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Publications

Below you can find a searchable list of my publications sorted by date. My Google Scholar profile and ResearchGate profile contains an up-to-date overview of my work.

 

2022

Livio Santos, Arash Dahi Taleghani, Derek Elsworth

Repurposing Abandoned Wells for Geothermal Energy: Current Status and and Future Prospects

Renewable Energy

A debate rages as to whether abandoned oil and gas wells have to be sealed to prevent methane leakage – a potent greenhouse gas – or whether the valuable infrastructure can be repurposed for environmental benefit. One viable solution is to repurpose such wells for the recovery of low-grade geothermal energy and simultaneously produce a revenue stream, staunch fugitive emissions and maintain workforce engagement. This avoids the major upfront costs of drilling and significant risks of non-transmissive reservoirs that remain major obstacles in the development of geothermal energy. Regions of extensive hydrocarbon exploration are often close to market and with significant geothermal gradients. Repurposing must accommodate local energy demand, potential markets, existing infrastructure and technical challenges. So far, most studies have been scattered or focused on the viability of converting a specific oilfield. This work integrates the accomplishments and key challenges faced from projects that converted hydrocarbon production in geothermal renewable energy and establish guidelines to assist future projects. Conversion strategies are discussed for open-loop systems with co-production and enhanced geothermal systems and for true closed-loop systems. Five key challenges relate to well selection, data availability, underground infrastructure, well integrity and regulatory factors. Potential challenges in inspection and preparation of these wells in terms of well integrity and productivity with possible remedies are also discussed. Pilot projects and feasibility studies that have been performed worldwide confirm the viability of this concept but at low efficiency, paving the way for future innovations in this area.

Website | DOI:10.1016/j.renene.2022.05.138

2021

Arash Dahi Taleghani, Livio Santos

Application of Shape Memory Polymers in the Oil & Gas Industry

Elsevier Reference Module in Materials Science and Materials Engineering

Hydrocarbon exploration and exploitation may occur in challenging environments, which require innovative solutions to lower the costs and risks of operations. SMPs are finding an increasing number of applications in the upstream oil & gas industry, where they respond dynamically to changes in downhole temperature. This article will provide readers with a review of the fundamentals of oil & gas operations, including drilling, completion and stimulation of wells, and a comprehensive coverage of design and testing of SMPs for each operation.

Website | DOI:10.1016/B978-0-12-820352-1.00189-9


Livio Santos, Arash Dahi Taleghani

Machine learning framework to generate synthetic cement evaluation logs for wellbore integrity analysis

55th US Rock Mechanics/Geomechanics Symposium

Proper zonal isolation is key to ensure optimum injection and production and it is highly dependent on the cement bond to the casing and the formation. Yet, in most wells, cement evaluation logs are not run. This work will describe a workflow to address the lack of cement evaluation data by creating synthetic logs to aid wellbore integrity analysis. Synthetic logs can be a reliable and cost-effective alternative to predicting the cement bond than running log tools in every well during a drilling campaign, and, with further development, has the potential to be used for well design. A machine learning framework based on Gaussian process regression (GPR) was chosen in the development of this procedure because it can assess uncertainty of the cement bond through estimation of error and confidence interval. GPR also require less training samples than conventional machine learning techniques. In this work CBL data was used for training and the model was validated through comparison with data from a different well in the same field. The results shows that the predicted case correlated very well with the base case, with some curves overlaying even in the poor bond sections. Initial assumptions given by the covariance function help capture not only the general trend relationship but also localized variations, which play a major role in the way a fracture propagates in the annulus. Additionally, the uncertainty assessment provided by this framework can assist risk management by determining worst case scenarios and potential fluid migration paths in the annulus.

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Livio Santos, Arash Dahi Taleghani

On Quantitative Assessment of Effective Cement Bonding to Guarantee Wellbore Integrity

