (Proc. IUPAC Conf. on Macromolecules, Florence, Italy, 1980) 1981, Suppl. 4, 3‑19.
- Allcock, H. R.
Phosphazene Rings and High Polymers Linked to Transition Metals or Biologically‑Active Organic Species
ACS Symp. Ser. (Proc. of Int. Conf. on Phosphorus Chemistry, Durham, N.C., 1981), 1981, 171, 311-314.
- Allcock, H. R.
Cyclic and High Polymeric Phosphazenes as Carrier Molecules for Carboranyl, Metallo, or Bioactive Organic Side Groups
Chapter in “Rings, Clusters, and Polymers of the Main Group Elements ACS Symp. Ser. 1983, 232, 49‑67.
- Allcock, H. R.
Cyclophosphazene Inclusion Adducts
Chapter 8 in “Chemistry of Host‑Guest Complexes,” Academic Press” New York. 1984, 351‑374.
- Allcock, H. R.
Polyphosphazene Elastomers
“Encyclopedia of Science and Engineering,” Pergamon Press: Oxford, 1986, 3787‑3789.
- Allcock, H. R.
Oligomerization and Polymerization
Chapter in “Inorganic Reactions and Methods,” Verlag Chemie 1989
- Allcock, H. R.;
Halogenophosphazene Cyclic Trimers, Tetramers, and High Polymers
Phosphorus and Sulfur, 1983, 18, 267‑270.
- Allcock, H. R.
Ring‑Ring and Ring‑Polymer Interconversions in Phosphorus‑Nitrogen Oligomers and Polymers
Chapter in “Inorganic Reactions and Methods” Verlag Chemie 1989
- Allcock, H. R.;
A New Approach to Polymer Chemistry: Organometallic and Bioactive Phosphazenes
- Polym. Sci., Polym. Symp. 1983, Vol. 70, 71‑77.
- Allcock, H. R.
Inorganic Macromolecules
Chem. and Eng. News, 1985, 63, 22‑36.
- Allcock, H. R.; Desorcie, J. L.; Riding, G. H.
The Organometallic Chemistry of Phosphazenes
Polyhedron 1987, 6, 119‑157.
- Allcock, H. R.
Inorganic Macromolecules and the Search for New Electroactive and Structural Materials
Chapter in “Design of New Materials,” (Eds. E. Cocke and A. Clearfield), Plenum Press, 1987, 67-77.
- Allcock, H. R.
Poly(organophosphazenes). Synthesis, Unique Properties, and Applications
Proc. of 5th Int. Symp. on Ring‑Opening Polymerization, Blois, France, 1986.
Makromol. Chem., Macromol. Symp. 1986, 6, 101‑108.
- Allcock, H. R.
Polyphosphazenes
Chapter in “Encyclopedia of Polymer Science and Engineering (Mark, Bikales, Overberger, Menges, Eds.)
John Wiley & Sons: New York, 1988, Vol. 13, 2nd. Ed., 31‑41.
- Allcock, H. R.
Phosphazene High Polymers
Chapter in “Comprehensive Polymer Science,” (G. C. Eastmond, A. Ledwith, S. Russo, and P. Sigwalt, eds.),
Pergamon Press: Oxford, Vol. 4, 1989, 525‑532.
- Allcock, H. R.
Polyphosphazenes and their Relationship to Ceramics and Metals
Chapter in “Ultra Structure Processing of Advanced Materials (Eds. J. D. Mackenzie, D. R. Ulrich)
John Wiley & Sons: New York, 1988, 705‑713.
- Allcock, H. R.
The Current Status of Polyphosphazene Chemistry
Chapter in “Inorganic and Organometallic Polymers,” (Zeldin, M.; Wynne, K. J.; Allcock, H. R.; eds.)
ACS Symp. Ser. 360, 1988, 250‑267.
- Allcock, H. R.; Brennan, D. J.
Organosilicon Derivatives of Cyclic and High Polymeric Phosphazenes
- Organomet. Chem., 1988, 341, 231‑239.
- Allcock, H. R.
