Publication Archive
For an up-to-date list, please check here. We are working on posting final versions of papers after the necessary embargo through Penn State’s ScholarSphere repository. To access, simply click on the DOI link to go to the journal page or the “available here” link to the version posted at Penn State. Papers published prior to 2020 are available through the Trinity University Digital Commons.
2023
Entropy Driven Hydrogen Spillover on Au/TiO2Mahdavi-Shakib, A; Whittaker, T; Yun, TY; Kumar, S; Rich, LC; Wang, S; Rioux, RM; Grabow, LC; Chandler, BD* “The Role of Surface Hydroxyls in the Entropy Driven Adsorption and Spillover of H2 on Au/TiO2 Catalysts”, Nature Catalysis, 2023, v6, p710-719
DOI: 10.1038/s41929-023-00996-3
Tae Yong Yun and Bert D. Chandler “Surface Hydroxyl Chemistry of Titania- and Alumina-Based Supports: Quantitative Titration and Temperature Dependence of Surface Brønsted Acid–Base Parameters” ACS Applied Materials and Interfaces, 2023, v15, p6868-6876.
2021
Mahdavi-Shakib, A; Rich, Lauren C; Wittaker, TN; Chandler, BD* “Hydrogen Adsorption on Au/TiO2 Catalysts: Quantitative Determination and Spectroscopic Signature of the Reactive Interface Hydroxyl Groups at the Active Site” ACS Catalysis, 2021, v11, p15194–15202.
H2 Adsorbs via Heterolytic H-H Activation across the at the Metal-Support Interface
Mahdavi-Shakib, A; Kumar, S; Whittaker, T; Grabow, LC; Chandler, BD* “Kinetics of H2 Adsorption at the Metal-Support Interface of Au/TiO2 Catalysts probed by Broad Background IR Absorbance” Angewandte Chemie International Ed, 2021, v60, p7735-7743
IR Spectra collected during D2 Adsorption on a Au/TiO2 Catalyst
2020
Kumar, S; Whittaker, T; Peterson, C; Grabow, LC; Chandler, BD*; “Water Poisons H2 Activation at the Au-TiO2 Interface by Slowing Proton and Electron Transfer between Au and Titania” Journal of the American Chemical Society, 2020, v124, p 5760-5772 (DOI: 10.1021/jacs.9b13729).
Bruno, J; Dwarica, N; Whittaker, T; Hand, ER; Guzman, CJ; Dasgupta, A, Chen, Z; Rioux, RM; Chandler, BD*; “Supported Ni-Au colloid precursors for active, selective, and stable alkyne partial hydrogenation catalysts” ACS Catalysis, 2020, v10, p2565-2580 (DOI: 10.1021/acscatal.9b05402).
Mahdavi-Shakib, A; Sempel, J; Babb, L; Oza, A; Hoffmann, M; Whittaker, T; Chandler, BD*; Austin, RN* “Combining benzyl alcohol oxidation saturation kinetics and Hammett studies as mechanistic tools for examining supported metal catalysts” ACS Catalysis, 2020, v10, p10207−10215 (DOI: 10.1021/acscatal.0c02212).