Journal of Energy Resources Technology

Methane leakage due to compromised wellbore cement integrity may result in operational complications and environmental contaminations in oil and gas wells. In this work, the problem of fluid-driven fracture propagation at the cement interfaces is revisited by a thorough and comprehensive consideration of the non-uniform cement bonding to the formation along the wellbore. While previous works were mainly focused on discharge without attention to mechanical failure or mechanical failure without ties to seepage rate; here, we couple these two analyses to provide a practical aspect of this approach. As revealed by cement evaluation logs, the quality of the cement behind the casing varies and may include flaws in the form of channels or pockets of mud residuals. A novel methodology, initiated with laboratory-scale cement bonding properties using the push-out test, is introduced to estimate the cohesive properties of the cement interface, considering mud removal and mud residuals in the rock. Then, the measured cohesive properties are applied to a field-scale numerical model with an embedded cohesive layer between cement and formation to evaluate the susceptibility of the wellbore to develop cement debonding. The excessive fluid pressure at the casing shoe is assumed to be the source for the fracture initiation. The proposed numerical model has been tested against actual sustained casing pressure (SCP) field tests for validation purposes. This model may estimate the geometry of leakage pathways and predict leakage flowrate within acceptable ranges. The effect of several key factors in the development of SCP due to the cement debonding is investigated. The results show that the early stage of SCP buildup is controlled by the cohesive properties of the cement interfaces (i.e., cement properties), but the cohesive properties have minor effects on the stabilized pressure. The method proposed herein presents a method to evaluate the cement bond quantitatively to be further integrated into cement design.

Website | DOI: 10.1115/1.4050878


Maryam Tabatabaei, Arash Dahi Taleghani, Yuzhe Cai, Livio Santos, Nasim Alem

Surface Modification of Proppant Using Hydrophobic Coating To Enhance Long-Term Production

SPE Production & Operations

Proppant bed can play a critical role in enhancing oil and gas production in stimulated wells. In the last 2 decades, there have been consistent efforts to improve shape characteristics and mechanical strength properties to guarantee high permeability in the resultant propped fracture. However, engineering the surface properties of proppants, such as tuning their wettability, has not received considerable attention. Considering that water-wet proppants can not only limit production because of reduced hydrocarbon relative permeability but also facilitate fines migration through the proppant bed, a methodology is presented here to alter the wettability of proppants using graphite nanoplatelets (GNPs). The idea benefits from the intrinsic hydrophobicity of graphitic surfaces, their relatively low cost, and their planar geometry for coating proppants. Conductivity tests are conducted according to ISO 13503-5:2006 (2006) and API RP 19D (2008) to examine how the coating process changes the relative permeability to water and oil. According to the simulation results, the newly developed graphite-coated proppants speed up the water cleanup and increase long-term oil production in an oil-wet reservoir.

Website | DOI: 10.2118/196067-PA


Livio Santos, Arash Dahi Taleghani, Guoqiang Li

Nanosilica-Treated Shape Memory Polymer Fibers to Strengthen Wellbore Cement

Journal of Petroleum Science and Engineering

To attain cement sheath integrity, a tight and ductile microstructure for the cement matrix is desirable. Despite improvements achieved in cement design by employing fiber additives, limitations such as low compressive strength and formation of weak regions may result in fracture initiation points in the cement matrix. In this work we grafted silica nanoparticles on the surface of expandable polymer fibers through a sol-gel process to improve the bonding with the cement matrix and inhibit the formation of weak points in the cement sheath. Considering water-phobic nature of some of these polymeric surfaces, hydrophilic coating of fibers may improve their adhesions to the water-based cement, significantly. The mechanical performance of the samples made of treated fibers are characterized by means of compressive strength, flexural strength, and cyclic loading. Cement samples with nanosilica-treated fibers demonstrated superior results in all mechanical tests in comparison to samples made from untreated fibers. Even at low concentrations, such as 2% by weight, higher flexural strength is observed in the cement with the treated fibers. We also noticed that the flexural strength increases proportionally to the fiber concentration. Therefore, the concentration of additives may be tailored to deter crack propagation in accordance with the other requirements of the cementing operation. The expansive capabilities and rheological properties of the cement are maintained after the surface treatment. The results also demonstrate that the damage to the cement during cyclic loading is reduced when the cement is reinforced with treated fibers that can be interpreted as improved resiliency which is critical in the wells undergone frequent pressure fluctuations during hydraulic fracturing treatments.

Website | DOI: 10.1016/j.petrol.2020.107646


2020


Jizhou Fan, Livio Yang Santos, Arash Dahi Taleghani, Guoqiang Li

Stimuli-Responsive Petroleum Cement Composite With Giant Expansion and Enhanced Mechanical Properties

Construction and Building Materials

Shrinkage, as an inherent property of cement during the curing process, has been a concern in the oil & gas industry for centuries. Therefore, expansive cement has been studied for many decades, primarily through incorporation of expansive additives. Nevertheless, traditional expansive additives are not able to achieve the required expansive ratio or maintain a good mechanical property for the cement composite at extreme underground condition. Accordingly, a new generation of expansive additive, which not only has the required expansion, but also work at the downhole high temperature and high pressure environment, and maintain or even enhance the mechanical property, is highly desired. In this study, a high enthalpy storage shape memory polymer (SMP) as a new class of expansive additive is investigated. It is found that the cement composite achieves 1.4% circumferential expansion by only 6% by weight of SMP additives. The compressive strength and flexural strength are also enhanced at the same time, which is hardly achievable by other expansive additives with the same concertation. Good pumpability is also proved by rheological study. The mechanism controlling the enhanced properties is reveled through morphological study and element mapping analysis at the SMP/cement interface.