Organometallic and Bioactive Cyclophosphazenes, and the Relationship to Inorganic Macromolecules
Proc. of Int. Symp. on Inorg. Ring Systems, Amherst, Mass., Phosphorus, Sulfur, and Silicon, 1989, 41, 119‑133.
- Allcock, H. R.
Polyphosphazenes as New Biomedical and Bioactive Materials
Chapter in Biodegradable Polymers as Drug Delivery Systems, (R. Langer and M. Chasin, eds),
Marcel Dekker: New York 1990, 163‑193.
- Allcock, H. R.
Polymer Chemistry and Inorganic Materials
The Chemist, January 1990, pp. 10‑16.
- Dembek, A. A.; Allcock, h. r.; Kim, C.; Steir, W. H.; Devine, R. L.s; Shi, Y.; Spangler, C. W.
Second Order Nonlinear Optically-Active Polyphosphazenes Materials for Nonlinear Optics (Marder, S.; Sohn, J. E.; Stucky, G. S., eds.)
ACS Symp. Ser.455, 1991, pp 258-266.
- Allcock, H. R.
The Current State‑of‑the‑Art in the Synthesis of Inorganic and Organometallic Polymers
Proc. of NATO Advanced Research Workshop, Cap d’Agde, France, 1990
Kluwer Academic Publishers, NATO ASI Ser. 206, 1992, 43‑61.
- High Molecular Weight Poly(alkoxy‑ and aryloxyphosphazenes) (1966)
Allcock, H. R. and Kugel, R. L.
A Citation Classic (Institute for Scientific Information)
Current Contents 1991, 22, 10.
- Allcock, H. R.
Materials Synthesis at the Boundary between Polymer Chemistry and Ceramic Science
Chapter in Chemical Processing of Advanced Materials (L. L> Hench and J. K. West, eds.)
John Wiley & Sons, 1992, pp. 699‑716.
- Allcock, H. R.
Polyphosphazenes
Proc. of 1st U.S.‑Japan Conference on Inorganic Polymers, Nagoya, Japan, 1991
- Inorg. and Organomet. Polymers 1992, 2, 197‑211.
- Allcock, H. R.
Ring‑Opening Polymerization in Phosphazene Chemistry
Chapter in “Ring‑Opening Polymerization” (D. J. Brunelle, ed.)
Hanser Publishers, Munich, Germany, 1993, 217‑237.
- Allcock, H. R.
Strained Inorganic Heterocyclic Compounds and their Conversion to Macrocycles and High Polymers
Chapter in “The Chemistry of Inorganic Ring Systems” (R. Steudel, ed.), Elsevier:
Amsterdam, 1992, pp. 145‑169.
- Allcock, H. R.
Tailored Design of New Polyphosphazenes with Special Properties
Proceedings of Second Pacific Polymer Conference, Otsu, Japan, 1991 (Y. Iminishi,ed.) Springer‑Verlag, 1992, pp. 89‑100.
- Allcock, H. R.
Mechanisms and Catalysis in Cyclophosphazene Polymerization
Proceedings of Symp. on Catalysis: A Key to Advances in Applied Polymer
Science (E. J. Vandenberg and J. C. Salamone, eds.), ACS National Meeting, Atlanta, 1991, ACS Symp. Ser.1992, 496, 236‑247.
- Allcock, H. R.
Rational Design and Synthesis of New Polymeric Materials
Science 1992, 255, 1106‑1112.
- Welker, M. F.; Allcock, H. R.; Grune, G. L.; Chern, R. T.; Stannett, V. T.
Radiation‑Induced Modifications of Allylamino‑Substituted Polyphosphazenes
ACS Sym. Ser. 1994, 537, 293‑303.
- Allcock, H. R.
Inorganic‑Organic Polymers and their Role in Materials Science
Advanced Materials 1994, 6, 106‑115.
- Allcock, H. R.
Polyphosphazenes and their Diversity
Chapter 28 in Macromolecular Design of Polymeric Materials (K. Hatada. T. Kitayama, O. Vogl, eds.)
Marcel Dekker: New York, 1996, 477-492.
- Allcock, H. R.
Water‑Soluble Polymers and their Hydrogels
Chapter in Hydrophilic Polymers (J. E. Glass, ed.)
ACS Symp. Ser. 1996, 248, 3-29.
- Allcock, H. R.
Macromolecular and Materials Design Using Polyphosphazenes
ACS Symp. Ser. 1994, 572, 208-231.
- Allcock, H. R.
Cross‑Linking Reactions for the Conversion of Polyphosphazenes into Useful Materials
Chemistry of Materials Review 1994, 6, 1476-1491.
- Allcock, H. R.; Kuharcik, S. E.
Hybrid Phosphazene-Organosilicon Polymers, Part I.
- Inorg. Organomet. Polym.1995, 5, 307-342.
- Flory, P. J.; Allcock, H. R.; Eisenberg, H.; Feldmann, R. J.; Yoon, D. Y.
The Science of Macromolecules
Chapter in Outlook for Science and Technology
National Academy of Sciences Report W. H. Freeman & Co.: San Francisco, 1982.
- Allcock, H. R.; Kuharcik, S. E
Hybrid Phosphazene-Organosilicon Polymers, Part II. High Polymer and Materials Synthesis and Properties
- Inorg. Organ. Polym.1996, 6, 1-41.
- Allcock, H. R.
Design and Synthesis of New Biomaterials via Macromolecular Substitution
Chapter in Bioartificial Organs (A. Prokop, D. Hunkler, A. Cherrington, eds.)
Annals of the New York Academy of Sciences 1997, 831, 13-31.
- Allcock, H. R.; Napierala, M. E.; Olmeijer, D. L.; Cameron, C. G.; Kuharcik, S. E.; Reed, C. S.; O.Connor, S. J. M.
Proc. Intern. Conf. on Solid Polym. Electrolytes, Uppsala, Sweden (J. Thomas, ed.)
Electrochimica Acta 1997, 1-6.
- Allcock, H. R.; Nelson, J. M.; de Denus, C. R.; Manners, I.
Design, Synthesis, and Uses of Phosphazene High Polymers
Proc. 3rd. Internat. Conf. on Advanced Polymers via Macromolecular Engineering, Williamsburg, Virginia, 1999
- Allcock, H. R.
General Introduction to Phosphazenes
Chapter 1 in. Polyphosphazenes: A Worldwide Insight (M. Gleria, R. de Jaeger, eds.)
NOVA Science Publishers 2004 1-22.
- Allcock, H. R.
Ambient Temperature Cationic Condensation of Polyphosphazenes
Chapter 3 in Polyphosphazenes: A Worldwide Insight (M. Gleria, R. de Jaeger, eds.)
NOVA Science Publishers 2004, 49-67.
- Ambrosio, A. M. A.; Sahota, J. S.; Runge, C.; Kurtz, S. M.; Lakshmi, S.; Allcock, H. R.; Laurencin, C. T.
Novel Polyphosphazene-Hydroxyapatite Composite for Bone Tissue Engineering
Eng. Biol. Magazine, Special Ed., Tissue Eng. 2003, 22, 18-26.
- Allcock, H. R.
The Crucial Role of Inorganic Ring Chemistry in the Development of New Polymers
Proc. Intern. Conf. on Inorg. Ring Systems, Burlington, Vermont (C. Allen ed.)Phosphorus, Silicon, and Sulfur 2004, 179, 661-671.
- Allcock, H. R.; Hofmann, M. A.; Ambler, C. M.; Maher, A. E.; Wood, R. M.; Lvov, S.; Zhou, X. Y.; Chalkova, E.; Fedkin, M. W.; Weston, J.
A.
Chapter in special volume of Polymers for Advanced Technology, 2006.
- Allcock, H. R.
Polyphosphazenes
Encyclopedia of Inorganic Chemistry 2nd. ed. Wiley, 2005, 4586-4593.
- Allcock, H. R.
Hybrid Metallocene-Phosphazene Polymers, Chapter in special issue of
Journal of Inorganic and Organometallic Polymers 2005, 15 (1), 57-65.
- Sethuraman, S.; Nair, L. S.; Singh, A.; Bender, J. D.; Greish, Y. E.; Allcock, H. R.; Laurencin, C. T.