Website | DOI: 10.1016/j.conbuildmat.2020.119783


Livio Santos, Arash Dahi Taleghani, Guoqiang Li

Smart Expandable Fiber Additive to Prevent Formation of Microannuli

SPE Drilling & Completion

One of the critical issues that occur in many oil and gas wells is the failure of the cement sheath because of debonding from the casing string or from the formation. This results in the formation of microannuli, which can become pathways for fluid migration. Cement shrinkage during setting is regarded as one of the main causes of the formation of microannuli. In this paper, a new class of polymer‐based expandable additives in the form of fibers is incorporated into the cement to compensate for shrinkage and thereby help prevent the formation of microannuli in oil and gas wells. The proposed fiber additives are made from shape‐memory polymers (SMPs) and expand when exposed to temperatures above a specific value that is, by design, below the downhole temperature of the cemented zone. Fiber expansion occurs after the placement of the cement slurry but before its setting to avoid the inducement of any microfractures. As a result of the expansion of the cement paste, flow channels and fluid migration may significantly decrease while preserving the mechanical properties required for the mechanical integrity of the cement sheath. The bridging effect of fibers across individual microcracks helps control the propagation and coalescence of small fractures. Considering the inert property of the proposed additive, the water‐cement ratio and its chemical properties do not need to be revisited. The measured increase in cement ductility makes the cement system more resistant to cracking. The cement expansion, fluid loss, gel strength, compressive strength, ductility, and tensile strength of the samples containing these fibers are examined using destructive and nondestructive methods, as reported here. The proposed class of expandable additives can help operators reach sustainable well integrity by increasing the contact stress at the cement–casing and the cement–formation interfaces to prevent fluid migration and the propagation of cracks.

Website | DOI: 10.2118/201100-PA


Livio Santos

A Comprehensive Wellbore Cement Integrity Analysis and Remedies

PhD Dissertation

Oil well cement is used to fill the annulus between casing and formation, and provide zonal isolation. The wide-spread hydraulic fracturing treatments in unconventional resources, recent development of deep-water and ultra-deep gas reservoirs, requires wellbore integrity as a critical factor to assure the safety in operations as well as protecting reserves and environments at the same time. Cement specifications are usually determined based on the uniaxial compressive strength (UCS) of the cured cement sample and its density. UCS by itself however, has little impact on assessing sealing capability of the cement under possible various loading conditions that casing and the cement sheath may experience during production life and after that. Basically, compressional strength is only representing one of the main functions of the cement sheath in the well, to ensure both structural support for the casing and borehole. The failure in sealing the annulus has been thought to be initiated by poor bonding of the cement to casing or formation rock. Poor bonding may lead to the development of microannulus cracks throughout cement setting process, or later during fracturing or events inducing intensive thermal stresses. Due to the lack of standard tests in current well construction codes, the experiments proposed in this work will provide a basic step to understand the debonding process. To fill the gap between lab experiments and field-scale problems, we propose the use of numerical simulations. Among the different methods available, cohesive zone model was chosen due to its simplicity and ability to describe in full the progressive debonding process. The experimental results will then be used to obtain cohesive interface parameters by matching them with outcomes from numerical finite element simulation. Finally, these parameters, such as cohesive strength and cohesive stiffness, are used to implement a cohesive interface model in order characterize the behavior of cement interfaces at field-scale wellbores and verify the susceptibility of annular pressure build-up. Having a framework for measuring cement bonding will allow us to measure the effect of different parameters on cement integrity. Cement debonding can lead to uncontrolled fluid migration and compromise wellbore integrity. Hence, an additive is proposed and tested using the proposed technique to quantify improvement of the cement properties. The additive is a novel material that can expand to compensate cement shrinkage. As a result of the expansion of the cement paste, flow channels and fluid migration may significantly decrease. A big concern with expansive cement additives used in the oil and gas industry is the mechanical properties. In order to further enhance the performance of the additive, a treatment to deposit nano-silica particles in the surface of the additive is conducted. The treatment can improve the adhesion of the additive to the cement to provide a tight and ductile microstructure of the cement matrix.