Development of Novel Biodegradable Amino Acid Ester Based Polyphosphazene-Hydroxyapatite Composites for Bone Tissue Engineering
Chapter in Applications of Micron and Nanoscale Materials for Biology and Medicine: Proc. of Mater. Res. Soc (in press).
- Allcock, H. R.
A Perspective of Polyphosphazene Research
- Inorganic and Organometallic Polymers and Materials2005 (in press)
- Allcock, H. R.
New Approaches to Hybrid Polymers that Contain Phosphazene Rings
- Inorganic and Organometallic Polymers and Materials 2006 (in press)
- Allcock, H. R.
Recent Developments in Polyphosphazene Materials Science
Current opinion in Solid State & Mater. Science 2007, 10, 231-240
- Allcock, H. R.; Steely, L. B.; Singh, A.; Hindenlang
Hydrophobic and Superhydrophobic Polyphosphazenes
Chapter in Superhydrophobic Surfaces (A. Carre, and K. L. Mittal, eds) VSP Publ., Leiden, The Netherlands, 2009, 127-138.
- Allcock, H. R.
Expanding options in Polyphosphazene Biomedical Research
Chapter 2 in Polyphosphazenes for Biomedical Applications (A. Andrianov, ed.) John Wiley & Sons, 2009, 15-43
- Allcock, H. R.
Hybrids of hybrids: Nanoscale Combinations of Polyphosphazenes with Other Materials
- Appl. Organomet. Chem. 2010, 24, 600-607
- Allcock, H. R.
General Overview of Polyphosphazenes
Chapter in Polymer Handbook (J. E. Mark, ed.) Oxford University Press (in press)
- Allcock, H. R.; Morozowich, N. L.
Bioerodible Polyphosphazenes and their Medical potential
Royal Soc. Chem. 2012, 3, 578-590
- Allcock, H. R.
Polyphosphazene Elastomers, Gels, and Other Soft Materials (invited review)
Soft Matter 2012, 8, 7521-7532
P1. “Vinylphosphine Oxides”
- R. Allcock
Fr. Patent 1,367820 (1964) to American Cyanamid Co.)
P2. Trispiro[1,3,5,4,6-triazatriphosphorine-2-2’:4.2”,6.2”-tris[1,3,2]benzodioxy-phospholes”
- R. Allcock
U.S. Patent 3,294,872 (1966) (to American Cyanamid Co.)
P3. “Cyclic Phosphonitrilic Compounds”
- R. Allcock and R. L. Kugel
U.S. Patent 3,299,128 (1967) (to American Cyanamid Co.)
P4. “Allylazaphosphorine Compounds and Polymers”
- R. Allcock and W. M. Thomas
U.S. Patent 3,329,663 (1967) (to American Cyanamid Company)
P5. “Phosphonitrilic Chloride Trimer-Dihydroxy Compound Reaction Products”
- R. Allcock
U.S. Patent 3,356,769 (1967) (to American Cyanamid Company)
P6. “Reactions of Phosphonitrilic Chloride”
- R. Allcock and R. L. Kugel
U.S. Patent 3,364,189 (1968) (to American Cyanamid Company)
P7. “Process for the Production of Phosphonitrilic Polymers and Polymers Produced
Thereby”
- R. Allcock and R. l. Kugel
U.S. Patent 3,370,020 (1968) (to American Cyanamid Company)
P8. “Crosslinking of Phosphazene Polymers”
- R. Allcock
U.S. Patent 3,732,175 (1973) (to the Firestone Tire and Rubber Company)
P9. “Preparation of Phosphazene Polymers”
- R. Allcock
U.S. Patent 3,888,800 (1975) (to the Firestone Tire and Rubber Co.)
P10 “Poly(amino acid ester phosphazenes)”
- R. Allcock, K. M. Smeltz, and D. P. Mack
U.S. Patent 3,893,980 (1975) (to the Pennsylvania State University)
P11. “Molecular Weight Control in (NPCl2) Polymerization”
- R. Allcock and J., E. Gardner
U.S. Patent 3,917,802 (1975) (to the Firestone Tire and Rubber Company)
P12. “Use of Water as a Catalyst for the Polymerization of Chlorocyclophosphazenes”
- R. Allcock, K. M. Smeltz, and J. E. Gardner
U.S. Patent 3,937790 (1976) (to the Firestone Tire and Rubber Co.)
P13 “Complex or Salt of a Platinum(II) Compound and a Nitrogen-Containing Polymer”
- R. Allcock, R. W. Allen, and J. P. O’Brien
U.S. Patent 4,151,185 (1979) (to the Pennsylvania state University)
P14. “Poly(monoalkyl Group Containing Organophosphazenes) and Methods for their Preparation”
- R. Allcock and R. J. Ritchie
U.S. Patent 4,237,263 (1980) (to the Firestone Tire and Rubber Company)
P.15 “Steroidal Cyclotriphosphazenes”
- R. Allcock, T. J. Fuller, and K. Matsumura
U.S. Patent 4,239,755 (1980) (to the U.S. Dept. of Health, Education & Welfare)
P.16 “Colored Polymers Comprising Poly(organophosphazenes) with Chromophores as Substituent Groups”
- R. Allcock, K. M. Kosydar, and S. D. Wright
U.S. Patent 4,242,499 (1980) (to the Firestone Tire and Rubber Company)
P17. “Alkylated Phosphazene Oligomers and Polymers, and Method of Preparation Thereof”
- R. Allcock and P. J. Harris
U.S. Patent 4,258,172 (1981) (to the U.S. Department of the Navy
P18. “Process for the Preparation of Polycarboranylphosphazenes”
- R. Allcock, J. P. O’Brien, A. G. Scopelianos, and L. L. Fewell
U.S. Patent 4,276,403 (1981) (to NASA)
P19. “Complex or Salt of a Platinum(II) Compound and a Nitrogen-Containing Polymer”
- R. Allcock, R. W. Allen, and J. P. O’Brien
U.S. Patent 4,278,660 (1981) (to the Pennsylvania Research Foundation)
P20. “Carboranylcyclotriphosphazenes and Their Polymers”
- R. Allcock, J. P. O’Brien, A. G. Scopelianos, and L. L. Fewell
U.S. Patent 4,288,585 (1981) (to NASA)
P21. “Dialkylated Phosphazene Oligomers and Method of Preparation Thereof”
- R. Allcock and P. J. Harris
U.S. Patent 4,321,217 (1982) (to the U.S. Department of the Navy)
P22. “Phosphorus-Containing Polymers as Carriers for Transition Metals”
- R. Allcock, T. J. Fuller, and T. J. Evans
U.S. Patent 4,387,208 (1983) (to the U.S. Department of the Navy)
P23. “Polymer-Bound Dyes Prepared by Diazo Coupling Reactions with Poly-
(organophosphazenes)”
- R. Allcock and P. E. Austin
U.S. Patent 4,412066 (1984) (to the U.S. Departmentof Health & Human Services)
P24. “Coupling of Poly(organophosphazenes) to Carboxylic Acid”
- R. Allcock, T. X. Neenan, and W. C. Kossa
U.S. Patent 4,440,921 (1984) (to the U.S. Department of Health & Human Services)
P25. “Heparinized Poly(organophosphazenes)”
- R. Allcock and T. X. Neenan
U.S. Patent 4,451,647 (1984) (to the Pennsylvania Research Foundation)
P26. “Pyridine Phosphonitrilic Halide Trimer Process”
- R. Allcock, S. J. Stinnett, J. B. Tedder, and J. R. Adams
U.S. Patent 4,656,017 (1987) (to Ethyl Corporation)
P27. “Anesthetic Poly(organophosphazenes)”
- R. Allcock and T. X. Neenan
U.S. Patent 4,451,647 (1985) (to the Pennsylvania Research Foundation)
P28. “Anesthetic Poly(organophosphazenes”
- R. Allcock and T. X. Neenan
U.S. Patent 4,636,387 (1987) (to the Pennsylvania Research Foundation)
P29. “Water-Soluble Phosphazene Controlled Release Articles”
- R. Allcock and S. Kwon
U.S. Patent 4,880,622 (1989) (to the Pennsylvania Research Foundation)
P30. “Poly(organophosphazene) Polymers with Stable Hydrogels that Can Be Used to Produce Membranes”