Website


2019


Maryam Tabatabaei, Arash Dahi Taleghani, Yuzhe Cai, Livio Yang Santos, Nasim Alem

Using Nanoparticles Coating to Enhance Proppant Functions to Achieve Sustainable Production

SPE Annual Technical Conference and Exhibition

Proppant bed plays a critical role in enhancing oil and gas production in stimulated wells. In the last two decades, there have been consistent efforts to improve shape characteristics and mechanical strength properties to guarantee high permeability in the resultant propped fracture. However tuning wettability of proppants have not yet engineered considerably maybe because natural sand has been a typical raw material for proppant manufacturing. However, water wet proppants may not only limit production due to reduced hydrocarbon relative permeability but also facilitate fine migration through the proppant bed. Fine migration and increasing water saturation may deteriorate oil production over time. Intrinsic hydrophobicity of graphitic surfaces and their two-dimensional geometries made them a promising candidate for coating proppant to alter its wettability. In this paper, we present a methodology for treating proppant surfaces with graphite nanoplatelets. Standard laboratory tests following modified API RP61 have conducted to show the effectiveness of the proposed methodology.

Website | DOI: 10.2118/196067-MS


Livio Santos, Anwar Alghamdi, Arash Dahi Taleghani

Experimental Evaluation of the Impact of Oil-Based Mud Residuals on Cement-Formation Bonding Strength

AADE National Technical Conference and Exhibition

One of the critical issues that might happen in some oil and gas wells is the failure of the cement sheaths and its debonding from the casing string. Cement shrinkage during setting is regarded as one of the main causes behind formation of microannulus cracks. In this paper, a new class of polymer-based expandable additives is presented in the form of fibers to address shrinkage and debonding issues in the subsurface. The proposed fiber additives are made from shape memory polymers. These fibers expand upon exposure to temperatures above certain limits; which is selected to be below the temperature of the cementing zone. In this situation, the expansion occurs before the cement setting but after its placement. If the expansion occurs after cement setting, it may lead to microfractures. As a result of the controlled expansion of the cement paste, the creation of channels and fluid migration can be minimized while maintaining the mechanical properties required for cement integrity. Considering the inert property of the proposed additive, the cement water ratio and its chemical properties do not change. The cement expansion, fluid loss, gel strength, compressive strength, and tensile strength of the samples containing these fibers are examined by destructive and non-destructive methods and presented here. The proposed class of expandable additives can help the operators reach sustainable well integrity by improving the bonding between the cement and casing.

Website


2018


Livio Santos, Arash Dahi Taleghani, Guoqiang Li

Smart Expandable Polymer Cement Additive to Improve Zonal Isolation

SPE/AAPG Eastern Regional Meeting

One of the critical issues that might happen in some oil and gas wells is the failure of the cement sheaths and its debonding from the casing string. Cement shrinkage during setting is regarded as one of the main causes behind formation of microannulus cracks. In this paper, a new class of polymer-based expandable additives is presented in the form of fibers to address shrinkage and debonding issues in the subsurface. The proposed fiber additives are made from shape memory polymers. These fibers expand upon exposure to temperatures above certain limits; which is selected to be below the temperature of the cementing zone. In this situation, the expansion occurs before the cement setting but after its placement. If the expansion occurs after cement setting, it may lead to microfractures. As a result of the controlled expansion of the cement paste, the creation of channels and fluid migration can be minimized while maintaining the mechanical properties required for cement integrity. Considering the inert property of the proposed additive, the cement water ratio and its chemical properties do not change. The cement expansion, fluid loss, gel strength, compressive strength, and tensile strength of the samples containing these fibers are examined by destructive and non-destructive methods and presented here. The proposed class of expandable additives can help the operators reach sustainable well integrity by improving the bonding between the cement and casing.