- R. Allcock and S. Kwon
U.S. Patent 5,053,451 (1991) (to the Pennsylvania Research Foundation)
P31. “Polycarbophosphazenes”
- R. Allcock, I. Manners, G. Renner, and O. Nuyken
U.S. Patent 5,093,438 (1992) (to the Pennsylvania Research Foundation)
P32. “Method for Forming Polythiophosphazene Macromolecules”
- R. Allcock, J. A. Dodge, I. Manners, G. Renner, and O, Nuyken
U.S. Patent 5,101,003 (1992) (to the Pennsylvania Research Foundation)
P33. “Ionically-Crosslinked Polymeric Microcapsules”
- Cohen, C. Bano, K. B. Visscher, M. Chow, H. R. Allcock, and R. S. Langer
U.S. Patent 5,149,543 (1992) (to M.I.T. and the Pennsylvania Research Corporation)
P34 “Method for Forming Polythiophosphazene Macromoleculs”
- R. Allcock, J. A. Dodge, I. Manners, G. Renner, and O. Nuyken
U.S. Patent 5,101,003 (1992) (to the Pennsylvania Research Corp.)
P35 “Ionically-Crosslinked Polymeric Microcapsules”
- Cohen, C. Bano, K. B. Visscher, M. Chow, H. R. Allcock, and R. S. Langer
U.S. Patent 5,149,543 (1992) (to M.I.T. and he Pennsylvania Research Corporation).
P36. “Composition Used as Bioreactor for Antibody-Comprised Material Encapsulated in Microcapsule Including Ionically-Crosslinked Polymer Gel”
WO 9,205,778A (1992) (to M.I.T. and the Pennsylvania Research Corporation)
P37. “Ionically-Cross-Linked Polymeric Microcapsules”
- Cohen, C. Bano, K. B. Visscher, M. B. Chow, H. R. Allcock, and R. S. Langer
U.S. Patent 5,308,701 (1994) (to M.I.T. and the Pennsylvania Research Corporation)
P38. “Crosslinking Battery Elecrolytes by UV-Radiation”
- R. Allcock, C. J. Nelson, and W. D. Coggio
U.S. Patent 5,414,025 (1995) (to the Penn State Research Foundation)
P39. “Polyphosphazene Blends”
- R. Allcock and K. B. Visscher
U.S. Paent 5,457,160 (1995) (to the Penn State Research Foundation)
P40. “Photocrosslinkable Polyphosphazenes and their Use as Microencapsulation Materials”
- R. Allcock, C. G. Cameron, and D. E. Smith
U.S. Patent 5,464,932 (1995) (to the Penn State Research Foundation)
P41. “Gas-Filled Polymeric Microbubbles for Ultrasound Imaging”
- Cohen, A. Andrianov, M. Wheatley, H. R. Allcock, and R. S. Langer
U.S. Patent 5,487,390 (1996) (to MIT and the Penn State Research Foundation)
P42. “Ionically-Crosslinked Polymeric Microcapsules”
- Cohen, C. Bano, K. B. Visscher, M. Chow, H. R. Allcock, and R. S. Langer
U.S. Patent 5,494,682 (1996) (to MIT and the Penn State Research Foundation)
P43. “Sulfonation of Polyphosphazenes”
- R. Allcock, E. H. Klingenberg, and M. F. Welker
U.S. Patent 5,548,060 (1996) (to the Penn State Research Foundation)
P44. “Polymeric Microcapsules Containing Agents for Imaging”
- Cohen, A. K. Andrianov, M. Wheatley, H. R. Allcock, and R. S. Langer
U.S. Patent 5,562,099 (1966) (to MIT and the Penn State Research Foundation)
P45. “Polyphosphazene Polyelectrolytes as Immunoadjuvants”
- R. Allcock, A. K. Andrianov, R. S. Langer, and K. B. Visscher
U.S. Patent 5,562909 (1966) (to MIT, Virus Research Institute, and the Penn State Research Foundation)
P46. “Polyphosphazenes Bearing Crown Ether and Related Podand Side Groups as Solid Solvents or Ionic Conduction”