Website | DOI: 191822-18ERM-MS


Livio Santos, Arash Dahi Taleghani, Guoqiang Li

Expandable Proppants to Moderate Production Drop in Hydraulically Fractured Wells

Journal of Natural Gas Science and Engineering

Hydraulic fracturing is recognized as the primary technique to achieve economic oil and gas production from low permeability reservoirs like shale and tight-sand formations. One of the main challenges facing the oil and gas industry is maintaining the proppant functionality in the subsurface to guarantee a sustainable production rate and higher ultimate recovery. Proppant crushing and proppant embedment may diminish production from stimulated wells especially when bottomhole pressure is reaching low flowing pressures in soft and deep formations like Haynesville or Tuscaloosa Marine Shales. Experimental measurements and field observations have shown the strong impact of proppant stress and proppant embedment on reducing fracture conductivity. In this work, we introduce a novel material developed in order to achieve higher fracture conductivities at a minimum cost. The new type of proppants, so called "Expandable Proppants" (EP), is able to remotely control the expanding force and maintain the functionality of placed proppants. The presented proppants are made out of thermoset shape memory polymers which are activated by formation's in situ temperature to effectively maintain or even increase fracture's width. A fully coupled numerical model is developed to study the effectiveness of expandable proppants and evaluate fracture conductivity enhancement for different combinations and distributions of EP. In addition, a series of experiments were conducted in a modified API conductivity cell to verify the increase in fracture conductivity. Numerical and experimental results demonstrate that proppant expansion can increase the permeability up to 100%. Different conditions of confining stress and proppant sizes are studied to verify the optimum proppant design. This product can extend the lifetime of the fracture and ensure lasting production.

Website | DOI: 10.1016/j.jngse.2018.04.026


2017


Livio Santos, Arash Dahi Taleghani, Guoqiang Li

Expandable Diverting Agents to Improve Efficiency of Refracturing Treatments

Unconventional Resources Technology Conference

The use of chemical diverters in refracturing operations has been increasing and taking the place of mechanical diverters, which were a prevailing technique for years. Chemical diverters consist of particles or liquid that can temporarily clog pre-existing fractures, allowing diversion of the fracturing fluid to create new fractures inside the reservoir and generate a more complex fracture network. The success or failure of a re-stimulation treatment largely depends on the diverter placement and effective isolation of previous fractures. In this work, we propose a novel class of materials as a diverting agent that after pumping into the formation expands to temporarily plug the existing fractures and allow the frac energy to concentrate on generating new fracture strands. Biodegradation and chemical dissolution can be utilized at the end of the treatment to resume the flow from isolated fractures. Proof-of-concept experiments were carried out using a particle-plugging apparatus to demonstrate the bridging ability of the expandable diverter. The fracture sealing process is observed with the steep increase in the fluid pressure. In order to further tune the performance of this diverter and simulate its performance in reservoir conditions, we developed a numerical model to simulate its placement and expansion. The coupled computational fluid dynamics-discrete element method approach can track the diverting particles individually and simulate the frac fluid flow within the fractures. Multiple scenarios were tested, with different particle sizes and networks of fractures.

Website | DOI: 10.15530/urtec-2017-2697493


2016


Livio Santos

Expandable Proppants for Hydraulic Fracturing

MSc Thesis

The use of chemical diverters in refracturing operations has been increasing and taking the place of mechanical diverters, which were a prevailing technique for years. Chemical diverters consist of particles or liquid that can temporarily clog pre-existing fractures, allowing diversion of the fracturing fluid to create new fractures inside the reservoir and generate a more complex fracture network. The success or failure of a re-stimulation treatment largely depends on the diverter placement and effective isolation of previous fractures. In this work, we propose a novel class of materials as a diverting agent that after pumping into the formation expands to temporarily plug the existing fractures and allow the frac energy to concentrate on generating new fracture strands. Biodegradation and chemical dissolution can be utilized at the end of the treatment to resume the flow from isolated fractures. Hydraulic fracturing is recognized as the primary technique to achieve economic oil and gas production from low permeability reservoirs like shale and tight-sand formations. One of the main challenges facing the oil and gas industry is maintaining the proppant functionality in the subsurface where replacement of proppant is only possible by expensive refracturing operations. Proppant crushing and proppant embedment have posed challenges for sustainable production from stimulated wells especially in soft and deep formations like Haynesville Shales. Experimental measurements show the strong impact of proppant stress and proppant embedment on reducing fracture conductivity. In this work, we introduce a new class of smart ”Expandable Proppants” (EP) to remotely control the expanding force and maintain the functionality of injected placed proppants. Our smart proppants are made out of thermoset shape memory polymers which are activated by formations in situ temperature to effectively maintain or even increase fractures width. A fully coupled CFD-DEM model is developed to study the effectiveness of expandable proppants and evaluate fracture conductivity enhancement via different combination and distribution of EP. In addition, a series of experiments were conducted in a modified API conductivity cell to measure the increase in fracture conductivity. Different conditions of temperature, confining stress, proppant size and concentrations are carried out to verify the optimum conditions.

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