- R. Allcock, S. J. M. O’Connor, M. E. Napierala, C. G. Cameron, and D. J. Olmeijer
U.S. Patent 5,567,783 (1996) (to the Penn State Research Foundation)
P47. “Synthesis of Polyphosphazenes with Controlled Molecular Weight and Polydispersity”
- R. Allcock, C. T. Morrissey, I. Manners, and C. H. Honeyman
U.S. Patent 5,698,664 (1997) (to the Penn State Research Foundation and the University of Toronto)
P48. “Polyphosphazenes with Unsaturated Side Groups Useful as Research
Intermediates, Crosslinkable polymers, and as Components of Interpenetrating Polymer Networks”
U.S. Patent 5,747,604 (1998) (to the Penn State research Foundation)
P49. “Poly(organophosphazene) Hydrogels”
- R. Allcock and A. M. A. Ambrosio
U.S. Patent 5,898,062 (1999) (to the Penn State Research Foundation)
P50. “Synthesis of Polyphosphazenes with Controlled Molecular Weight and Polydispersity”
- R. Allcock, C. T. Morrissey, I. Manners, C. H. Honeyman, J. M. Nelson, C. A. Crane, S. D. Reeves, A. P. Primrose, T. J. Hartle, and R. Prange
U.S. Patent 5,914,388 (1999) (to the Penn State Research Foundation)
P51. “Blends of Polyurethane and Polyphosphazene and their Use as Flame-Retardant Foamed Compositions”
- R. Allcock, J. P. Taylor, M. M. Coleman, and K. S. Guigley
U.S. Patent 5,965,627 (1999) (to the Penn State Research Foundation)
P52. “Biodegradable Mixtures of Polyphosphazene and Other Polymers”
- Laurencin, H. R. Allcock, S. Ibim, A. M. A. Ambrosio, and M. Kwon
U.S. Patent 6,077,916 (2000) (to the Penn State Research Foundation)
P53. “Phosphorylation of Phosphazenes”
- R. Allcock and J. P. Taylor
U.S. Patent 6,093,758 (2000) (to the Penn State Research Foundation)
P54. “Poly(organophosphazene) Matrices for Bone Replacement”
- T. Laurencin, S. El-Amin, A. M. A. Ambrosio, S. R. pucher, and H. R. Allcock
U.S. Patent 6,235,061 (to Penn State and The University of Virginia)
P55. “Phosphinimine Modification of Organic Polymers and Silicones”
- R. Allcock, T. J. Hartle, M. B. McIntosh, N. J. Sunderland, R. Prange, and J. P. Taylor
U.S. Patent 6,339,166 (2002) (to the Penn State Research Foundation
P56. “Polyphosphazene Polymers”
- R. Allcock, R. Prange, C. de Denus, J. Nelson, W. Laredo, and S. Reeves
U.S. Patent 6,392,008 (2002) (to the Penn State Research Foundation)
P57. “pH-Dependent Membrane Diffusion”
- R. Allcock, J. D. Bender, R. Hammerstedt, S. Schwartz, and W. Laredo
- S. Patent 6,558,546 B2 (2003) (to the Penn State Research Foundation)
P58. “Polyphosphazenes as Gel Polymer Electrolytes”
- R. Allcock, E. C. Kellam, and R. V. Morford
U.S. Patent 6,605,237 (2003) (to the Penn State Research Foundation)
P59. “Proton Conducting Polymer Membranes”
- R. Allcock, M. A. Hofmann, S. N. Lvov, X. Y. Zhou, and D. Macdonald
U.S. Patent 6,759,157 (2004) (to the Penn State Research Foundation)
P60 “Polymeric Nanofibers for Tissue Engineering and Drug Delivery”
- T. Laurencin, L. S. Nair, S. Bhattacharya, H. R. Allcock, J. D. Bender, P. W. Brown, and Y. E. Greish
U.S. Patent 7,235,295 (2007).
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